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Angew Chem Int Ed Engl
; : e202205748, 2022 May 10.
Article
in English
| MEDLINE
| ID: mdl-35536889
ABSTRACT
A powerful approach to cooperative group-transfer catalysis is demonstrated using the Co=Si bond of a cobalt silylene to provide two distinct sites for substrate activation. The orthogonal selectivity of the Co and Si centers enables efficient nitrene-group transfer to carbon monoxide by avoiding poisoning that would result from substrates competing for a single reactive site.
