Near-source hypochlorous acid emissions from indoor bleach cleaning.

Cleaning surfaces with sodium hypochlorite (NaOCl) bleach can lead to high levels of gaseous chlorine (Cl2) and hypochlorous acid (HOCl); these have high oxidative capacities and are linked to respiratory issues. We developed a novel spectral analysis procedure for a cavity ring-down spectroscopy (CRDS) hydrogen peroxide (H2O2) analyzer to enable time-resolved (3 s) HOCl quantification. We measured HOCl levels in a residential bathroom while disinfecting a bathtub and sink, with a focus on spatial and temporal trends to improve our understanding of exposure risks during bleach use. Very high (>10 ppmv) HOCl levels were detected near the bathtub, with lower levels detected further away. Hypochlorous acid concentrations plateaued in the room at a level that depended on distance from the bathtub. This steady-state concentration was maintained until the product was removed by rinsing. Mobile experiments with the analyzer inlet secured to the researcher's face were conducted to mimic potential human exposure to bleach emissions. The findings from mobile experiments were consistent with the spatial and temporal trends observed in the experiments with fixed inlet locations. This work provides insight on effective strategies to reduce exposure risk to emissions from bleach and other cleaning products.

Development of a Monitoring System for Semicontinuous Measurements of Stable Carbon Isotope Ratios in Atmospheric Carbonaceous Aerosols: Optimized Methods and Application to Field Measurements.

Carbon content constitutes a major fraction of atmospheric particulate matter (PM) and directly influences the earth's climate and human health. The stable carbon isotope ratios (δ13C) can be used to track potential sources and atmospheric processes of carbonaceous aerosols. Previously, determination of δ13C was always conducted in offline carbonaceous aerosol samples. The poor time-resolution results cannot provide information regarding the temporal evolution of δ13C at a short-time scale. In this study, we developed a new system for online measurements of δ13C in atmospheric carbonaceous aerosols by combining a semicontinuous organic carbon/elemental carbon (OC/EC) analyzer and online cavity ring-down spectroscopy (CRDS) (OC/EC analyzer-CRDS). To provide better stability in the determination of δ13C, a carrier gas with CO2 (∼200 ppm) in "balance gas" was used, and Keeling analysis was employed to separate the δ13C signal of the sample from background CO2 gas. Our results showed that the accuracy and absolute precision of the δ13C measurements by the OC/EC analyzer-CRDS system were better than 0.1‰ and 0.5‰, respectively, for the samples containing carbon content more than 5 µg. Furthermore, we employed this system to monitor δ13C (δ13C-TC) in particulate total carbon (TC) with a time resolution of 2-4 h over Beijing in late summer and early autumn, 2019. During the sampling period, the TC concentrations varied from 0.1 to 12.0 µg m-3 with a mean value of 6.0 ± 2.4 µg m-3. The δ13C-TC ranged from -28.2 to -24.2‰ (mean value was -25.9 ± 0.9‰) without significant diurnal variations, suggesting similar contributing sources to TC. Comparing the δ13C signatures of different emissions, we found that liquid fuels and primary and secondary C3 plants were likely the dominant sources of particulate TC. Finally, we found that atmospheric heavy precipitation washed out the aged aerosols from the polluted air, resulting in significant depletion (∼2.4‰) of δ13C-TC in the atmosphere. This paper described a novel system for conducting online measurements of δ13C in atmospheric carbonaceous aerosols and provided us information to better understand the temporal evolution of emission sources and atmospheric processes of carbonaceous aerosols.

Refracting the k-function: Stavroudis's solution to the eikonal equation for multielement optical systems.

The k-function of Stavroudis describes a solution of the eikonal equation in a region of constant refractive index. Given the k-function describing the optical field in one region of space, and given a prescribed refractive or reflective boundary, we construct the k-function for the refracted or reflected field. This procedure, which Stavroudis calls refracting the k-function, can be repeated any number of times, and therefore extends the usefulness of the k-function formalism to multielement optical systems. As examples, we present an analytic solution for the k-function, wavefronts, and caustics generated by a biconvex thick lens illuminated by a plane wave propagating parallel to the symmetry axis, and numerical results for off-axis plane-wave illumination of a two-mirror telescope.

Wavefront and caustics of a plane wave refracted by an arbitrary surface.

A simple expression is given for the k-function associated with the general solution of Stavroudis to the eikonal equation for refraction or reflection of a plane wave from an arbitrary surface. Using this result, we specialize the solution to derive analytic expressions for the wavefront and caustic surfaces after refraction of a plane wave from any rotationally symmetric surface. The method is applied to evaluating and comparing the wavefront and caustic surfaces formed both by a planospherical lens and a planoaspheric lens used for laser beam shaping, which provides understanding of how the irradiance is redistributed over a beam as the wavefront folds back on itself within the focal region.

Laser beam shaping profiles and propagation.

We consider four families of functions--the super-Gaussian, flattened Gaussian, Fermi-Dirac, and super-Lorentzian--that have been used to describe flattened irradiance profiles. We determine the shape and width parameters of the different distributions, when each flattened profile has the same radius and slope of the irradiance at its half-height point, and then we evaluate the implicit functional relationship between the shape and width parameters for matched profiles, which provides a quantitative way to compare profiles described by different families of functions. We conclude from an analysis of each profile with matched parameters using Kirchhoff-Fresnel diffraction theory and M2 analysis that the diffraction patterns as they propagate differ by small amounts, which may not be distinguished experimentally. Thus, beam shaping optics is designed to produce either of these four flattened output irradiance distributions with matched parameters will yield similar irradiance distributions as the beam propagates.