Theoretical Investigation of Spectroscopic Properties of the Alkaline-Earth-Metal Monohydrides toward Laser Cooling and Magneto-Optical Trapping.

Alkaline-earth-metal monohydrides MH (M = Be, Mg, Ca, Sr, Ba) have long been regarded as promising candidates toward laser cooling and trapping; however, their rich internal level structures that are amenable to magneto-optical trapping have not been completely explored. Here, we first systematically evaluated Franck-Condon factors of these alkaline-earth-metal monohydrides in the A2Π1/2 ← X2Σ+ transition, exploiting three respective methods (the Morse potential, the closed-form approximation, and the Rydberg-Klein-Rees method). The effective Hamiltonian matrix was introduced for MgH, CaH, SrH, and BaH individually in order to figure out their molecular hyperfine structures of X2Σ+, the transition wavelengths in the vacuum, and hyperfine branching ratios of A2Π1/2(J' = 1/2,+) ← X2Σ+(N = 1,-), followed by possible sideband modulation proposals to address all hyperfine manifolds. Lastly, the Zeeman energy level structures and associated magnetic g factors of the ground state X2Σ+(N = 1,-) were also presented. Our theoretical results here not only shed more light on the molecular spectroscopy of alkaline-earth-metal monohydrides toward laser cooling and magneto-optical trapping but also can contribute to research in molecular collisions involving few-atom molecular systems, spectral analysis in astrophysics and astrochemistry, and even precision measurement of fundamental constants such as the quest for nonzero detection of electron's electric dipole moment.

High resolution spectroscopic measurement of 130Te2: Reference lines near 444.4 nm for eEDM experiment using PbF molecules.

Molecular tellurium (Te2) offers a wide range of potential applications, including frequency reference. Spectroscopic results about the 130Te2 spectrum were previously reported, but few lines lie around the PbF transition of A (2Σ+) (υ' = 0) â† X12Π1/2 (υ = 0) (∼444.4 nm) which is regarded as an eEDM (electron's Electric Dipole Moment) sensitive transition. Here electronic transition lines for 130Te2 were determined using the Saturated Absorption Spectroscopy method, where the origin of the transition band was investigated for the B1 (3Σu-)0u+ (υ' = 10) â† X1 (3Σg-)0g+ (υ = 5) transition. The Dunham model with high orders was utilized to assign these transition lines, while Dunham parameters of the excited state B1 (υ' = 10) were updated to a new level. The Toptica TA-SHG Pro laser was then locked to a single absorption line using a P-I servo. Our results here not only provide the assigned atlas of Te2 spectrum near 444.4 nm, but also contribute to a stable and sensitive spectroscopic detection of PbF molecules toward the eEDM measurement, which is significant in understanding the fundamental physics beyond the Standard Model.

A novel molecular synchrotron for cold collision and EDM experiments.

Limited by the construction demands, the state-of-the-art molecular synchrotrons consist of only 40 segments that hardly make a good circle. Imperfections in the circular structure will lead to the appearance of unstable velocity regions (i.e. stopbands), where molecules of certain forward velocity will be lost from the structure. In this paper, we propose a stopband-free molecular synchrotron. It contains 1570 ring electrodes, which nearly make a perfect circle, capable of confining both light and heavy polar molecules in the low-field-seeking states. Molecular packets can be conveniently manipulated with this synchrotron by various means, like acceleration, deceleration or even trapping. Trajectory calculations are carried out using a pulsed (88)SrF molecular beam with a forward velocity of 50 m/s. The results show that the molecular beam can make more than 500 round trips inside the synchrotron with a 1/e lifetime of 6.2 s. The synchrotron can find potential applications in low-energy collision and reaction experiments or in the field of precision measurements, such as the searches for electric dipole moment of elementary particles.

Slowing and cooling of heavy or light (even with a tiny electric dipole moment) polar molecules using a novel, versatile electrostatic Stark decelerator.

To meet some demands for realizing precise measurements of an electric dipole moment of electron (eEDM) and examining cold collisions or cold chemical physics, we have proposed a novel, versatile electrostatic Stark decelerator with an array of true 3D electric potential wells, which are created by a series of horizontally-oriented, U-shaped electrodes with time-sequence controlling high voltages (± HV) and two guiding electrodes with a constant voltage. We have calculated the 2D electric field distribution, the Stark shifts of the four lowest rotational sub-levels of PbF molecules in the X1(2)Π1/2(v = 0) electronic and vibrational ground states as well as the population in the different rotational levels. We have discussed the 2D longitudinal and transverse phase-space acceptances of PbF molecules in our decelerator. Subsequently, we have simulated the dynamic processes of the decelerated PbF molecules using the 3D Monte-Carlo method, and have found that a supersonic PbF beam with a velocity of 300 m s(-1) can be efficiently slowed to about 5 m s(-1), which will greatly enhance the sensitivities to research a parity violation and measure an eEDM. In addition, we have investigated the dependences of the longitudinal velocity spread, longitudinal temperature and bunching efficiency on both the number of guiding stages and high voltages, and found that after bunching, a cold packet of PbF molecules in the J = 7/2, MΩ = -7/4 state with a longitudinal velocity spread of 0.69 m s(-1) (corresponding to a longitudinal temperature of 2.35 mK) will be produced by our high-efficient decelerator, which will generate a high energy-resolution molecular beam for studying cold collision physics. Finally, our novel decelerator can also be used to efficiently slow NO molecules with a tiny electric dipole moment (EDM) of 0.16 D from 315 m s(-1) to 28 m s(-1). It is clear that our proposed new decelerator has a good slowing performance and experimental feasibility as well as wide applications in the field of precise measurements and cold molecule physics.

Experimental demonstration of a controllable electrostatic molecular beam splitter.

We experimentally demonstrate a controllable electrostatic beam splitter for guided ND3 molecules with a single Y-shaped charged wire and a homogeneous bias field generated by a charged metallic parallel-plate capacitor. We study the dependences of the splitting ratio R of the guided ND3 beam and its relative guiding efficiency η on the voltage difference between two output arms of the splitter. The influences of the molecular velocity v and the cutting position L on the splitting ratio R are investigated as well, and the guiding and splitting dynamic processes of cold molecules are simulated. Our study shows that the splitting ratio R of our splitter can be conveniently adjusted from 10% to 90% by changing ΔU from -6 kV to +6 kV, and the simulated results are consistent with our experimental ones.