ABSTRACT
Electromagnetic interference (EMI) shielding materials are highly necessary to solve the problem of electromagnetic radiation. Transition-metal carbide/nitride (MXene) materials offer great potential for the construction of high-performance EMI shields because of their high electrical conductivity and versatile surface chemistry. However, MXene generally suffers from poor mechanical and oxidation-resistant properties, which hinders its practical applications. Herein, flexible, strong, and hydrophobic sandwich-structured composite films (H-S-MXene), consisting of a conductive MXene layer and supporting aramid nanofiber layer, were fabricated using step-by-step vacuum-assisted filtration and dip coating. Given the unique sandwich structure, hydrogen bonding interactions, and covalent cross-linking of the MXene sheets, the H-S-MXene composite films demonstrated simultaneously excellent EMI shielding and mechanical properties. The EMI shielding effectiveness of the H-S-MXene composite film with 20 wt % MXene content reached 46.1 dB at thickness of 23.2 ± 0.5 µm, and the tensile strength of the film reached 302.1 MPa, which outperformed other reported EMI shielding materials. The excellent mechanical flexibility and hydrophobicity of the H-S-MXene composite films ensured a stable EMI shielding performance, which could withstand cycled bending, torsion, and exposure to aqueous environments. These impressive features made the H-S-MXene composite films promising candidates for electronic devices and aerospace. This study provides important guidance for the rational design of stable MXene-based composites with advanced properties.
ABSTRACT
An efficient and straightforward synthesis of polysubstituted oxazol-2(3H)-ones has been developed via a tandem Hofmann-type rearrangement and cyclization reaction of various α-acyl-ß-aminoacrylamides mediated by phenyl iodine(III) bis(trifluoroacetate) (PIFA) in the presence of trifloroacetic acid (TFA). This novel protocol features readily available starting materials, mild reaction conditions, simple execution, high chemoselectivity, good functional group tolerance, and a metal-free oxidation process.
ABSTRACT
A facile and efficient direct synthesis of N-substituted 4H-pyrido[1,2-a]pyrimidin-4-imines is developed from α-acyl-ß-(2-aminopyridinyl)acrylamides mediated by triflic anhydride (Tf2O) in the presence of 2-chloropyridine. This amide activation protocol features mild reaction conditions, simple execution, excellent yields, and high chemoselectivity, and is also applied to the synthesis of substituted 4H-pyrido[1,2-a]pyrimidin-4-ones via a practical one-pot procedure.
ABSTRACT
A new drug delivery system, based on mesoporous silica nanoparticles gated by carboxylatopillar[5]arene-modified gold nanoparticles, has been fabricated, which demonstrated good responses to competitive binding and temperature variation. This multifunctional nanosystem combines the excellent characteristics of two kinds of nanoparticles and utilizes a supramolecular host-guest approach for on-demand cargo release.
