Determining the ventilation and aerosol deposition rates from routine indoor-air measurements.

Measurement of air exchange rate provides critical information in energy and indoor-air quality studies. Continuous measurement of ventilation rates is a rather costly exercise and requires specific instrumentation. In this work, an alternative methodology is proposed and tested, where the air exchange rate is calculated by utilizing indoor and outdoor routine measurements of a common pollutant such as SO2, whereas the uncertainties induced in the calculations are analytically determined. The application of this methodology is demonstrated, for three residential microenvironments in Athens, Greece, and the results are also compared against ventilation rates calculated from differential pressure measurements. The calculated time resolved ventilation rates were applied to the mass balance equation to estimate the particle loss rate which was found to agree with literature values at an average of 0.50 h(-1). The proposed method was further evaluated by applying a mass balance numerical model for the calculation of the indoor aerosol number concentrations, using the previously calculated ventilation rate, the outdoor measured number concentrations and the particle loss rates as input values. The model results for the indoors' concentrations were found to be compared well with the experimentally measured values.

Issues related to aircraft take-off plumes in a mesoscale photochemical model.

The physical and chemical characteristics of aircraft plumes at the take-off phase are simulated with the mesoscale CAMx model using the individual plume segment approach, in a highly resolved domain, covering the Athens International Airport. Emission indices during take-off measured at the Athens International Airport are incorporated. Model predictions are compared with in situ point and path-averaged observations (NO, NO2) downwind of the runway at the ground. The influence of modeling process, dispersion properties and background air composition on the chemical evolution of the aircraft plumes is examined. It is proven that the mixing properties mainly determine the plume dispersion. The initial plume properties become significant for the selection of the appropriate vertical resolution. Besides these factors, the background NOx and O3 concentration levels control NOx distribution and their conversion to nitrogen reservoir species.

Temporal evolution of the main processes that control indoor pollution in an office microenvironment: a case study.

The aim of this study is to examine the relative contribution of the outdoor concentration, the ventilation rate, the geometric characteristics of the indoor environment (i.e., extent of indoor surfaces and indoor volume), the deposition, and chemical reactions to the indoor air quality of the office microenvironment. For this case study, the NO, NO2, and O3 concentrations indoors and outdoors and TVOCs and CO2 concentrations indoors were measured in an office microenvironment in Athens, Greece, that was ventilated both naturally and mechanically. The calculated ventilation and loss rates and the measured outdoor concentrations of NO, NO2, and O3 were set as input to Multi-chamber Indoor Air Quality Model in order to study the temporal variation of the indoor NO, NO2, and O3 concentrations. Results showed that when the ventilation rate and outdoor concentration are high, the relative contribution of the transport process contributes significantly, while the chemical process depends on the contemporary interplay between the indoor O3, NO, and NO2 concentrations and lighting levels. The significance of each process was further examined by performing sensitivity tests, and it was found that the most important parameters were the deposition velocities, the UV infiltration rates (which determines the indoor chemical reaction rates), the ventilation rates, and the filtration (when a mechanical ventilation system is used). The effect of the hydrocarbon chemistry was not significant.

Indoor air quality assessment in the air traffic control tower of the Athens Airport, Greece.

In this study, an assessment of indoor air quality (IAQ) and thermal comfort in the Athens Traffic Control Tower (ATCT) offices of Hellinicon building complex, which is mechanically ventilated, is presented. Measurements of PM(10), PM(2.5), TVOCs and CO(2) concentrations were performed during three experimental cycles, while the Thom Discomfort Index was calculated to describe the employees' feeling of discomfort. The aim of the first cycle was to identify the IAQ status, the second to investigate the effectiveness of certain measures taken, and the third to continuously monitor and control IAQ. During the first two cycles, daily spot measurements of TVOCs and CO(2) were performed at various indoor locations and at the respective outdoor air intake positions, in addition with mean 24-h spot measurements of indoor PM(10) and PM(2.5). Results revealed that pollution levels vary according to the occupancy and the kind of activity. Following that, an automated system (IMAS) was designed and employed to continuously monitor indoor and outdoor CO(2), TVOCs, temperature and relative humidity. The ultimate scope was to control the IAQ and offer acceptable comfort conditions to the employees, whose work is of special nature and extremely demanding. Intervention scenarios were formulated and applied to the system to improve indoor conditions, when and where necessary. Regarding the third cycle, 1-year measurements collected from the system to examine its effectiveness. While it was shown that discomfort may be attributed to co-existence of unsatisfactory thermal comfort conditions and IAQ, usually the sole predominant factor of discomfort feeling is thermal comfort.

