The transfer of 137Cs and heavy metals to tissues within the organs of snails.

This paper describes the dynamics of 137Cs accumulation and its concentration ratio as well as that of some stable elements in the body, shell, gastrointestinal tract and albumin gland of a particular species of snail (terrestrial gastropod), namely the Giant African snail (Lissachatina fulica), after the long-term ingestion of contaminated forage and/or soil. The activity concentration of 137Cs in the their bodies increased over the first 40 days of the experiment, after which the increase in the activity of this radionuclide significantly reduced. The distribution of 137Cs in the body of a snail decreases as follows: gastrointestinal tract ˃ body = albumin gland ˃ shell. It was found that the contribution of soil towards the contamination of their bodies by 137Cs is far less than that of forage. Although the biological availability of Pb and U in forage is one order of magnitude higher than in soil, the main contribution to the contamination of snails originates from soil.

Modelling of indoor external and internal exposure due to different building materials containing NORMs in the vicinity of a HNBRA in Mahallat, Iran.

In this study, by considering the Naturally Occurring Radioactive Materials (NORMs) contained in the building materials used in Mahallat, Iran - an area exposed to a high level of natural background radiation - residential scenarios were simulated by applying the computer code RESRAD-BUILD to estimate the long-term Effective Dose rate of three different cases of basic building materials utilized in walls, floors and ceilings. Maximum effective dose rates of between 504 and 1433 µSv yr-1 were calculated in the second case study, tiled cement floor. The highest external and radon doses were also calculated to be 369 and 1064 µSv, respectively. The simulation results revealed that 232Th and 40K contribute the most and least to the indoor dose, respectively. As a result of a sensitivity analysis, it was found that the air exchange rate is a key variable to easily reduce the radiological impacts of building materials. It was also shown that due to the presence of 226Ra, the sensitivity of effective dose to changes in wall thickness was higher than other radionuclides found in the building materials.

Transfer and bioaccumulation of 210Po from soil to water spinach (Ipomoea aquatica Forrsk.) in Vietnam.

The water spinach (Ipomoea aquatica Forrsk.) is a common vegetable and a part of the staple diet in Vietnam. It has a well-known tendency for the high absorption of lead, including the radioactive isotope 210Pb. 210 Pb day to 210Po, which is one of the most toxic radioactive isotopes when ingested. Currently, there are few data available on the activity concentration or transfer parameters of water spinach grown in Vietnam. To provide this data, in this study, the 210Po activity concentrations in the soil, water and the roots, stems, and leaves of two types of spinach (grown in soil flooded with water and grown in normal soil) in Hanoi, Vietnam were determined by alpha spectrometry. The order of activity concentrations for water spinach grown in unflooded was Cstem < Cleaf < Croot, while for flooded Cstem ≈ Croot < Cleaf. The transfer factors followed a similar pattern.

Transfer of radionuclides from soil to Acacia auriculiformis trees in high radioactive background areas in North Vietnam.

The Acacia auriculiformis is a tree common in tropical Asian countries, capable of growing in many different soil types, so it could be used for biomonitoring for high natural radionuclide areas in tropical and subtropical climates. The transfer factor (TF) of radionuclides from soil to A. auriculiformis in eight uranium and rare earth element (REE) mining areas of North Vietnam was investigated. The activity concentrations 226Ra, 238U, 137Cs, 228Ra, and 40K in both soil and A. auriculiformis showed considerable variation. The TFs of these radionuclides also varied in a wide range. In most of the eight areas, the highest TF was observed for 137Cs and 228Ra. While the TFs for 226Ra and 238U were smallest. In addition, the TFs for radionuclides near REE mines were similar to those observed near uranium mines. The TFs for A. auriculiformis were within the ranges of TF reported for other plants, except for 137Cs.

Study of Well Waters from High-Level Natural Radiation Areas in Northern Vietnam.

The determination of natural radionuclide concentrations plays an important role for assuring public health and in the estimation of the radiological hazards. This is especially true for high level radiation areas. In this study, 226Ra, 228Ra and 238U concentrations were measured in well waters surrounding eight of the high-level natural radiation areas in northern Vietnam. The 226Ra, 228Ra and 238U activity concentrations vary from <1.2 × 10-3-2.7 (0.46), <2.6 × 10-3-0.43 (0.07) and <38 × 10-3-5.32 Bq/L (0.50 of median), respectively. 226Ra and 238U isotopes in most areas are in equilibrium, except for the DT-Thai Nguyen area. The calculated radiological hazard indices are generally higher than WHO (World Health Organization) recommendations. Average annual effective dose and excess lifetime cancer risk values due to drinking well water range from to 130 to 540 µSv/year and 7.4 × 10-6 to 3.1 × 10-5, respectively.

Study of soil to plant transfer factors of 226Ra, 232Th, 40K and 137Cs in Vietnamese crops.

