Changing the Emission Properties of Phosphorescent C

Cyclometalated thiazol-2-ylidene platinum(II) complexes based on the N-phenyl-4,5-dimethyl-1,3-thiazol-2-ylidene N-heterocyclic carbene (NHC) ligand and seven different ß-diketonate ligands have been synthesised and investigated for their structural and photophysical properties. The complexes were synthesised in a one-pot procedure starting with the in situ formation of the corresponding silver(I) carbene and transmetalation to platinum, followed by the reaction with the respective ß-diketonate under basic conditions. All the compounds were fully characterised by standard techniques, including 195 Pt NMR spectroscopy. Three solid-state structures revealed quite different aggregation behaviour depending on the ß-diketonate architecture. The reported complexes showed strong phosphorescence at room temperature in amorphous poly(methyl methacrylate) films. The emission wavelengths (ca. 510 nm) were found to be independent of the ß-diketonate ligand, but the electronically diverse ß-diketonates strongly influence the observed quantum yields (QY) and decay lifetimes. The results of theoretical studies employing density functional theory (DFT) methods support the conclusion of a metal-to-ligand charge transfer (3 MLCT) as the main emission process, in accordance with the reported photophysical properties. Standard organic light-emitting diodes (OLEDs) prepared with unoptimised matrix materials using one of the complexes showed values of 12.3 % external quantum yield, 24.0 lm W-1 luminous efficacy and 37.8 cd A-1 current efficiency at 300 cd m-2 .

Optical properties of pentacene and perfluoropentacene thin films.

The optical properties of pentacene (PEN) and perfluoropentacene (PFP) thin films on various SiO(2) substrates were studied using variable angle spectroscopic ellipsometry. Structural characterization was performed using x-ray reflectivity and atomic force microscopy. A uniaxial model with the optic axis normal to the sample surface was used to analyze the ellipsometry data. A strong optical anisotropy was observed, and enabled the direction of the transition dipole of the absorption bands to be determined. Furthermore, comparison of the optical constants of PEN and PFP thin films with the absorption spectra of the monomers in solution shows significant changes due to the crystalline environment. Relative to the monomer spectrum, the highest occupied molecular orbital to lowest unoccupied molecular orbital transition observed in PEN (PFP) thin film is reduced by 210 meV (280 meV). A second absorption band in the PFP thin film shows a slight blueshift (40 meV) compared to the spectrum of the monomer with its transition dipole perpendicular to that of the first absorption band.