Sensitivity Improvement of Multi-Slot Subwavelength Bragg Grating Refractive Index Sensors by Increasing the Waveguide Height or Suspending the Sensor.

We present two methods of improving wavelength sensitivity for multi-slot sub-wavelength Bragg grating (MS-SW BG) refractive index sensors. The sensor structure is designed to have high optical mode confinement in the gaps between the silicon pillars whereby the surrounding medium interaction is high, thus improving the sensitivity. Further sensitivity improvements are achieved by increasing the waveguide height or suspending the sensor. The second option, sensor suspension, additionally requires supporting modifications in which case various configurations are considered. After the optimization of the parameters the sensors were fabricated. For the case of a waveguide height increase to 500 nm, the sensitivity of 850 nm/RIU was obtained; for sensor suspension with fully etched holes, 922 nm/RIU; for the case of not fully etched holes, 1100 nm/RIU; with the sensor lengths of about 10 µm for all cases. These values show improvements by 16.5%, 25%, and 50.5%, respectively, compared to the previous result where the height was fixed to 340 nm.

Graphene-Enhanced Raman Scattering from the Adenine Molecules.

An enhanced Raman scattering from a thin layer of adenine molecules deposited on graphene substrate was detected. The value of enhancement depends on the photon energy of the exciting light. The benzene ring in the structure of adenine molecule suggests π-stacking of adenine molecule on top of graphene. So, it is proposed that the enhancement in the adenine Raman signal is explained by the resonance electron transfer from the Fermi level of graphene to the lowest unoccupied molecular orbital (LUMO) level of adenine.

Gilded nanoparticles for plasmonically enhanced fluorescence in TiO2:Sm3+ sol-gel films.

Silica-gold core-shell nanoparticles were used for plasmonic enhancement of rare earth fluorescence in sol-gel-derived TiO2:Sm3+ films. Local enhancement of Sm3+ fluorescence in the vicinity of separate gilded nanoparticles was revealed by a combination of dark field microscopy and fluorescence spectroscopy techniques. An intensity enhancement of Sm3+ fluorescence varies from 2.5 to 10 times depending on the used direct (visible) or indirect (ultraviolet) excitations. Analysis of fluorescence lifetimes suggests that the locally stronger fluorescence occurs because of higher plasmon-coupled direct absorption of exciting light by the Sm3+ ions or due to plasmon-assisted non-radiative energy transfer from the excitons of TiO2 host to the rare earth ions. PACS: 78; 78.67.-n; 78.67.Bf.