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1.
Polymers (Basel) ; 15(14)2023 Jul 21.
Article in English | MEDLINE | ID: mdl-37514503

ABSTRACT

Over the past three decades, chemical and biological water contamination has become a major concern, particularly in the industrialized world. Heavy metals, aromatic compounds, and dyes are among the harmful substances that contribute to water pollution, which jeopardies the human health. For this reason, it is of the utmost importance to locate methods for the cleanup of wastewater that are not genuinely effective. Owing to its non-toxicity, biodegradability, and biocompatibility, starch is a naturally occurring polysaccharide that scientists are looking into as a possible environmentally friendly material for sustainable water remediation. Starch could exhibit significant adsorption capabilities towards pollutants with the substitution of amide, amino, carboxyl, and other functional groups for hydroxyl groups. Starch derivatives may effectively remove contaminants such as oil, organic solvents, pesticides, heavy metals, dyes, and pharmaceutical pollutants by employing adsorption techniques at a rate greater than 90%. The maximal adsorption capacities of starch-based adsorbents for oil and organic solvents, pesticides, heavy metal ions, dyes, and pharmaceuticals are 13,000, 66, 2000, 25,000, and 782 mg/g, respectively. Although starch-based adsorbents have demonstrated a promising future for environmental wastewater treatment, additional research is required to optimize the technique before the starch-based adsorbent can be used in large-scale in situ wastewater treatment.

2.
Polymers (Basel) ; 15(4)2023 Feb 06.
Article in English | MEDLINE | ID: mdl-36850101

ABSTRACT

Studies on the external strengthening of tin slag polymer concrete by fibre-reinforced plastic confinement have provided strength enhancement of tin slag polymer concrete up to 128% with carbon fibre-reinforced plastic confinement. However, the effect of metallic material confinement has yet to be studied. This article presents the experimental finding on tin slag polymer concrete strengthening through metallic material confinement under compressive loads. Machined mild steel metal tube has been employed to strengthen tin slag polymer concrete core in partial and fully confinement prior to compression testing. Through this study, compressive strength of tin slag polymer concrete short column has been enhanced with the metal tube confinement application from 59.19 MPa (unconfined) to 95.86 MPa (partial metal confinement) and 131.84 (full metal confinement) representing 61.95% and 122.74% of strength enhancement percentage. Material behaviour analysis through stress versus strain curves has revealed that the strain softening curve is modified by metal tube confinement before a fracture occurs on both partial and full metal confinement samples compared to the control sample (unconfined). In addition, the failure modes have indicated that the high ductility of metallic confinement material has effectively confined tin slag polymer concrete from sudden fracture where the metal tube in partial confinement indicates ductile expansion while the metal tube in full confinement has shown ductile crushing. In general, it was concluded that metallic material confinement on tin slag polymer concrete under compressive load has resulted in providing strength enhancement and modified the failure mode of tin slag polymer concrete. Finally, further research is recommended, especially by initiating numerical analysis to facilitate parametric studies on tin slag polymer concrete for structural material design.

3.
Polymers (Basel) ; 14(19)2022 Sep 29.
Article in English | MEDLINE | ID: mdl-36236031

ABSTRACT

The crashworthiness of composite tubes is widely examined for various types of FRP composites. However, the use of hybrid composites potentially enhances the material characteristics under impact loading. In this regard, this study used a combination of unidirectional glass-carbon fibre reinforced epoxy resin as the hybrid composite tube fabricated by the pultrusion method. Five tubes with different length aspect ratios were fabricated and tested, in which the results demonstrate "how structural energy absorption affects by increasing the length of tubes". Crash force efficiency was used as the criterion to show that the selected L/D are acceptable of crash resistance with 95% efficiency. Different chamfering shapes as the trigger mechanism were applied to the tubes and the triggering effect was examined to understand the impact capacity of different tubes. A finite element model was developed to evaluate different crashworthiness indicators of the test. The results were validated through a good agreement between experimental and numerical simulations. The experimental and numerical results show that hybrid glass/carbon tubes accomplish an average 25.34 kJ/kg specific energy absorption, average 1.43 kJ energy absorption, average 32.43 kN maximum peak load, and average 96.67% crash force efficiency under quasi-static axial loading. The results show that selecting the optimum trigger mechanism causes progressive collapse and increases the specific energy absorption by more than 35%.

4.
J Mech Behav Biomed Mater ; 136: 105514, 2022 12.
Article in English | MEDLINE | ID: mdl-36215770

ABSTRACT

Sandwich panel is increasingly used as lightweight energy absorbing components, which provides excellent crashworthiness performance with the three-dimensional periodic core. This paper investigates 3D-printed bio-inspired spherical-roof cubic cores with multi-walled carbon nanotubes (MWCNT) and foam-filled cores under quasi-static loading. The proposed bio-inspired spherical-roof cubic cores with 1.5 mm wall thickness were manufactured using the fused filament fabrication process, which used 70% polylactic acid (PLA) and 30% carbon fiber filament. Moreover, four groups of 3D-printed bio-inspired spherical-roof cubic cores were compared and analyzed on compressive properties and failure behavior. Experimental results were shown that foam-filled double bio-inspired spherical-roof cubic core with MWCNT was the maximum Fpeak with 1.92 kN, which provided a much more stable plateau load and better energy-absorbing characteristics. In addition, it is conducted that a double bio-inspired spherical-roof cubic core with four notches core is considered as the potential energy-absorbing core.


Subject(s)
Nanotubes, Carbon , Carbon Fiber , Cytoskeleton , Food , Printing, Three-Dimensional
5.
Polymers (Basel) ; 14(18)2022 Sep 07.
Article in English | MEDLINE | ID: mdl-36145875

ABSTRACT

"Fibre-Reinforced Polymer Composites: Mechanical Properties and Applications" is a newly open Special Issue of Polymers, which aims to publish original and review papers on new scientific and applied research and make boundless contributions to the finding and understanding of the reinforcing effects of various synthetic and natural fibres on the performance of biopolymer composites [...].

6.
Int J Biol Macromol ; 151: 584-594, 2020 May 15.
Article in English | MEDLINE | ID: mdl-32081758

ABSTRACT

Arabinoxylan (AX) is a natural biological macromolecule with several potential biomedical applications. In this research, AX, nano-hydroxyapatite (n-HAp) and titanium dioxide (TiO2) based polymeric nanocomposite scaffolds were fabricated by the freeze-drying method. The physicochemical characterizations of these polymeric nanocomposite scaffolds were performed for surface morphology, porosity, swelling, biodegradability, mechanical, and biological properties. The scaffolds exhibited good porosity and rough surface morphology, which were efficiently controlled by TiO2 concentrations. MC3T3-E1 cells were employed to conduct the biocompatibility of these scaffolds. Scaffolds showed unique biocompatibility in vitro and was favorable for cell attachment and growth. PNS3 proved more biocompatible, showed interconnected porosity and substantial mechanical strength compared to PNS1, PNS2 and PNS4. Furthermore, it has also showed more affinity to cells and cell growth. The results illustrated that the bioactive nanocomposite scaffold has the potential to find applications in the tissue engineering field.


Subject(s)
Biocompatible Materials/chemistry , Bone and Bones , Durapatite/chemistry , Nanocomposites/chemistry , Tissue Engineering , Tissue Scaffolds/chemistry , Titanium/chemistry , Xylans/chemistry , Animals , Biopolymers/chemistry , Cell Line , Cell Survival , Mice , Molecular Structure , Nanocomposites/ultrastructure , Porosity , Spectrum Analysis , Stress, Mechanical
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