3D carbonized grooved straw with efficient evaporation and salt resistance for solar steam generation.

Solar steam generation (SSG) is considered an effective solution to the global shortage of freshwater resources. To solve the practical application challenges of SSG in remote outdoor environments where electricity is scarce, it is of great importance to developing new solar evaporators. In this study, a three-dimensional (3D) biochar solar evaporator based on carbonized grooved straw was prepared from agricultural waste corn straw, which had high solar energy conversion efficiency and excellent salt resistance. The existence of grooves increases the surface area to absorb more sunlight and makes the light multilevel reflection improve the evaporation rate. The excellent light absorption, super hydrophilic, and heat shielding properties of 3D carbonized grooved straw resulted in a good evaporation rate (1.57 kg⋅m-2·h-1) and energy efficiency (85.9%) under 1 sun irradiation. The 3D grooved biochar solar distiller also demonstrated efficient formation evaporation performance and excellent salt resistance in practical applications in seawater desalination and surface water purification. The 3D grooved biochar solar distiller prepared from agricultural waste has the advantages of being economical and environmentally friendly, with good application prospects.

In-situ electrodeposition synthesis of Z-scheme rGO/g-C3N4/TNAs photoelectrodes and its degradation mechanism for oxytetracycline in dual-chamber photoelectrocatalytic system.

The dual-chamber photoelectrocatalytic (PEC) system possess advantages in the degradation efficiency and processing cost of organic contaminants. In this study, TiO2 nanotube arrays modified by rGO and g-C3N4 (rGO/g-C3N4/TNAs) photoelectrodes were successfully prepared. The surface micromorphology, chemical structure, crystal structure, and basic element composition of rGO/g-C3N4/TNAs photoelectrodes were studied by SEM, FTIR, XRD, Raman, and XPS. UV-vis absorption, photoluminescence (PL) spectra, and photoelectrochemical (PECH) tests were used to explore the photoelectrochemical characteristics of rGO/g-C3N4/TNAs photoelectrodes. Under simulated sunlight illumination, the dual-chamber PEC system with external bias voltage was used to investigate the degradation of oxytetracycline (OTC) on rGO/g-C3N4/TNAs photoelectrodes. The results showed that rGO and g-C3N4 were successfully loaded on TNAs, and the separation efficiency of electrons and holes at rGO/g-C3N4/TNAs photoelectrodes was improved. The light absorption range of rGO/g-C3N4/TNAs photoelectrodes extends to the visible light region and has better light absorption performance. Compared with the photocatalytic process, when 1.2 V bias voltage was applied, the degradation efficiency of OTC in anode and cathode chambers in PEC were increased by 3.28% and 44.01% within 60 min, respectively. In addition, the anode and cathode chambers have different degradation effects on OTC. Both the external bias voltage and initial pH have significant effects in cathode chamber, but have little effect in photoanode chamber. The fluorescence excitation-emission matrix spectra and liquid chromatography-tandem mass spectrometry showed that there were different intermediates in the degradation process of OTC. This study indicated that for the dual-chamber PEC system, rGO/g-C3N4/TNAs photoelectrodes exhibited excellent photocatalytic performance and have potential application prospects in water environmental remediation.

Degradation of rifamycin from mycelial dreg by activated persulfate: Degradation efficiency and reaction kinetics.

Rifamycin mycelial dreg (RMD) is a biological waste, and its residual rifamycin (RIF) is potentially harmful to both the environment and human health. In this work, thermally activated persulfate (PDS) oxidative degradation of RIF in RMD was developed for the first time. The effects of reaction temperature, initial PDS concentration, and pH on RIF degradation in RMD were investigated, and the treatment conditions were optimized using response surface methodology (RSM). The results showed that 90 °C, 50 mg/g PDS, and pH = 5.3 were the optimal pretreatment conditions, and 100% degradation efficiency of RIF (734 mg/kg) was achieved. SEM and FTIR analyses confirmed that the RIF was destroyed and decomposed after the oxidation reaction. The possible degradation pathways of RIF in the thermally activated PDS system were discussed through HPLC/MS and ESR analyses. The intermediate product was identified, and the toxicity of the final product was predicted to be low or nontoxic. In this work, a degradation pathway of RMD was proposed by activating persulfate, which facilitates subsequent resource utilization and provides meaningful guidance for the practical treatment of antibiotic mycelium residue (AMR).

