1.
Chemistry
; 27(7): 2342-2347, 2021 Feb 01.
Article
in English
| MEDLINE
| ID: mdl-32902879
ABSTRACT
A thermally stable carbocationic covalent organic network (CON), named RIO-70 was prepared from pararosaniline hydrochloride, an inexpensive dye, and triformylphloroglucinol in solvothermal conditions. This nanoporous organic material has shown a specific surface area of 990â m2 g-1 and pore size of 10.3â Å. The material has CO2 uptake of 2.14â mmol g-1 (0.5â bar), 2.7â mmol g-1 (1â bar), and 6.8â mmol g-1 (20â bar), the latter corresponding to 3 CO2 molecules adsorbed per pore per sheet. It is shown to be a semiconductor, with electrical conductivity (σ) of 3.17×10-7 â S cm-1 , which increases to 5.26×10-4 â S cm-1 upon exposure to I2 vapor. DFT calculations using periodic conditions support the findings.