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1.
Carbohydr Polym ; 223: 115062, 2019 Nov 01.
Article in English | MEDLINE | ID: mdl-31426967

ABSTRACT

Nata de coco was chemically modified to afford the bacterial cellulose hydrogels carrying terminal alkynes. The resultant hydrogels were then converted into hydrogels carrying lactosides or those carrying α-2,3-sialyllactosides by the Cu+-catalyzed alkyne-azide cyclization. The stable homo association of the hydrogels carrying lactosides was observed in an aqueous solution containing Ca2+, thereby demonstrating the Ca2+-mediated lactoside-lactoside interactions. Ca2+ also stabilized the hetero associations among the hydrogels carrying lactosides and those carrying α-2,3-sialyllactosides, thereby also demonstrating the Ca2+-induced interactions between the lactosides and the α-2,3-sialyllactosides. The sizes of these hydrogels were of the order of ca. 5 mm, and their associations could thus be readily monitored with the naked eye.


Subject(s)
Cellulose/chemistry , Hydrogels/chemistry , Oligosaccharides/chemistry , Polysaccharides, Bacterial/chemistry , Alkynes/chemistry , Azides/chemistry , Calcium/chemistry , Cocos/chemistry , Cocos/microbiology , Hydrogels/chemical synthesis , Magnesium/chemistry , Plant Lectins/chemistry , Ricinus/chemistry , Sodium/chemistry
2.
Carbohydr Res ; 481: 23-30, 2019 Jul 15.
Article in English | MEDLINE | ID: mdl-31220628

ABSTRACT

We synthesized phenylacetylenes containing ß-lactoside, ß-cellobioside, or ß-maltoside, and polymerized them to produce the corresponding poly (phenylacetylene)s. In these poly (phenylacetylene)s, the pendent carbohydrates were tethered to the mainchains by serinol spacers. Because similar glycosyl serinol units are found in the natural glycosphingolipids in cell membranes, the densely packed carbohydrate clusters along the poly (phenylacetylene) mainchains act as molecular mimics of cell surface glycoclusters. We analyzed the conformation of the glycosylated poly (phenylacetylene)s using circular dichroism spectroscopy, and found that the spatial carbohydrate packing within the glycoclusters changed on the addition of salts.


Subject(s)
Acetylene/analogs & derivatives , Molecular Conformation , Propanolamines/chemistry , Propylene Glycols/chemistry , Sugars/chemistry , Acetylene/chemical synthesis , Acetylene/chemistry , Chemistry Techniques, Synthetic , Glycosylation , Molecular Dynamics Simulation , Polymerization , Salts/chemistry , Stereoisomerism , Water/chemistry
3.
Adv Exp Med Biol ; 1104: 21-39, 2018.
Article in English | MEDLINE | ID: mdl-30484242

ABSTRACT

Densely packed carbohydrate clusters on cell surfaces play essential roles in varieties of bioprocesses. Little information has been, however, accumulated so far concerning their structural/functional details. In this chapter, we discuss artificial systems to investigate carbohydrate-carbohydrate interactions within/between the carbohydrate cluster(s). Among such artificial systems, much attention will be especially placed on glycosylated tris-bipyridine ferrous complexes for monitoring not only carbohydrate-carbohydrate interactions within the glycocluster but also their resultant conformational changes.


Subject(s)
Carbohydrates/chemistry , Coordination Complexes/chemistry , Glycosylation
4.
Carbohydr Res ; 458-459: 67-76, 2018 Mar 22.
Article in English | MEDLINE | ID: mdl-29466762

ABSTRACT

We developed new gossypol (Gos)-based glycoconjugates through dehydration condensation of native Gos and chemically modified glycosides having aminooxy groups. The resultant glycoconjugates (glycoGos) were resistant to hydrolysis, although they were light-sensitive and slowly decomposed even under indoor lighting. The glycoGos also exhibited improved water solubility compared with native Gos, but their saturated concentrations in water were still low (6.4-17 µM), due to their hydrophobic naphthyl rings. We also carried out WST-8 assays to assess the anticancer activity of the glycoGos on DLD-1 and HepG2 cells and found that the glycoGos having ß-lactosides and having ß-galactosides (specific ligands for asialoglycoprotein receptors) showed enhanced anticancer activity on HepG2 cells.