Recent advances in layered double hydroxides (LDHs) derived catalysts for selective catalytic reduction of NOx with NH3.

In recent years, layered double hydroxides (LDHs) derived metal oxides as highly efficient catalysts for selective catalytic reduction of NOx with NH3 (NH3-SCR) have attracted great attention. The high dispersibility and interchangeability of cations within the brucite-like layers make LDHs an indispensable branch of catalytic materials. With the increasingly stringent and ultra-low emission regulations, there is an urgent need for highly efficient and stable low-medium temperature denitration catalysts in markets. In this contribution, we have critically summarized the recent research progress in the LDHs derived NH3-SCR catalysts, including their ability for NOx removal, N2 selectivity, active temperature window, stability and resistance to poisoning. The advantages and defects of various types of LDHs-derived catalysts are comparatively summarized, and the corresponding modification strategies are discussed. In addition, considering the importance of the catalyst's resistance to poisoning in practical applications, we discuss the poisoning mechanism of each component in flue gases, and provide the corresponding strategies to improve the poisoning resistance of catalysts. Finally, from the perspective of practical applications and operation cost, the regeneration measures of catalysts after poisoning is also discussed. We hope that this work can give timely technical guidance and valuable insights for the applications of LDHs materials in the field of NOx control.

Trans-boundary air pollution in a city under various atmospheric conditions.

Trans-boundary air pollution (TAP) is a crucial factor affecting air quality, and its contribution may vary over time and differ under various atmospheric conditions. This study firstly applies an integrated statistical scheme to estimate the contributions of TAP and local sources to air pollutants in a city, and then investigate the influences of tropical cyclones (TC) on TAP. Hong Kong is chosen as an example because of its significant and special TAP characteristics. This study focuses on four major air pollutants, namely, respirable and fine suspended particulates (RSP/PM10 and FSP/PM2.5), sulfur dioxide (SO2), and nitrogen dioxide (NO2), from 2002 to 2013. Our results show that, on average, TAP is the major contributor of the annual RSP, FSP, SO2, and NO2 in Hong Kong. We estimate that when a TC is approaching, the increase in pollutant concentration in Hong Kong is mainly due to the increase in TAP contribution by the strengthened northerly wind at higher level of atmosphere (≥900hPa). These changes are accompanied by decreases in precipitation and increases in northerly/north-easterly wind, which may prolong the lifetime of pollutants, enhancing pollutant transport from mainland China to Hong Kong.

Resource allocation for mitigating regional air pollution-related mortality: A summertime case study for five cities in the United States.

UNLABELLED: An important issue of regional air quality management is to allocate air quality management funds to maximize environmental and human health benefits. In this study, we use an innovative approach to tackle this air quality management issue. We develop an innovative resource allocation model that allows identification of air pollutant emission control strategies that maximize mortality avoidances subject to a resource constraint. We first present the development of the resource allocation model and then a case study to show how the model can be used to identify resource allocation strategies that maximize mortality avoidances for top five Metropolitan Statistical Areas (MSAs) (i.e., New York, Los Angeles, Chicago, Dallas-Fort Worth, and Philadelphia) in the continental United States collectively. Given budget constraints in the U.S. Environmental Protection Agency's (EPA) Clean Air Act assessment, the results of the case study suggest that controls of sulfur dioxide (SO2) and primary carbon (PC) emissions from EPA Regions 2, 3, 5, 6, and 9 would have significant health benefits for the five selected cities collectively. Around 30,800 air pollution-related mortalities could be avoided during the selected 2-week summertime episode for the five cities collectively if the budget could be allocated based on the results of the resource allocation model. Although only five U.S. cities during a 2-week episode are considered in the case study, the resource allocation model can be used by decision-makers to plan air pollution mitigation strategies to achieve the most significant health benefits for other seasons and more cities over a region or the continental U.S. IMPLICATIONS: Effective allocations of air quality management resources are challenging and complicated, and it is desired to have a tool that can help decision-makers better allocate the funds to maximize health benefits of air pollution mitigation. An innovative resource allocation model developed in this study can help decision-makers identify the best resource allocation strategies for multiple cities collectively. The results of a case study suggest that controls of primary carbon and sulfur dioxides emissions would achieve the most significant health benefits for five selected cities collectively.

Optimization of multipollutant air quality management strategies: A case study for five cities in the United States.

