Biopolymer Compositions Based on Poly(3-hydroxybutyrate) and Linear Polyurethanes with Aromatic Rings-Preparation and Properties Evaluation.

Polymer biocompositions of poly(3-hydroxybutyrate) (P3HB) and linear polyurethanes (PU) with aromatic rings were produced by melt-blending at different P3HB/PU weight ratios (100/0, 95/5, 90/10, and 85/15). Polyurethanes have been prepared with 4,4'-diphenylmethane diisocyanate and polyethylene glycols with molar masses of 400 g/mol (PU400), 1000g/mol (PU1000), and 1500 g/mol (PU1500). The compatibility and morphology of the obtained polymer blends were determined by infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). The effect of the polyurethane content in the biocompositions on their thermal stability and mechanical properties was investigated and compared with those of the native P3HB. It was shown that increasing the PU content in P3HB-PU compositions to 10 wt.% leads to an improvement in the mentioned properties. The obtained results demonstrated that the thermal stability and mechanical properties of P3HB were improved, particularly in terms of increasing the degradation temperature, reducing hardness, and increasing impact strength. The best thermal and mechanical properties were shown by the P3HB-PU polymer compositions containing 10 wt.% of polyurethane modifiers, especially PU1000, which was also confirmed by the morphology analysis of these biocompositions. The presence of polyurethanes in the resulting polymer biocomposites decreases their glass transition temperatures, i.e., makes the materials more flexible. The resulting polymer biocompositions have suitable mechanical properties and thermal properties within the processing conditions for the predicted application as biodegradable, short-lived products for agriculture.

Renewable whey-based hydrogel with polysaccharides and polyvinyl alcohol as a soil amendment for sustainable agricultural application.

This work describes the preparation of a novel biopolymer hydrogel based on acid whey, cellulose derivatives and polyvinyl alcohol (PVA). The hydrogel was prepared and characterized with the aim of producing an environmentally-friendly soil amendment to increase water retention capacity of the soil. The findings showed considerable swelling properties of the hydrogels depending on the PVA content and crosslinking density. The samples with PVA in a concentration 2.5 % and 5 % were more rigid, the gel fraction increased with a subsequently decrease in their swelling capacity. The hydrogels crosslinked with 15 % of citric acid demonstrated a constant swelling ratio (SR) of around 500 % within 10 swelling/drying cycles. The hydrogels crosslinked with 10 % citric acid and supplemented with 1 % of PVA showed SR of 1000-1400 % caused by less crosslinked polymer network and increased pore volume for water uptake. It was found that hydrogel with a higher gel fraction had a stable structure. Supplementing PVA at 5 % extended the period of decomposition of the hydrogel material by almost 60 % in the soil environment and soil humidity was maintained for longer. Applying 2 % of the hydrogel 5PVA to soil increased the water retention capacity by 19 %.

Eco-friendly whey/polysaccharide-based hydrogel with poly(lactic acid) for improvement of agricultural soil quality and plant growth.

A set of renewable and biodegradable hydrogels based on acid whey and cellulose derivatives blended with poly(lactic acid) (PLA) were designed as eco-friendly biopolymeric material for sustainable agricultural applications. The physico-chemical properties of the hydrogel were evaluated using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and rheological measurements. The effect of the whey/polysaccharide/PLA hydrogel on soil quality improvement (water retention study, biodegradability, loading capacity and release of the fertilizers) and the growth pattern of Raphanus sativus and Phaseolus vulgaris has been also studied. The addition of PLA has been found to improve mechanical properties of the hydrogel. The introduction of 20% wt PLA extended decomposition time of hydrogels by 25% which makes the material more stable in the environment and maintaining the soil humidity for longer. The increasing the amount of PLA led to a rise in hydrogel viscosity brought about better entrapment efficiency of the fertilizers (86-92% for KNO3 and 87-96% for urea, resp.) compared to control (82% for KNO3 and 85% for urea, resp.). The novel hydrogels with swelling ratio of up to 500% showed potential as a sustainable water reservoir for plants improving water retention capacity of the soil by 30%.