Subject(s)
Antineoplastic Agents/chemistry , Carbohydrates/chemistry , Gossypol/chemistry , Drug Delivery Systems/methods
5.
Anim Sci J ; 88(10): 1636-1643, 2017 Oct.
Article in English | MEDLINE | ID: mdl-28402014

ABSTRACT

The efficacy of advanced treatment of swine wastewater using thermally polymerized, modified amorphous silica and hydrated lime (M-CSH-lime) for color and phosphorus removal and sulfur for nitrogen removal was examined with a demonstration-scale treatment plant. The color removal rate was approximately 78% at M-CSH-lime addition rates of > 0.055 wt/v%. The PO43--P removal rate exceeded 99.9% with > 0.023 wt/v%. pH of the effluent from the M-CSH-lime reactor increased with the addition rate till a maximum value of 12.7, which was effective in disinfection. The recovered M-CSH-lime would be suitable as a phosphorus fertilizer because the total P2 O5 content was approximately 10%. The nitrogen oxide (NOx-N) removal rate by sulfur denitrification increased to approximately 80% when the NOx-N loading rate was around 0.1 kg-N/ton-S/day. It was suggested that the combination of the two processes would be effective in the advanced treatment of swine wastewater.


Subject(s)
Bioreactors , Calcium Compounds , Color , Nitrogen/isolation & purification , Oxides , Phosphorus/isolation & purification , Silicon Dioxide , Sulfur/isolation & purification , Wastewater/chemistry , Water Purification/methods , Animals , Denitrification , Disinfection , Fertilizers , Nitrogen Oxides/isolation & purification , Polymerization , Swine , Water Pollution/prevention & control
6.
Sci Rep ; 6: 37937, 2016 11 29.
Article in English | MEDLINE | ID: mdl-27897218

ABSTRACT

We report an unexpectedly large flux loss observed in permanent magnets in one of the undulators operated in SACLA, the x-ray free electron laser facility in Japan. Characterizations of individual magnets extracted from the relevant undulator have revealed that the flux loss was caused by a homogeneous magnetization reversal extending over a wide area, but not by demagnetization of individual magnets damaged by radiation. We show that the estimated flux-loss rate is much higher than what is reported in previous papers, and its distribution is much more localized to the upstream side. Results of numerical and experimental studies carried out to validate the magnetization reversal and quantify the flux loss are presented, together with possible countermeasures against rapid degradation of the undulator performance.

7.
Carbohydr Polym ; 137: 277-286, 2016 Feb 10.
Article in English | MEDLINE | ID: mdl-26686131

ABSTRACT

Chitosan-based glycopolymers having multiple ß-lactosides exclusively at their C6-positions were successfully synthesized from partially deacetylated chitin through perfect N-deacetylation/phthaloylation and C6-selective bromination/azidation to afford 6-azide-6-deoxy-N-phthaloyl-chitosan and the subsequent Cu(+)-catalyzed Huisgen cycloadditions using alkyne-terminated ß-lactoside and/or quaternary ammonium modules followed by dephthaloylations. Lectin-affinities of the resultant chitosan-based glycopolymers were assessed through fluorescence titration assays to show their unique sigmoidal binding profiles with amplified binding constants.


Subject(s)
Chitosan/chemistry , Lectins/chemistry , Polymers/chemistry , Click Chemistry , Stereoisomerism
8.
Environ Technol ; 35(21-24): 2982-7, 2014.
Article in English | MEDLINE | ID: mdl-25189846

ABSTRACT

Advanced treatment using an agent synthesized from amorphous silica and hydrated lime (M-CSH-lime) was developed and applied to swine wastewater treatment. Biologically treated wastewater and M-CSH-lime (approximately 6 w/v% slurry) were fed continuously into a column-shaped reactor from its bottom. Accumulated M-CSH-lime gradually formed a bed layer. The influent permeated this layer and contacted the M-CSH-lime, and the treatment reaction progressed. Treated liquid overflowing from the top of the reactor was neutralized with CO2gas bubbling. The colour removal rate approximately exceeded 50% with M-CSH-lime addition rates of > 0.15 w/v%. The removal rate of PO(3⁻)(4) exceeded 80% with the addition of>0.03 w/v% of M-CSH-lime. The removal rates of coliform bacteria and Escherichia coli exceeded 99.9% with > 0.1 w/v%. Accumulated M-CSH-lime in the reactor was periodically withdrawn from the upper part of the bed layer. The content of citric-acid-soluble P2O5 in the recovered matter was>15% when the weight ratio of influent PO(3⁻)(4) -P to added M-CSH-lime was > 0.15. This content was comparable with commercial phosphorus fertilizer. The inhibitory effect of recovered M-CSH-lime on germination and growth of leafy vegetable komatsuna (Brassica rapa var. perviridis) was evaluated by an experiment using the Neubauer's pot. The recovered M-CSH-lime had no negative effect on germination and growth. These results suggest that advanced water treatment with M-CSH-lime was effective for simultaneous removal of colour, [Formula: see text] and coliform bacteria at an addition rate of 0.03-0.15 w/v%, and that the recovered M-CSH-lime would be suitable as phosphorus fertilizer.


