ABSTRACT
We have directly time resolved coherent phonon oscillations in quasi-one-dimensional organic crystals of MePTCDI ( N-N'-dimethylperylene-3,4,9,10-dicarboximide), using femtosecond pump-probe experiments. We observe both higher-energy oscillations caused by intramolecular vibrations (internal phonons) and, for the first time in a quasi-one-dimensional organic system, lower-energy modulations which are related to coherent lattice phonons (external phonons). For internal A(g) vibrations, the coherence decay time of about 2 ps is almost independent of the mode. In contrast, the damping time of the external phonons increases strongly with decreasing energy.
ABSTRACT
High-resolution amplitude and phase linear spectroscopy of high-quality bulk GaAs are reported. The detailed structure of the observed full complex transmission is consistently explained by polariton effects on the basis of microscopic calculations. The coupled equations for the excitonic polarization and the light field in the slab configuration are evaluated using appropriate boundary conditions for the electromagnetic field and the excitonic wave function without reference to additional boundary conditions for the macroscopic polarization.
