A multifactorial study of mass movement in the hilly and gully Loess Plateau based on intensive field surveys and remote sensing techniques.

Mass movements, driven by various non-linearly correlated factors, exhibit high randomness, posing vast difficulties for field observations and subsequent investigations into the underlying mechanisms. In this study 157 mass movement incidents (including collapses, slump and spalling) and their primary influencing factors were surveyed in a small catchment of the hilly and gully Loess Plateau, China, through intensive field investigations and remote sensing techniques. The spatial pattern of mass movement and its relation with the influencing factors were assessed, while the relative impact of different factors was studied using the canonical correlation analysis. Results showed that 1) Mass movements predominantly occurred on gully slopes steeper than 70°. Collapses were the main type of mass movement, accounting for 87.9 % of the number of samples. 2) With regard to the impact of individual factors, rainstorms (rainfall intensity >50 mm day-1) significantly enhanced the occurrence frequency, erosion area and erosion volume of mass movement. The occurrence frequency and erosion area / volume were highest at a soil dry bulk density of 1.34 g cm-3 and 1.54 g cm-3, respectively. Mass movement occurred most frequently on unvegetated or unrooted gully slopes, where the resisting effect of vegetation on mass movement was absent. Gully slopes with smooth rather than rugged profiles were also found to be typical areas of mass movement. The occurrence frequency of mass movement decreased with the elevated topographic wetness index (TWI) and distance to slope top and increased with the distance to channels. 3) For the relative impact of different factors, rainfall and shear strength were key factors facilitating and resisting the onset of mass movement, respectively, while topography exerted the greatest influence on the erosion area and volume. This study revealed the relative influence of different factors on occurrence and scale of mass movement, providing a useful reference for modelling and control of the problem.

Energy-efficient electrochemical degradation of ciprofloxacin by a Ti-foam/PbO2-GN composite electrode: Electrode characteristics, parameter optimization, and reaction mechanism.

Reducing energy comsuption is crucial to commercialize electrochemical oxidation technologies. In this study, a novel PbO2 composite electrode (Ti-foam/PbO2-GN) was successfully fabricated based on a porous titanium (Ti) foam substrate and a ß-PbO2 active layer embedded with multiple graphene (GN) interlayers, and applied as an anode for energy-efficient pulse electrochemical oxidation of ciprofloxacin (CIP). In contrast to PbO2 and Ti-foam/PbO2 electrodes, the Ti-foam/PbO2-GN electrode surface exhibited a more compact structure, smaller crystal grain size, and greater electrochemical active surface area. CIP removal of 89.7% was obtained with a low energy consumption (EE/O) of 6.17 kWh m-3 under pulse electrolysis conditions with a current density of 25.00 mA cm-2, pulse frequency of 5000 Hz, and pulse duty cycle of 50.0%. Up to 70.7% of the energy was saved in the pulse current mode compared to the direct current mode. Narrowing the electrode spacing to 2 cm facilitated the mass transfer process and enhanced oxidation efficiency. According to the intermediates identified, the pulse electrolysis of CIP primarily involved hydroxylation of the quinolone ring, breaking of the piperazine ring, defluorination, and decarboxylation processes, and a possible degradation mechanism of CIP was proposed. The continuous oxidation performance of CIP and the relatively low leaching of Pb2+ suggested that the Ti-foam/PbO2-GN electrode exhibited excellent stability, repeatability, and safety. The degradation results of CIP in real water also exhibits the great potential of environmental application. As a result, pulse electrochemical oxidation using a Ti-foam/PbO2-GN electrode has proven to be an energy-efficient and promising alternative for antibiotic wastewater treatment.

Determining the drivers and rates of soil erosion on the Loess Plateau since 1901.