Subject(s)
Calcium Compounds/chemistry , Fertilizers , Oxides/chemistry , Silicon Dioxide/chemistry , Swine , Waste Disposal, Fluid/methods , Wastewater , Animals , Brassica rapa/drug effects , Brassica rapa/growth & development , Calcium Compounds/toxicity , Color , Enterobacteriaceae/isolation & purification , Fertilizers/toxicity , Germination/drug effects , Metals, Heavy/analysis , Oxides/toxicity , Phosphates/analysis , Silicon Dioxide/toxicity , Water Pollutants/analysis
9.
Bioorg Med Chem ; 21(11): 2895-902, 2013 Jun 01.
Article in English | MEDLINE | ID: mdl-23639683

ABSTRACT

The glycopolymer composed of an inulin scaffold and pendent ß-lactosides was developed from commercially available inulin through sequential chemical modification processes composed of tosylation, azidation, and the subsequent Huisgen cyclocoupling with an alkyne-terminated ß-lactoside. The resultant inulin-based glycopolymer has unique dual affinity towards ß-galactoside and α-glucoside specific lectins which is attributable to its pendent ß-lactosides and terminal α-glucoside. Its gellation property was also accessed to find that the inulin-based glycopolymer forms hydrogels whose critical gellation concentration (CGC) was lower than that required for hydrogels made from native inulin. Drug release properties of the inulin-based glycopolymer were also discussed in this paper.


Subject(s)
Drug Carriers/chemical synthesis , Galactosides/chemistry , Hydrogels/chemistry , Inulin/chemical synthesis , Lectins/chemistry , Alkynes/chemistry , Drug Carriers/chemistry , Fluorescein-5-isothiocyanate , Fluorescent Dyes , Inulin/chemistry , Kinetics , Rutin/chemistry , Spectrometry, Fluorescence , Tosyl Compounds/chemistry
10.
Bioorg Med Chem Lett ; 22(2): 1189-93, 2012 Jan 15.
Article in English | MEDLINE | ID: mdl-22177083

ABSTRACT

We successfully synthesized inulin tosylates by treating commercially available inulin with tosyl chloride and triethylamine in N,N-dimethylacetoamide at the ambient temperature for 24h. The subsequent S(N)2 reactions using sodium azide afford inulin azides that can act as useful substrates for the following Huisgen cycloaddition with alkyne-terminated ß-lactoside. The resultant inulin derivative having multiple ß-lactosides has excellent affinity towards a ß-lactoside binding lectin (RCA(120)). This synthetic strategy has various advantages, such as non-fragmentation of the inulin mainchain and wide applications for various alkyne-terminated functional units. Our strategy can be, therefore, used to develop various inulin derivatives that are applicable for food and medicinal industries.


Subject(s)
Azides/chemistry , Glycoconjugates/chemistry , Inulin/chemistry , Tosyl Compounds/chemistry , Glycoconjugates/chemical synthesis , Inulin/chemical synthesis , Magnetic Resonance Spectroscopy/standards , Reference Standards , Spectrometry, Fluorescence , Spectrophotometry, Infrared
11.
Chem Commun (Camb) ; (36): 5442-4, 2009 Sep 28.
Article in English | MEDLINE | ID: mdl-19724812

ABSTRACT

The conformation of ferrocene with two betaLac appendages is changed on addition of Ca2+ and Na+, which can be ascribed to intramolecular betaLac-betaLac interactions mediated by these cations and the resultant stabilization of twisted rotamers along the Cp-Fe-Cp axis.


