Rapid vertical exchange at fronts in the Northern Gulf of Mexico.

Over the Texas-Louisiana Shelf in the Northern Gulf of Mexico, the eutrophic, fresh Mississippi/Atchafalaya river plume isolates saltier waters below, supporting the formation of bottom hypoxia in summer. The plume also generates strong density fronts, features of the circulation that are known pathways for the exchange of water between the ocean surface and the deep. Using high-resolution ocean observations and numerical simulations, we demonstrate how the summer land-sea breeze generates rapid vertical exchange at the plume fronts. We show that the interaction between the land-sea breeze and the fronts leads to convergence/divergence in the surface mixed layer, which further facilitates a slantwise circulation that subducts surface water along isopycnals into the interior and upwells bottom waters to the surface. This process causes significant vertical displacements of water parcels and creates a ventilation pathway for the bottom water in the northern Gulf. The ventilation of bottom water can bypass the stratification barrier associated with the Mississippi/Atchafalaya river plume and might impact the dynamics of the region's dead zone.

Surface Water CO2 variability in the Gulf of Mexico (1996-2017).

Approximately 380,000 underway measurements of sea surface salinity, temperature, and carbon dioxide (CO2) in the Gulf of Mexico (GoM) were compiled from the Surface Ocean CO2 Atlas (SOCAT) to provide a comprehensive observational analysis of spatiotemporal CO2 dynamics from 1996 to 2017. An empirical orthogonal function (EOF) was used to derive the main drivers of spatial and temporal variability in the dataset. In open and coastal waters, drivers were identified as a biological component linked to riverine water, and temperature seasonality. Air-sea flux estimates indicate the GoM open (- 0.06 ± 0.45 mol C m-2 year-1) and coastal (- 0.03 ± 1.83 mol C m-2 year-1) ocean are approximately neutral in terms of an annual source or sink for atmospheric CO2. Surface water pCO2 in the northwest and southeast GoM open ocean is increasing (1.63 ± 0.63 µatm  year-1 and 1.70 ± 0.14 µatm year-1, respectively) at rates comparable to those measured at long-term ocean time-series stations. The average annual increase in coastal CO2 was 3.20 ± 1.47 µatm year-1 for the northwestern GoM and 2.35 ± 0.82 µatm year-1 for the west Florida Shelf. However, surface CO2 in the central (coastal and open) GoM, which is influenced by Mississippi and Atchafalaya River outflow, remained fairly stable over this time period.

Texas and Louisiana coastal vulnerability and shelf connectivity.

A numerical study of connectivity between the continental shelf and coast in the northwestern Gulf of Mexico using a circulation model and surface-limited numerical drifters shows that despite seasonal changes in winds, the overall connectivity of the shelf with the coastline is similar in the winter and summer, though it extends more offshore in Texas in summer. However, there is a spatial pattern to the connectivity: more of the inner shelf is connected with the coast in Texas as compared with Louisiana. Subsets of the coast do have seasonal variability: the coast near both Galveston and Port Aransas has more connectivity from upcoast in the winter and from offshore and downcoast in the summer. In both seasons, we find drifters reach the Port Aransas coast most frequently, with a stronger trend in the summer. These results are important for assessing likely pathways for spilled oil and other potentially hazardous material.

Efficient tools for marine operational forecast and oil spill tracking.

Ocean forecasting and oil spill modelling and tracking are complex activities requiring specialised institutions. In this work we present a lighter solution based on the Operational Ocean Forecast Python Engine (OOFε) and the oil spill model General NOAA Operational Modelling Environment (GNOME). These two are robust relocatable and simple to implement and maintain. Implementations of the operational engine in three different regions with distinct oceanic systems, using the ocean model Regional Ocean Modelling System (ROMS), are described, namely the Galician region, the southeastern Brazilian waters and the Texas-Louisiana shelf. GNOME was able to simulate the fate of the Prestige oil spill (Galicia) and compared well with observations of the Krimsk accident (Texas). Scenarios of hypothetical spills in Campos Basin (Brazil) are illustrated, evidencing the sensitiveness to the dynamical system. OOFε and GNOME are proved to be valuable, efficient and low cost tools and can be seen as an intermediate stage towards more complex operational implementations of ocean forecasting and oil spill modelling strategies.