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Environ Sci Technol ; 43(6): 2018-21, 2009 Mar 15.
Article in English | MEDLINE | ID: mdl-19368207

ABSTRACT

Supercritical CO2 extraction of aqueous streams is a convenient and effective method to remove commonly used solvents of varying polarities from aqueous waste streams. The resulting aqueous layers can potentially be sewered; whereas the organic layer can be recovered for potential reuse. Supercritical fluid extraction (SFE) is a technology that is increasingly being used in commercial processes (1). Supercritical fluids are well suited for extraction of a variety of media, including solids, natural products, and liquid products. Many supercritical fluids have low critical temperatures, allowing for extractions to be done at modestly low temperatures, thus avoiding any potential thermal decomposition of the solutes under study (2). Furthermore, the CO2 solvent strength is easily tuned by adjusting the density of the supercritical fluid (The density is proportional to the pressure of the extraction process). Since many supercritical fluids are gases at ambient temperature, the extract can be concentrated by simply venting the reaction mixture to a cyclone collection vessel, using appropriate safety protocols.


Subject(s)
Carbon Dioxide/chemistry , Chromatography, Supercritical Fluid/methods , Green Chemistry Technology/methods , Solvents/chemistry , Waste Disposal, Fluid/methods , Chromatography, Supercritical Fluid/instrumentation , Drug Industry , Industrial Waste , Organic Chemicals , Water Pollutants, Chemical/chemistry
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