Subject(s)
Carbohydrates/chemistry , Ferrous Compounds/chemistry , Cations/chemistry , Circular Dichroism , Glycosides/chemical synthesis , Glycosides/chemistry , Glycosylation , Lactose/analogs & derivatives , Lactose/chemistry , Maltose/chemistry , Metallocenes , Models, Molecular , Sialic Acids/chemistry
12.
Org Biomol Chem ; 5(15): 2404-12, 2007 Aug 07.
Article in English | MEDLINE | ID: mdl-17637960

ABSTRACT

Beta-1,3-glucans having carbohydrate-appendages (alpha-D-mannoside, N-acetyl-beta-D-glucosaminide and beta-lactoside) at the C6-position of every repeating unit can be readily prepared from curdlan (a linear beta-1,3-glucan) through regioselective bromination/azidation to afford 6-azido-6-deoxycurdlan followed by chemo-selective Cu(i)-catalyzed [3 + 2]-cycloaddition with various carbohydrate modules having a terminal alkyne. The resultant carbohydrate-appended curdlans can interact with polycytosine to form stable macromolecular complexes consistent with two polysaccharide strands and one polycytosine strand. Furthermore, these macromolecular complexes show strong and specific affinity toward carbohydrate-binding proteins (lectins). Therefore, one can utilize these carbohydrate-appended curdlans as a new family of glycoclusters.


Subject(s)
Lectins/chemistry , Polynucleotides/chemistry , beta-Glucans/chemistry , Alkynes/chemistry , Azides/chemistry , Catalysis , Circular Dichroism , Copper/chemistry , Cytosine/chemistry , Glycosylation , Magnetic Resonance Spectroscopy , Models, Molecular , Molecular Structure , Oxidation-Reduction , Solvents , Surface Plasmon Resonance
13.
J Am Chem Soc ; 129(13): 3979-88, 2007 Apr 04.
Article in English | MEDLINE | ID: mdl-17352476

ABSTRACT

We succeeded in the quantitative and selective introduction of an ammonium cationic group into the C6 position of Curdlan (CUR) by "Click Chemistry", and the obtained cationic Curdlan (CUR-N+) showed good solubility in water. ORD studies suggested that CUR-N+ adopts a single-stranded structure, different from a right-handed, triple-stranded helical structure of beta-1,3-glucan polysaccharides in water. It has been revealed that the polymeric complexes of CUR-N+ with polymeric guest molecules, such as polycytidylic acid (poly(C)), permethyldecasilane (PMDS), and single-walled carbon nanotubes (SWNTs), can be easily obtained by just mixing them in water with sonication. The characterization of the resultant CUR-N+-poly(C) complexes by UV-vis, CD spectroscopic measurements, and AFM and TEM observations revealed that they have stoichiometric, nanosized fibrous structures. From these experimental results as well as our precedent studies (e.g., refs 6 and 23), we propose that the complexation would be driven by the cooperative action of (1) the hydrogen-bonding interaction between the OH group at the C2 position and hydrogen-bonding sites of the cytosine ring (ref 6d), (2) the electrostatic interaction between the ammonium cation and the phosphate anion (ref 23), as well as (3) the background hydrophobic interaction. In addition, the complexed polynucleotide chain showed a strong resistance against enzymatic hydrolysis. Likewise, the dispersion of PMDS and SWNTs in water by CUR-N+ and the fibrous structures of the complexes were confirmed by spectroscopic measurements as well as microscopic observations. These binding properties of CUR-N+, which can proceed spontaneously in water, clearly differ from those of schizophyllan (SPG), which inevitably require a denature-renature process corresponding to a conversion of a triple strand to single strands induced by DMSO or base for inclusion of polymeric guest molecules.


Subject(s)
Cations/chemistry , Glucans/chemistry , Polynucleotides/chemistry , Carbohydrate Conformation , Glucans/metabolism , Glucans/ultrastructure , Hydrolysis , Hydrophobic and Hydrophilic Interactions , Microscopy, Atomic Force , Microscopy, Electron, Transmission , Models, Molecular , Ribonucleases/metabolism , Solutions , Spectrum Analysis , beta-Glucans/chemistry
14.
Org Lett ; 8(24): 5533-6, 2006 Nov 23.
Article in English | MEDLINE | ID: mdl-17107065

ABSTRACT

We have demonstrated that one-dimensional supramolecular dye assemblies with a uniform diameter can be created by utilizing schizophyllan (SPG) as a one-dimensional host. In the supramolecular nanofibers, the dye molecules are assembled into the different aggregation modes depending on the preparation procedures. The findings establish that SPG is useful for creating the supramolecular nanofibers, where temporal superstructures can be stabilized by the SPG-specific helical higher-order structure. [structure: see text].

