Laboratory trial and full-scale implementation of integrated anaerobic-aerobic treatment for high strength acrylic acid wastewater.

Sustainable treatment of highly polluting industrial wastewaters poses a challenge to many municipalities. This study presented treatment of a high strength inhibitory acrylic acid wastewater by integrated anaerobic-aerobic processes. A novel scheme integrating anaerobic granular sludge blanket (GSB) reactor, aerobic carrier biofilm (CBR) reactor and activated sludge reactor (ASR) was tested. The laboratory trial showed that the GSB was able to degrade exceptionally high chemical oxygen demand (COD up to 32,420 mg/L) acrylic acid wastewater laden with 5% waste oil. Operated under a high volumetric loading (VLR) rate of 21.6 g/L·d, the integrated GSB-CBR-ASB achieved 99% of COD removal, of which 90% were removed by the anaerobic process and 9% by the aerobic processes. Full-scale implementation indicated comparable performance with overall removal up to 99%, thus meeting the discharge limits of 500 mg COD/L of public sewer. The integrated scheme was effective in which the anaerobic GSB functioning as a prime degrader that degraded most of the pollutants, while the aerobic CBR-ASB serving as a polisher that removed the remaining COD. With adequate microbial acclimation and granulation, the novel integrated scheme offers a resilient and robust treatment system for high strength inhibitory acrylic acid wastewater.

Startup and performance of full-scale anaerobic granular sludge blanket reactor treating high strength inhibitory acrylic acid wastewater.

High strength inhibitory wastewaters from chemical industries are commonly treated by energy-intensive physicochemical methods. The present work examines the startup and performance of a full-scale anaerobic granular sludge blanket (GSB) plant for treatment of an inhibitory acrylic acid wastewater. From a performance test on chemical oxygen demand (COD) loading up to 9800 mg/L and 3074 kg/d, the GSB plant removed 95% of COD. Coupled with a two-stage aerobic effluent polishing unit, the integrated anaerobic-aerobic plant achieved a remarkable total COD removal of 98-99% at full design load. Final effluent ranging from 173 to 278 mg COD/L conformed to the public sewer limits of 500 mg/L. Acclimated microbes and granulation resulted in efficient degradation of the inhibitory wastewater. Adequate reactor and process designs are crucial for granulation and robust treatment. The anaerobic and aerobic processes complement each other as anaerobic prime degrader and aerobic polisher in the integrated processes.