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Formal Total Synthesis of (+)-C9-Deoxyomuralide from l-Leucine Using a Double Sacrificial Chirality Transfer Approach.
Bulman Page, Philip C; Goodyear, Ross L; Horton, Alexandra E; Chan, Yohan; Karim, Rehana; O'Connell, Maria A; Hamilton, Christopher; Slawin, Alexandra M Z; Buckley, Benjamin R; Allin, Steven M.
J Org Chem ; 82(23): 12209-12223, 2017 12 01.
Article in English | MEDLINE | ID: mdl-29111711

ABSTRACT

Formal stereocontrolled syntheses of (±)- and (+)-C9-deoxyomuralide is reported, constituting one of the shortest routes to the full carbon skeleton reported to date.


Subject(s)
Leucine/chemistry , Molecular Structure , Stereoisomerism
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