On the estimation of characteristic indoor air quality parameters using analytical and numerical methods.

Indoor exposure to air contaminants penetrating from the outdoor environment depends on a number of key processes and parameters such as the ventilation rate, the geometric characteristics of the indoor environment, the outdoor concentration and the indoor removal mechanisms. In this study two alternative methods are used, an analytical and a numerical one, in order to study the time lag and the reduction of the variances of the indoor concentrations, and to estimate the deposition rate of the air contaminants in the indoor environment employing both indoor and outdoor measurements of air contaminants. The analytical method is based on a solution of the mass balance equation involving an outdoor concentration pulse which varies sinusoidally with the time, while the numerical method involves the application of the MIAQ indoor air quality model assuming a triangular pulse. The ratio of the fluctuation of the indoor concentrations to the outdoor ones and the time lag were estimated for different values of the deposition velocity, the ventilation rate and the duration of the outdoor pulse. Results have showed that the time lag between the indoor and outdoor concentrations is inversely proportional to the deposition and ventilation rates, while is proportional to the duration of the outdoor pulse. The decrease of the ventilation and the deposition rate results in a rapid decrement of the variance ratio of indoor to outdoor concentrations and to an increment of the variance ratio, respectively. The methods presented here can be applied for gaseous species as well as for particulate matter. The nomograms and theoretical relationships that resulted from the simulation results and the analytical methods respectively were used in order to study indoor air phenomena. In particular they were used for the estimation of SO2 deposition rate. Implications of the studied parameters to exposure studies were estimated by calculating the ratio of the indoor exposure to the exposure outdoors. Limitations of the methods were explored by testing various scenarios which are usually met in the indoor environment. Strong indoor emissions, intense chemistry and varying ventilation rates (opening and closing of the windows) were found to radically influence the time lag and fluctuation ratios.

An experimental study of aerosol distribution over a Mediterranean urban area.

In this study an attempt is made to investigate the aerosol spatial and size distributions at different heights over the Greater Athens Area (GAA), Greece, under sea breeze conditions and clear sky and to further discuss possible implications for aerosol characteristics. The data used are airborne measurements of aerosol collected during two flights that were performed within the context of the 1997 STAAARTE experimental campaign. The aerosol measurements cover particle diameters from 0.1 to 45.5 microm. The horizontal and vertical distribution revealed that higher concentrations exist within or just above the atmospheric boundary layer, while greater concentrations are observed over the sea compared to land at high altitudes. At all altitudes the number size distributions show dominant diameter ranges between 0.1 and 0.3 microm at all altitudes. The volume distributions are characterised by two modes, one in the accumulation and the other in the coarse particle regime. At lower altitudes, fresh combustion emissions more likely cause the predominance of the size range 0.1-0.3 microm while enhanced physical and chemical processes that favour the growth of smaller particles to larger sizes could also act. The relative humidity does not seem to affect the observed number size distributions at low altitudes, where relative humidity is below 70% while at 4000 m the distributions seem to change over the sea where the humidity increases.

Investigating cigarette-smoke indoor pollution in a controlled environment.

The objective of this study was to investigate the evolution of pollutant concentrations generated by smoking in a controlled indoor environment. For this purpose, a small flat in the centre of Athens, Greece was equipped with NO(x), O(3) and SO(2) continuous measuring instruments and portable analysers for spot measurements of TVOCs and CO(2), while two volunteer smokers remained inside and smoked as normal inhabitants. The results indicated that when windows are kept closed and smoking takes place NO(x), CO(2) and TVOCs concentrations increase by an order of 3, 4 or 10 times, respectively, and decrease returning to initial levels after 1 or 2 h.