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4.
Z Lebensm Unters Forsch ; 159(5): 287-92, 1975 Dec 16.
Article in English | MEDLINE | ID: mdl-1224802

ABSTRACT

Phosphatidylethanolamine reacts with 1,4-benzoquinone with the formation of a red unstable intermediary product consisting of one phosphatidylethanolamine residue and one 1,4-benzoquinone residue. The secondary reaction products are purple, violet, and reddish brown. Consequently, the absorption maximum shifts from 430 nm to 490 nm during the reaction. Finally, brown macromolecular end-products are formed. Phospholipids derived from choline, such as phosphatidylcholine, lysophosphatidylcholine, sphingomyelin, contribute only a little to the browning reactions, in comparison with phospholipids containing a primary amino-group (phosphatidylethanolamine, lysophosphatidylethanolamine, phosphatidylserine). The browning of a natural mixture of egg phospholipids depends on the content of derivatives containing a primary amino-group.


Subject(s)
Phospholipids , Quinones , Absorption , Color , Macromolecular Substances , Phosphatidylcholines , Phosphatidylethanolamines , Phosphatidylserines , Sphingomyelins
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