Electrolytic manganese residue disposal based on basic burning raw material: Heavy metals solidification/stabilization and long-term stability.

Solidification/stabilization (S/S) is an option for the treatment of electrolytic manganese residue (EMR). Basic burning raw material (BRM) could successfully solidify/stabilize EMR, though heavy metals S/S mechanism and long-term stability remain unclear. Herein, Mn2+ and NH4+ S/S behavior, hydrated BRM and S/S EMR characterization, Mn2+ long-term leaching behavior, phase and morphology changes for long-term leaching were discussed in detail to clarify these mechanisms. Mn2+ and NH4+ leaching concentrations as well as pH value in S/S EMR were respectively 0.02 mg/L, 0.68 mg/L and 8.75, meeting the regulations of Chinese standard GB 8978-1996. Long-term stability of EMR was significantly enhanced after S/S. Mn2+ leaching concentration, Mn2+ migration, Mn2+ cumulative release, Mn2+ apparent diffusion coefficient and conductivity of EMR reduced to 0.05 mg/L, 5.5 × 10-6 mg/(m2·s), ~ 9 mg/m2, 6.30 × 10-15 m2/s and 435 µs/cm. Mechanism studies showed that the hydration of BRM forms OH-, calcium silicate hydrate gels (C-S-H) and ettringite. Therefore, during S/S process, NH4+ was escaped as NH3, Mn2+ was solidified/stabilized as tephroite (Mn2SiO4), johannsenite (CaMnSi2O6) and davreuxite (MnAl6Si4O17(OH)2), and Pb2+, Cu2+, Ni2+, Zn2+ were solidified/stabilized by C-S-H and ettringite via substitution and encapsulation. This study provides a good choice for EMR long-term stable storage.

Synergistic solidification/stabilization of electrolytic manganese residue and carbide slag.

Electrolytic manganese residue (EMR) contains high concentrations of NH4+ and heavy metals, such as Mn2+, Zn2+, Cu2+, Pb2+, Ni2+ and Co2+, while carbide slag (CS) contains high amount of OH- and CO32-, both posing a serious threat to the ecosystem. In this study, EMR and CS synergistic stabilization/solidification (S/S) was discussed science CS could stabilize or solidify EMR and simultaneously reduce its corrosive. The results showed that after the synergistic S/S for 24 h when liquid-solid ratio was 17.5% and CS dosage was 7%, Mn2+ and NH4+ leaching concentrations of the S/S EMR were below the detection limits (0.02 mg/L and 0.10 mg/L) with a pH value of 8.8, meeting the requirements of the Chinese integrated wastewater discharge standard (GB 8978-1996). Mn2+ was stabilized as MnFe2O4, Mn2SiO4, CaMnSi2O6, and NH4+ escaped as NH3. Zn2+, Cu2+, Pb2+, Ni2+ and Co2+ in EMR can also be stabilized/solidified because of the react with OH- and CO32- in CS. Chemical cost was only $ 0.54 for per ton of EMR synergistic harmless treatment with CS. This study provided a new idea for EMR cost-effective and environment-friendly harmless treatment.

A critical review on approaches for electrolytic manganese residue treatment and disposal technology: Reduction, pretreatment, and reuse.

Electrolytic manganese residue (EMR) has become a barrier to the sustainable development of the electrolytic metallic manganese (EMM) industry. EMR has a great potential to harm local ecosystems and human health, due to it contains high concentrations of soluble pollutant, especially NH4+ and Mn2+, and also the possible dam break risk because of its huge storage. There seems to be not a mature and stable industrial solution for EMR, though a lot of researches have been done in this area. Hence, by fully considering the EMM ecosystem, we analyzed the characteristics and eco-environmental impact of EMR, highlighted state-of-the-art technologies for EMR reduction, pretreatment, and reuse; indicated the factors that block EMR treatment and disposal; and proposed plausible and feasible suggestions to solve this problem. We hope that the results of this review could help solve the problem of EMR and thus promote the sustainable development of EMM industry.