1.
Dalton Trans
; 48(39): 14606-14610, 2019 Oct 07.
Article
in English
| MEDLINE
| ID: mdl-31549112
ABSTRACT
The synthesis and structural analyses of pincer-type iridium complexes having gallyl- and indyl-metalloligands were achieved utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal-metal bonds. A BH3-coordinated PInP-Ir dihydride complex was also developed as an equivalent to an iridium dihydride complex, which could be a useful catalyst for synthetic reactions.