UNLABELLED: Developing regional air quality management strategies is a difficult task because formation of air pollutants is interdependent and air quality at different locations may have different responses to emissions from common sources. We developed an optimization-based model, OPtimal integrated Emission Reduction Alternatives (OPERA), which allows for identifications of least-cost control strategies for attaining multipollutant air quality targets at multiple locations simultaneously. To implement OPERA, first, sensitivities of air quality to precursor emission changes are quantified. Second, cost functions of emission reductions are estimated using a cost analysis tool that includes a pool of available control measures. The third step is to determine desired reductions in concentrations of air pollutants. The last step is to identify the optimal control strategies by minimizing costs of emission controls using the sensitivities of air pollutants to emission changes, cost functions, and constraints for feasible emission reduction ratios. A case study that investigates ozone and PM2.5 air quality in the summer of 2007 for five major cities in the eastern United States is presented in this paper. The results of the OPERA calculations show that reductions in regional NOx and VOC as well as local primary PM2.5 emissions were more cost-effective than SO2 controls for decreasing ozone and total PM2.5 concentrations in the summer of 2007. This was because reductions in SO2 emissions would only decrease PM2.5 concentrations, and reductions in primary PM2.5 emissions were more cost-effective than SO2 emission controls. IMPLICATIONS: We developed an optimization-based model, OPtimal integrated Emission Reduction Alternatives (OPERA), which allows for identification of least-cost emission control strategies for attaining multipollutant air quality targets at multiple locations simultaneously. A major strength of OPERA is its flexibility, which allows for changes in air quality regulations, involving agencies, study regions, and so on, to be readily incorporated. Overall, it has been demonstrated that OPERA is useful in developing least-cost emission control strategies for achieving multipollutant air quality targets at multiple locations simultaneously and could be useful for policymakers developing integrated air quality management plans.

Contributions of regional air pollutant emissions to ozone and fine particulate matter-related mortalities in eastern U.S. urban areas.

Ground-level ozone and fine particulate matter (PM2.5) are associated with adverse human health effects such as lung structure dysfunction, inflammation and infection, asthma, and premature deaths. This study estimated contributions of emissions of anthropogenic nitrogen oxides (NOx), volatile organic compounds (VOCs) and sulfur dioxides (SO2) from four regions to summertime (i.e., June, July, and August) ozone and PM2.5-related mortalities in seven major Metropolitan Statistical Areas (MSAs with more than 4 million people) in the eastern United States (U.S.). A photochemical transport model, Community Multi-scale Air Quality (CMAQ) with sensitivity analyses, was applied to quantify the contribution of the regional anthropogenic emissions to ambient ozone and PM2.5 concentrations in the seven MSAs. The results of the sensitivity analysis, along with estimates of concentration-response from published epidemiologic studies, were used to estimate excess deaths associated with changes in ambient daily 8-h average ozone and daily PM2.5 concentrations during the summer of 2007. The results show that secondary PM2.5 (i.e., PM2.5 formed in the atmosphere) had larger effects on mortality (95% confidence interval (C.I.) ranged from 700 to 3854) than ambient ozone did (95% C.I. was 470-1353) in the seven MSAs. Emissions of anthropogenic NOx, VOCs and SO2 from the northeastern U.S. could cause up to about 2500 ozone and PM2.5-related deaths in the urban areas examined in this study. The results also show that the contributions of emissions from electrical generating units (EGUs) and anthropogenic non-EGU sources to ozone-related mortality in the MSAs were similar. However, emissions from EGUs had a more significant impact on PM2.5-related deaths than anthropogenic emissions from non-EGUs sources did. Anthropogenic NOx and VOCs emissions from the regions where the MSAs are located had the most significant contributions to ozone-related mortalities in the eastern U.S. urban areas. On the other hand, PM2.5-related mortalities in the MSAs were more likely to be affected by precursors transported from other regions.

Complexation amplified pH oscillation in metal involved systems.

A novel mechanism of amplifying pH oscillations by pH-dependent EDTA-metal ion complexation is proposed. If there is a metal ion involved in the H(+) consuming reactions in the pH oscillator and the metal's complex formation constant is big enough, the nonlinear coupling of the original oscillator with the complexation induced metal ion oscillation can finally amplify the pH oscillation. This effect is demonstrated in H(2)O(2)-S(2)O(3)(2-)-Cu(2+) system and further discussed in three other systems. Since pH oscillation is widely used in many areas as a spontaneous periodical driving force at the molecular level, this work may help to broaden the driving range of pH oscillators.