15.
Biomaterials ; 27(8): 1626-35, 2006 Mar.
Article in English | MEDLINE | ID: mdl-16174528

ABSTRACT

Antisense oligonucleotides (AS ODNs) are applied to silence a particular gene, and this approach is one of the potential gene therapies. However, naked oligonucleotides are easy to be degraded or absorbed in biological condition. Therefore, we need a carrier to deliver AS ODNs. This paper presents galactose moieties that were conjugated to the side chain of SPG to enhance cellular ingestion through endocytosis mediated by asialoglycoprotein receptor specifically located on parenchymal liver cells. We introduced galactose with two types of chemical bonds; amide and amine, and the amine connection showed lower ingestion and more toxicity than the amide one. Since PEG was known to induce endocytosis escape, we combined PEG and galactose aiming to provide both cellular up-take and subsequent endocytosis escape. We designed lactose or galactose moieties to attach to the end of the PEG chain that connects to the SPG side chain. When the PEG had the molecular weight of 5000-6000, the antisense effect reached the maximum. We believe that this new type of galactose and PEG dual conjugation broaden the horizon in antisense delivery.


Subject(s)
Biocompatible Materials , Drug Delivery Systems , Galactose , Oligonucleotides, Antisense/metabolism , Polyethylene Glycols , Sizofiran , beta-Glucans/pharmacology , Cell Line , Cell Line, Tumor , Humans , Sizofiran/chemical synthesis , Sizofiran/metabolism , Sizofiran/pharmacology , beta-Glucans/chemical synthesis , beta-Glucans/metabolism
16.
Carbohydr Res ; 341(1): 35-40, 2006 Jan 16.
Article in English | MEDLINE | ID: mdl-16289495

ABSTRACT

(1-->3)-beta-D-Glucans having various functional appendages (lactoside, ferrocene, pyrene, and porphyrin) can be prepared in an convenient, quantitative, and regioselective manner through regioselective bromination-azidation of curdlan to afford 6-azido-6-deoxycurdlan followed by chemoselective [3+2]-cycloadditions with various functional modules bearing a terminal alkyne group. The ability to monitor reaction conversions is an additional advantage of this synthetic approach over the conventional direct modifications on polysaccharides; the reaction can be readily monitored based on the intensity of azido peaks in the in situ attenuated total reflection infrared spectra.


Subject(s)
beta-Glucans/chemical synthesis , Alkynes/chemistry , Azides/chemistry , Nuclear Magnetic Resonance, Biomolecular , Proteoglycans , Spectroscopy, Fourier Transform Infrared , beta-Glucans/chemistry
17.
Org Lett ; 7(25): 5605-8, 2005 Dec 08.
Article in English | MEDLINE | ID: mdl-16321002

ABSTRACT

[chemical structure: see text]. Schizophyllan can interact with permethyldecasilane to produce the corresponding decasilane-nanofiber, in which the decasilane adopts helical conformations in a tubular hollow created by the helical superstructure of schizophyllan.


Subject(s)
Nanostructures/chemistry , Nanostructures/ultrastructure , Nanotechnology/methods , Silanes/chemistry , Sizofiran/chemistry , Microscopy, Atomic Force , Microscopy, Electron, Transmission , Models, Molecular , Molecular Conformation , Spectrometry, Fluorescence
18.
Org Biomol Chem ; 3(24): 4321-8, 2005 Dec 21.
Article in English | MEDLINE | ID: mdl-16327892

ABSTRACT

Schizophyllan interacts with various 1,4-diphenylbutadiyne derivatives to induce their chirally-twisted packing. A series of referential experiments using other polysaccharides (amylose, pullulan, dextran, etc.) and a carbohydrate-appended detergent (dodecyl-beta-d-glucopyranoside) indicates that these 1,4-diphenylbutadiyne derivatives are accommodated within a tubular cavity constructed by a helical superstructure of schizophyllan. In these 1,4-diphenylbutadiyne derivatives, 1,4-bis(p-propionamidophenyl)butadiyne can be easily polymerized through UV-irradiation, in which schizophyllan acts as a one-dimensional mold to produce the corresponding poly(diacetylene)s with fibrous morphologies. Detailed investigations on this unique approach to prepare the nanofibers revealed that it includes two individual processes, that is, 1) UV-mediated polymerization of encapsulated 1,4-bis(p-propionamidophenyl)butadiyne to produce immature nanofibers and 2) their reorganization through hydrophobic interfiber interactions into ordered nanofibers. The other 1,4-diphenylbutadiyne derivatives could not be polymerized through UV-irradiation, indicating that the p-propionamido-functionalities play substantial roles for a suitable packing of the monomer for the polymerization. The other 1,4-diphenylbutadiyne derivatives, however, can be also polymerized through gamma-ray irradiation in the presence of schizophyllan to give the corresponding poly(diacetylene)-nanofibers, emphasizing the wide applicability of the schizophyllan-based strategy for polymerization of various 1,4-diphenylbutadiyne derivatives.


