1.
Anal Chem
; 57(6): 1096-100, 1985 May.
Article
in English
| MEDLINE
| ID: mdl-4014698
2.
Talanta
; 28(1): 1-6, 1981 Jan.
Article
in English
| MEDLINE
| ID: mdl-18962847
ABSTRACT
A digitized fluorescence spectrum containing n points may be considered as a vector in n-dimensional space. This concept is used to develop a vector model employing angular distance in n-space as parameter for comparison of fluorescence spectra of weathered oil. The vector model is applied to the problem of forensic oil-identification, by comparing the spectra of oil-spill samples with the spectra of unweathered and laboratory-weathered oils through likely suspects. The vector representing the oil-spill spectrum is projected on the hyperlane formed by the spectra of the unweathered and corresponding laboratory-weathered oils to locate the vector which has the smallest angular deviation from the spill vector ("best fit").