ABSTRACT
Nanoporous carbons are very attractive for various applications including energy storage. Templating methods with assembled amphiphilic molecules or porous inorganic templates are typically used for the synthesis. Amongst the different members of this family, CMK-5-like structures that are constructed to consist of sub-10 nm amorphous carbon nanotubes and ultrahigh specific surface area due to their thin pore walls, have the best properties in various respects. However, the fabrication of such hollow-structured mesoporous carbons entails elaborately tailoring the surface properties of the template pore walls and selecting specific carbon precursors. Thus, very limited cases are successful. Herein, a versatile and general silanol-assisted surface-casting method to create hollow-structured mesoporous carbons and heteroatom-doped derivatives with numerous organic molecules (e.g., furfuryl alcohol, resol, 2-thiophene methanol, dopamine, tyrosine) and different structural templates is reported. These carbon materials exhibit ultrahigh surface area (2400 m2 g-1 ), large pore volume (4.0 cm3 g-1 ), as well as satisfactory lithium-storage capacity (1460 mAh g-1 at 0.1 A g-1 ), excellent rate capability (320 mAh g-1 at 5 A g-1 ), and very outstanding cycling performance (2000 cycles at 5 A g-1 ).
ABSTRACT
Transition-metal sulfides are promising electrochemical energy storage materials due to their abundant active sites, large interlayer space, and high theoretical capacities, especially for sodium storage. However, the low conductivity and poor cycling stability at high current densities hamper their applications. Herein, a versatile dual-template method is reported to elaborate ordered mesoporous single-layered MoS2 /carbon composite with high specific area, uniform pore size, and large pore volume. The single-layered MoS2 is confined in the carbon matrix. The mesopores between the composite nanorods provide fast electrolyte diffusion. The obtained nanocomposite shows a high sodium-storage capability, excellent rate capacity, and very good cycling performance. A capacity of 310 mAh g-1 can remain at 5.0 A g-1 after 2500 cycles. Furthermore, a sodium-ion battery (SIB) full cell composed of the MoS2 /carbon composite anode and a Na3 V2 (PO4 )3 (NVP) cathode maintains a specific capacity of 330 mAh g-1 at 1.0 A g-1 during 100 cycles. The mechanism is investigated by in situ and ex situ characterizations as well as density functional theory (DFT) calculations.
