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Caesium ion sequestration by a fluoro-metallocrown [16]-MC-8.
Faust, Thomas B; Heath, Paul G; Muryn, Christopher A; Timco, Grigore A; Winpenny, Richard E P.
Chem Commun (Camb) ; 46(34): 6258-60, 2010 Sep 14.
Article in English | MEDLINE | ID: mdl-20694231

ABSTRACT

A fluoro-metallocrown selectively binds caesium, extracting it from aqueous solutions into an organic layer; the binding of Cs is monitored by (1)H-NMR of the paramagnetic complexes.


Subject(s)
Cesium/chemistry , Organometallic Compounds/chemical synthesis , Crystallography, X-Ray , Ions/chemistry , Magnetic Resonance Spectroscopy , Models, Molecular , Organometallic Compounds/chemistry
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