Subject(s)
Acetylene/analogs & derivatives , Nanostructures/radiation effects , Polymers/chemistry , Sizofiran/chemistry , Acetylene/chemistry , Butadienes/chemical synthesis , Butadienes/chemistry , Microscopy, Electron, Transmission , Molecular Structure , Nanostructures/ultrastructure , Polyacetylene Polymer , Polyynes , Spectrum Analysis , Stereoisomerism
19.
Chem Commun (Camb) ; (35): 4383-98, 2005 Sep 21.
Article in English | MEDLINE | ID: mdl-16136229

ABSTRACT

Beta-1,3-glucan polysaccharides have triple-stranded helical structures whose sense and pitch are comparable to those of polynucleotides. We recently revealed that the beta-1,3-glucans could interact with certain polynucleotides to form triple-stranded and helical macromolecular complexes consisting of two polysaccharide-strands and one polynucleotide-strand. This unique property of the beta-1,3-glucans has made it possible to utilize these polysaccharides as potential carriers for various functional polynucleotides. In particular, cell-uptake efficiency of the resultant polysaccharide/polynucleotide complexes was remarkably enhanced when functional groups recognized in a biological system were introduced as pendent groups. The beta-1,3-glucans can also interact with various one-dimensional architectures, such as single-walled carbon nanotubes, to produce unique nanocomposites, in which the single-walled carbon nanotubes are entrapped within the helical superstructure of beta-1,3-glucans. Various conductive polymers and gold nanoparticles are also entrapped within the helical superstructure in a similar manner. In addition, diacetylene monomers entrapped within the helical superstructure can be photo-polymerized to afford the corresponding poly(diacetylene)-nanofibers with a uniform diameter. These findings indicate that the beta-1,3-glucans are very attractive and useful materials not only in biotechnology but also in nanotechnology. These unique properties of the beta-1,3-glucans undoubtedly originate from their inherent, very strong helix-forming character which has never been observed for other polysaccharides.


Subject(s)
DNA/chemistry , Polysaccharides/chemistry , RNA/chemistry , beta-Glucans/chemistry , Biotechnology , Circular Dichroism , Models, Molecular , Spectrophotometry, Ultraviolet
20.
J Am Chem Soc ; 127(16): 5875-84, 2005 Apr 27.
Article in English | MEDLINE | ID: mdl-15839686

ABSTRACT

We have found that single-chain schizophyllan and curdlan (s-SPG and s-curdlan, respectively) can dissolve as-grown and cut single-walled carbon nanotubes (ag-SWNTs and c-SWNTs, respectively) in aqueous solution. The vis-NIR spectra of the composites suggest that c-SWNTs are dissolved as a bundle, whereas ag-SWNTs exist as one or only a few pieces in the tubular hollow constructed by the helical structure inherent to these beta-1,3-glucans. EDX and CLSM measurements and TEM observation established that the distribution map of these polysaccharides overlaps well with the image of SWNTs, indicating that these two components form a composite. Very interestingly, when c-SWNTs were dissolved with the aid of s-SPG or s-curdlan in water, a clear periodical structure with inclined stripes, as detected by AFM, appeared on the fibrous composite surface. Because this periodical structure has never been recognized for the composites with other water-soluble polymers, one can regard that s-SPG or s-curdlan wraps c-SWNTs constructing a helically twined structure. High-resolution TEM observation of an ag-SWNTs/s-SPG composite gave a clearer image in that two s-SPG chains twine one ag-SWNT and the helical motif is right-handed. When this sample was subjected to the AFM measurement, the composite showed the 2-3 nm height. This height implies that one piece of ag-SWNT is included in the s-SPGs helical structure. As a summary, it has been established that beta-1,3-glucans such as s-SPG and s-curdlan not only dissolve SWNTs but also create a novel superstructure on the surface.


Subject(s)
Nanotubes, Carbon/chemistry , Sizofiran/chemistry , beta-Glucans/chemistry , Carbohydrate Sequence , Microscopy, Atomic Force , Models, Molecular , Molecular Sequence Data , Solutions , Spectroscopy, Near-Infrared , Spectrum Analysis, Raman , Water/chemistry
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