The study of staple food products is crucial to assure public safety and provides input for predictive dose assessment models. To further this goal, the activity concentrations, transfer factors, and radiological hazards of 226Ra, 232Th, 40K, and 137Cs were studied for ten pairs of selected vegetables and soils in Tien Le near Hanoi in Vietnam. This is the first study in this area for Vietnamese vegetable samples. The ten most popular vegetables in Vietnamese diet were selected, namely choy sum, crown daisy, lettuce, cabbage, Malabar spinach, beans, sweet potato, potato, kohlrabi and carrot. The research results showed that the activity concentrations observed in vegetable crops did not present the previously reported strong correlation to those in soil. The ranges of TFs of 226Ra, 232Th, and 40K were 4 × 10-2 - 6.9 × 10-1, 8 × 10-2 - 9.7 × 10-1; and 1.0 × 100-1.6 × 101, respectively. Values for leafy vegetables and tubers exceed previous world range figures for Th and K. The soil has been evaluated for radiological hazard indices, which predict almost no risk to human health in the study area.

CAESIUM RETENTION CHARACTERISTICS OF KNIFC-PAN RESIN FROM RIVER WATER.

The caesium retention characteristics of a potassium-nickel hexacyanoferrate resin in a polyacrylnitrile (KNiFC-PAN) matrix were tested in fresh water over the range of 2.5-400 mL min-1. The experimental setup used 2 mL resin and 4-L aliquots of freshwater samples. The results showed nearly 100% retention at speeds below 10 mL min-1, above 80% up to 100 mL min-1, and approached 50% at 400 mL min-1. Using 100 mL min-1 flow rate and KNiFC-PAN resin in a well-type HPGe detector, the minimum detectable concentration was reduced to 3 mBq kg-1 for 4-L aliquots of water samples from the previous 15 mBq kg-1 achieved by Powdex ion-exchange resin and a planar type HPGe detector.

Gross alpha and gross beta activities in selected marine species in Vietnam.

The measured gross alpha and gross beta activities in the edible muscle tissues of eleven selected marine species along the coast of North Vietnam varied from 10.2 ± 1.5 to 73.2 ± 8.1 Bq/kg (wwt) and from 10.6 ± 0.4 to 68.8 ± 2.8 Bq/kg (wwt), respectively. The lowest gross alpha activity was recorded for bigfin reef squid (Sepioteuthis lessoniana) as a result of its carnivorous diet, and the highest alpha activity was noted for blood cockle (Anadara granosa) as a result of its omnivorous diet. However, the gross beta activities in both carnivorous and omnivorous species were similar. The highest and lowest gross beta activities were observed for narrow-barred Spanish mackerel (Scomberomorus commerson) and for bigfin reef squid and squid (Teuthida), respectively. All three aforementioned species have carnivorous diets. The calculated annual committed effective dose resulting from the consumption of 25 kg of muscle tissue per year varied from 192 to 1375 µS with an average of 689 µS.

Numerical modeling of the sources and behaviors of 222Rn, 220Rn and their progenies in the indoor environment-A review.

222Rn, 220Rn and their short-lived progenies are well known radioactive indoor pollutants, identified as the leading environmental cause of lung cancer next to smoking. Apart from the conventional measurement methods, numerical modeling methods are developed to simulate their physical and decay processes in 222Rn and 220Rn's life cycle, estimate their levels, concentration distributions, as well as effects of control strategies in the indoor environment. In this article, we summarized the numerical models used to illustrate the physical processes of each source of 222Rn and 220Rn entry into the indoor environment, and the application of Jacobi room models and CFD (Computational Fluid Dynamic) models used to present the behaviors of indoor 222Rn, 220Rn and their progenies. Furthermore, we consider that the development of numerical modeling of 222Rn and 220Rn would have a bright prospect in the directions of stochastic methods based on a steady-state model, the fine simulation of the time-dependent model as well as the multi-dimension model.

Mobility of 232Th and 210Po in red mud.

The valorization of industrial by-products such as red mud became a tempting opportunity, but the understanding of the risks involved is required for the safe utilization of these products. One of the risks involved are the elevated levels of radionuclides (in the 100-1300 Bq/kg range for both the 238U and 232 Th decay chains, but usually lower than 1000 Bq/kg, which is the recommended limit for excemption or clearance according to the EU BSS released in 2013) in red mud that can affect human health. There is no satisfactory answer for the utilization of red mud; the main current solution is still almost exclusively disposal into a landfill. For the safe utilization and deposition of red mud, it is important to be able to assess the leaching behaviour of radionuclides. Because there is no commonly accepted measurement protocol for testing the leaching of radionuclides in the EU a combined measurement protocol was made and tested based on heavy metal leaching methods. The leaching features of red mud were studied by methods compliant with the MSZ-21470-50 Hungarian standard, the CEN/TS 14429 standard and the Tessier sequential extraction method for 232Th and 210Po. The leached solutions were taken to radiochemical separation followed by spontaneous deposition for Po and electrodeposition for Th. The 332 ±â€¯33 Bq/kg 232Th content was minimally mobile, 1% became available for distilled water 1% and 6% for Lakanen-Erviö solution; the Tessier extraction showed minimal mobility in the first four steps, while more than 85% remained in the residue. The 210Po measurements had a severe disturbing effect in many cases, probably due to large amounts of iron present in the red mud, from the 310 ±â€¯12 Bq/kg by aqua regia digestion, distilled water mobilized 23%, while Lakanen-Erviö solution mobilized ∼13%. The proposed protocol is suitable for the analysis of Th and Po leaching behaviour.

