ABSTRACT
Herein, we have characterized in depth the effect of femtosecond (fs)-laser writing on various polydimethylsiloxane (PDMS)-based composites. The study combines systematic and nanoscale characterizations for the PDMS blends that include various photoinitiators (organic and inorganic agents) before and after fs-laser writing. The results exhibit that the photoinitiators can dictate the mechanical properties of the PDMS, in which Young's modulus of PDMS composites has higher elasticity. The study illustrates a major improvement in refractive index change by 15 times higher in the case of PDMS/BP-Ge [benzophenone (BP) allytriethylgermane] and Irgacure 184. Additional enhancement was achieved in the optical performance levels of the PDMS composites (the PDMS composites of Irgacure 184/500, BP-Ge, and Ge-ATEG have a relative difference of less than 5% in comparison with pristine PDMS), which are on par with glasses. This insightful study can guide future investigators in choosing photoinitiators for particular applications in photonics and polymer chemistry.
ABSTRACT
We report the structural and optical properties of Nd:YAB (NdxY1-x Al3(BO3)4)-nanoparticle-doped PDMS elastomer films for random lasing (RL) applications. Nanoparticles with Nd ratios of x = 0.2, 0.4, 0.6, 0.8, and 1.0 were prepared and then incorporated into the PDMS elastomer to control the optical gain density and scattering center content over a wide range. The morphology and thermal stability of the elastomer composites were studied. A systematic investigation of the lasing wavelength, threshold, and linewidth of the laser was carried out by tailoring the concentration and optical gain of the scattering centers. The minimum threshold and linewidth were found to be 0.13 mJ and 0.8 nm for x = 1 and 0.8. Furthermore, we demonstrated that the RL intensity was easily tuned by controlling the degree of mechanical stretching, with strain reaching up to 300%. A strong, repeatable lasing spectrum over ~ 50 cycles of applied strain was observed, which demonstrates the high reproducibility and robustness of the RL. In consideration for biomedical applications that require long-term RL stability, we studied the intensity fluctuation of the RL emission, and confirmed that it followed Lévy-like statistics. Our work highlights the importance of using rare-earth doped nanoparticles with polymers for RL applications.
