Elucidating transport dynamics and regional division of PM2.5 and O3 in China using an advanced network model.

Air pollution exhibits significant spatial spillover effects, complicating and challenging regional governance models. This study innovatively applied and optimized a statistics-based complex network method in atmospheric environmental field. The methodology was enhanced through improvements in edge weighting and threshold calculations, leading to the development of an advanced pollutant transport network model. This model integrates pollution, meteorological, and geographical data, thereby comprehensively revealing the dynamic characteristics of PM2.5 and O3 transport among various cities in China. Research findings indicated that, throughout the year, the O3 transport network surpassed the PM2.5 network in edge count, average degree, and average weighted degree, showcasing a higher network density, broader city connections, and greater transmission strength. Particularly during the warm period, these characteristics of the O3 network were more pronounced, showcasing significant transport potential. Furthermore, the model successfully identified key influential cities in different periods; it also provided detailed descriptions of the interprovincial spillover flux and pathways of PM2.5 and O3 across various time scales. It pinpointed major pollution spillover and receiving provinces, with primary spillover pathways concentrated in crucial areas such as the Beijing-Tianjin-Hebei (BTH) region and its surrounding areas, the Yangtze River Delta, and the Fen-Wei Plain. Building on this, the model divided the O3, PM2.5, and synergistic pollution transmission regions in China into 6, 7, and 8 zones, respectively, based on network weights and the Girvan Newman (GN) algorithm. Such division offers novel perspectives and strategies for regional joint prevention and control. The validity of the model was further corroborated by source analysis results from the WRF-CAMx model in the BTH area. Overall, this research provides valuable insights for local and regional atmospheric pollution control strategies. Additionally, it offers a robust analytical tool for research in the field of atmospheric pollution.

Research on regional ozone prevention and control strategies in eastern China based on pollutant transport network and FNR.

O3 pollution in China has worsened sharply in recent years, and O3 formation sensitivity (OFS) in many regions have gradually changed, with eastern China as the most typical region. This study constructed the transport networks of O3 and NO2 in different seasons from 2017 to 2020. The transport trends and the clustering formation patterns were summarized by analyzing the topological characteristics of the transport networks, and the patterns of OFS changes were diagnosed by analyzing the satellite remote sensing data. Based on that, the main clusters that each province or city belongs to in different pollutant transport networks were summarized and proposals for the inter-regional joint prevention and control were put forward. As the results showed, O3 transport activity was most active in spring and summer and least active in winter, while NO2 transport activity was most active in autumn and winter and least active in summer. OFS in summer mainly consisted of transitional regimes and NOx-limited regimes, while that in other seasons was mainly VOC-limited regimes. Notably, there was a significant upward trend in the proportion of transitional regimes and NOx-limited regimes in spring, autumn, and winter. For regions showing NOx-limited regime, areas with higher out-weighted degrees in the NO2 transport network should focus on controlling local NOx emissions, such as central regions in summer. For regions showing VOC-limited regime, areas with higher out-weighted degrees in the O3 transport network should focus on controlling local VOCs emissions, such as central and south-central regions in summer. For regions that belong to the same cluster and present the same OFS in each specific season, regional cooperative emission reduction strategies should be established to block important transmission paths and weaken regional pollution consistency.

Spatial clustering and spillover pathways analysis of O3, NO2, and CO in eastern China during 2017-2021.

The eastern China presented the most serious O3 pollution and increasingly prominent regional characteristics. To understand the transport characteristics of O3 and its precursors and identify their potential relationships are of great guiding significance for interregional joint prevention and control. In this study, the annual and seasonal transport networks of O3 and its precursors (NO2 and CO) during 2017-2021 were constructed by applying the complex network method to air quality observations. And the key spatial clusters, the spillover paths and the potential links among pollutants were comprehensively analyzed based on the topological characteristic analysis of the established air pollutant transport networks. As the results showed, O3 pollution in the eastern China was affected by active regional transports of O3 and its precursors. Regional transports of O3, NO2, and CO were more prominent in autumn and showed high synchronization. The regional transport of precursors, especially NOx, was an important cause of regional O3 pollution. Air pollutant transport characteristics varied with seasons and regions, which demonstrating the importance of regulating seasonal and regional differentiated joint prevention and control strategies, especially for NOx. The results of this study can provide science-based guidance for the regional cooperative control of O3 pollution in the eastern China, and the application of complex networks can also provide a new methodological perspective for the study of air pollution transmission.

Influence of High Sulfate Mine Water on Spontaneous Combustion of Coal.

Mine water cannot be discharged until it has been treated, which increases the cost of mining and causes environmental damage. This paper attempted to use sulfate mine water as a flame retardant material for the treatment of coal spontaneous combustion (CSC) in underground mines. The temperature-programed experimental device and gas chromatograph were used to simulate the low-temperature oxidation process of coal. Infrared spectroscopy was used to study the influence and inhibition mechanism of mine water and chloride inhibitor on active functional groups. It was found that although the sulfate mine water inhibited the formation of -OH, it accelerated the cleavage of the aromatic ring. The thermogravimetric experiment was used to analyze the ignition temperature and activation energy of different coal samples. It was found that mine water had an obvious effect on inhibiting CSC in the combustion stage, which could increase the oxidation temperature of coal.