Study of a remediated coal ash depository from a radiological perspective.

Coal-fired power plants play a significant role in the production of electricity. The Ra-226 concentration of coals mined in the Ajka region can reach up to 3000 Bq/kg. This study focuses on the effects of a Hungarian (Ajka) remediated coal ash depository on the environment and the effectiveness of the cover layer. During the remediation, a method patented in Hungary was used, in which the upper layer of the depository, which had settled like concrete, was ploughed and mixed with woodchips before being planted with vegetation. The gamma dose rate H*(10) of the depository and its vicinity was measured using Automess 6150AD-b at 32 points, surface Rn-222 exhalation at 19 points and air radon concentration at 34 points; at 32 points, soil gas radon content was measured with AlphaGUARD and soil permeability with RADON-JOK. The nuclide content of nine samples was determined using an HPGe gamma spectrometer and their Rn-222 exhalation rates were measured using the AlphaGUARD. H*(10) was 290 (130-525) nSv/h at the covered depository; CRa-226 was 1997 Bq/kg, 960 Bq/kg and 104 Bq/kg for the ash, cover layer and background soil respectively. CRn-222 in the soil was 25-161 kBq/m3, and soil gas permeability K was between 6.4E-13 and 1.80E-11 m2. The radon exhalation of the uncovered and covered depository was 259-1100 mBq/m2s. The exhalation and emanation coefficients of the samples were 0.05-0.32 mBq/kgs and 8-22%. The effects of vegetation on the migration of radon were also examined. The results show that the Ajka coal ash depository involves higher radiological risk than that reported by previously published studies on depositories. The applied cover layer halved the field radon exhalation; in addition, the vegetation reduced the convective airflow and, with this, the migration of Rn.

Radiological investigation of phosphate fertilizers: Leaching studies.

The raw materials of the phosphate fertilizer industry are the various apatite minerals. Some of these have high levels of natural radionuclides, and thus phosphate fertilizers contain significant amounts of U-238, K-40 and Ra-226. These can leach out of the fertilizers used in large quantities for resupplying essential nutrients in the soil and can then enter the food chain through plants, thereby increasing the internal dose of the affected population. In the current study, the radiological risk of eight commercially available phosphate fertilizers (superphosphate, NPK, PK) and their leaching behaviours were investigated using different techniques (gamma and alpha spectrometry), and the dose contributions of using these fertilizers were estimated. To characterize the leaching behaviour, two leaching procedures were applied and compared -the MSZ 21470-50 (Hungarian standard) and the Tessier five-step sequential extraction method. Based on the evaluation of the gamma-spectra, it is found that the level of Th-232 in the samples was low (max.7 ± 6 Bq kg-1), the average Ra-226 activity concentration was 309 ± 39 Bq kg-1 (min. 10 ± 8 Bq kg-1, max. 570 ± 46 Bq kg-1), while the K-40 concentrations (average 3139 ± 188 Bq kg-1, min. 51 ± 36 Bq kg-1) could be as high as 7057 ± 427 Bq kg-1. The high K-40 can be explained by reference to the composition of the investigated fertilizers (NPK, PK). U concentrations were between 15 and 361 Bq kg-1, with the average of 254 Bq kg-1, measured using alpha spectrometry. The good correlation between P2O5 content and radioactivity reported previously is not found in our data. The leaching studies reveal that the mobility of the fertilizer's uranium content is greatly influenced by the parameters of the leaching methods. The availability of U to water ranged between 3 and 28 m/m%, while the Lakanen-Erviö solution mobilized between 10 and 100% of the U content.

Radiological characterization of clay mixed red mud in particular as regards its leaching features.

The reuse of industrial by-products such as red mud is of great importance. In the case of the building material industry the reuse of red mud requires a cautious attitude, since the enhanced radionuclide content of red mud can have an effect on human health. The natural radionuclide content of red mud from the Ajka red mud reservoir and the clay sample from a Hungarian brick factory were determined by gamma spectrometry. It was found that maximum 27.8% red mud content can be added to fulfil the conditions of the EU-BSS. The effect of heat treatment was investigated on a red mud-clay mixture and it was found that in the case of radon and thoron exhalation the applied heat reduced remarkably the exhalation capacities. The leaching features of red mud and different mixtures were studied according to the MSZ-21470-50 Hungarian standard, the British CEN/TS 14429 standard and the Tessier sequential extraction method. The Tessier method and the MSZ-21470-50 standard are suitable for the characterization of materials; however, they do not provide enough information for waste deposition purposes. To this end, we propose using the CEN/TS 14429 method, because it is easy to use, and gives detailed information about the material's behaviour under different pH conditions, however, further measurements are necessary.