Confined Co@NCNTs as highly efficient catalysts for activating peroxymonosulfate: free radical and non-radical co-catalytic mechanisms.

A series of transition metal (Co, Ni, Fe) nanoparticles were confined in N-doped carbon nanotubes (NCNTs) prepared (Co@NCNTs, Ni@NCNTs, and Fe@NCNTs) by the polymerization method. The structure and composition of catalysts were well characterized. The catalytic activity of catalysts for activating peroxymonosulfate (PMS) was conducted via acid orange 7 (AO7) degradation. Among the catalysts, Co@NCNTs performed the best catalytic activity. Additionally, Co@NCNTs performed good catalytic activity in pH values of 2.39-10.98. Cl- and SO42- played a promoting roles in AO7 degradation. NO3- presented a weak effect on the catalytic performance of Co@NCNTs, while HCO3- and CO32- significantly suppressed the catalytic performance of Co@NCNTs. Both non-radical (1O2 and electron transfer) and free-radical (·OH and SO4·-) pathways were detected in the Co@NCNTs/PMS system. Notably, 1O2 was identified to be the main active specie in this study. The catalytic activity of Co@NCNTs gradually decreased after cycle reuse of Co@NCNTs. Finally, the toxicity of the AO7 degradation solution in the study was evaluated by Chlorella pyrenoidosa.

Highly efficient removal of glyphosate from water by hierarchical-pore UiO-66: Selectivity and effects of natural water particles.

The selective removal of glyphosate (GP) from aqueous environments is crucial for ensuring human health and environmental sustainability. The preparation of hierarchical-pore MOFs and the reasonable regulation of the pore size are effective strategies for achieving selective removal. In this study, we applied hierarchical-pore UiO-66 analogues (HUiO-66s) synthesized by the template technique through a mild method for the removal of GP from water. The results showed that the maximum adsorption capacity of HUiO-66s was as high as 400 mg/g, which is higher than that of most reported adsorbents. Notably, HUiO-66s showed the highest adsorption rate and distribution coefficient for GP in a multivariate system containing different organophosphorus pesticides and antibiotics, exhibiting suitable selective adsorption performance for GP. Furthermore, GP adsorption onto HUiO-66-2 (prepared from 2 mL of MOF-5 template) did not affect the presence of competing anions and humic acids. Naturally occurring particles in the water body had an enhanced (i.e., Al2O3, sepiolite, and montmorillonite), reduced (i.e., illite and SiO2), or insignificant (i.e., kaolin) effect on the GP adsorption rate of HUiO-66-2. Further analysis based on the bulk adsorption results and microscopic characterisation indicated that the pore structure synergistically occurred with metal-ligand bonding, hydrogen bonding, and electrostatic interactions, which together determined the GP adsorption. Overall, the high adsorption and apparent adsorption selectivity of HUiO-66s facilitated the rapid separation and removal of GP in complex aqueous environments. Our findings provide insights into the transport and fate of MOFs and contaminants in natural aquatic systems.

Recent advances in cobalt-activated sulfate radical-based advanced oxidation processes for water remediation: A review.

Sulfate radical-based advanced oxidation processes (SR-AOPs) have attracted increasing attention for the degradation of organic contaminants in water. The oxidants of SR-AOPs could be activated to generate different kinds of reactive oxygen species (ROS, e.g., hydroxyl radicals (OH), sulfate radicals (SO4-), singlet oxygen (1O2), and superoxide radicals (O2-)) by various catalysts. As one of the promising catalysts, cobalt-based catalysts have been extensively investigated in catalytic activity and stability during water remediation. This article mainly summarizes recent advances in preparation and applications of cobalt-based catalysts on peroxydisulfate (PDS)/peroxymonosulfate (PMS) activation since 2016. The review covers the development of homogeneous cobalt ions, cobalt oxides, supported cobalt composites, and cobalt-based mixed metal oxides for PDS/PMS activation, especially for the latest nanocomposites such as cobalt-based metal-organic frameworks and single-atom catalysts. This article also discussed the activation mechanisms and the influencing factors of different cobalt-based catalysts for activating PDS/PMS. Finally, the future perspectives on the challenges and applications of cobalt-based catalysts are presented at the end of this paper.