Attributing soil erosion to land management and climatic drivers is important for global policy development to protect soils. The Chinese Loess Plateau is one of the most eroded areas in the world. However, there has been limited assessment of historic spatial changes in erosion rates on the Loess Plateau and the major contributors driving these spatial changes. In this study, the Revised Universal Soil Loss Equation was empirically validated and employed to assess spatially distributed historical erosion rates on the Loess Plateau from 1901 to 2016. A double mass curve attribution technique was then used to investigate the impact of land management and climatic drivers on the Loess Plateau. Decadal average erosion rates and the total area with intensive erosion (>5000 t km-2 yr-1) experienced a sharp increase from the 1930s to 1970s, followed by a decline to an historic low between the 1980s and 2000s. Mean erosion rates for the 2000s were 54.3% less than those of the 1970s. However, a recent increase in erosion rates was observed between 2010 and 2016. Land management change was the dominant driver of historical erosion rate changes before 2010. Extensive deforestation and farming, driven by population increase, were responsible for intensifying erosion between the 1930s and 1970s, while policy-driven conservation schemes and revegetation led to reduction thereafter. However, the recent increase in erosion between 2010 and 2016 was mainly driven by extreme rainfall events, a major concern given climate change projections. Advanced erosion control strategies are therefore required as part of integrated catchment management that both maintain water supplies for human use during dry periods while reducing erosion during storm events.

Fast and sensitive graphene oxide-DNAzyme-based biosensor for Vibrio alginolyticus detection.

DNAzymes have been widely and effectively used for the detection of pathogenic bacteria, which pose a serious public health threat. However, the rapid and cost-effective detection of such bacteria remains a major challenge. In this study, we successfully selected Vibrio alginolyticus-specific DNAzymes. The activity of the candidates was assessed via fluorescence intensity and gel electrophoresis. The DNAzyme DT1 had a detection limit of 31 CFU/ml for V. alginolyticus and exhibited high specificity. Graphene oxide (GO) was used to develop a DNAzyme-based fluorescent sensor for the detection of V. alginolyticus, which significantly improved detection performance and shortened the reaction time as little as 10 s. The proposed method was then validated using crab, shrimp, fish, clam, and oyster samples. This study thus provides a new method for the rapid and sensitive detection of V. alginolyticus.

Desired compensation adaptive robust repetitive control of a multi-DoFs industrial robot.

In the presence of system coupling and dynamic uncertainties, extensive research has been conducted on the precise motion control of industrial manipulators with general reference trajectories. Since repetitive operations are common tasks in industrial applications, it is an essential and practical problem to further improve the control accuracy by taking advantage of the periodicity of the reference trajectory. In this paper, a desired compensation adaptive robust repetitive control is proposed for multi-DoFs industrial manipulators to perform repetitive tasks. Specifically, the link dynamics identified offline is compensated directly to decouple the system and capture the main characteristics of the link effect. Then, the uncertain friction is dealt with through an online adaptation scheme, in which the desired compensation is utilized to avoid measurement noise and chattering at low speed. And periodic disturbances are approximated by Fourier series expansion with unknown Fourier coefficients, which will be learned online. Finally, the robust feedback is designed to guarantee transient control accuracy and robustness against dynamic uncertainties. Comparative experiments on an industrial manipulator show that the proposed controller possesses better transient and steady-state control accuracy and error convergence rate.

Reliable Output Feedback Control for T-S Fuzzy Systems With Decentralized Event Triggering Communication and Actuator Failures.

Due to the unavailability of full state variables in many control systems, this paper is concerned with the design of reliable observer-based output feedback controller for a class of network-based Takagi-Sugeno fuzzy systems with actuator failures. In order to better allocate network resources under the case that the sensor nodes are physically distributed, the decentralized event triggering communication scheme is adopted such that each sensor node is capable to determine the transmission of its local measurement information independently. Considering that the implementation of the controller may not be synchronized with the plant trajectories due to asynchronous premise variables with such communication mechanism, a novel piecewise fuzzy observer-based output feedback controller is developed. By applying a piecewise Lyapunov function and some techniques on matrix convexification, an approach to the design of observer and controller gain is derived for the augmented closed-loop system to be asymptotically stable with a guaranteed H∞ performance and reduced transmission frequency. Finally, two examples are given to show the effectiveness of the developed method.

Animal Bone Supported SnO2 as Recyclable Photocatalyst for Degradation of Rhodamine B Dye.

SnO2 nanoparticles supported on an animal bone which serves as inexpensive and environment-friendly natural products were developed by a facile hydrothermal approach. As a promising photocatalyst, the novel SnO2/porcine bone material exhibited high photocatalytic activity towards the degradation of rhodamine B (RhB) dye under UV-Vis irradiation. About 97.3% of RhB can be effectively decomposed by the catalysis with the SnO2/porcine bone in 90 min, while only 51.5% of RhB can be degraded by pure SnO2 nanoparticles. Moreover, the photocatalytic activity was incremental with the increase of cycle times in previous five cycles. It is mainly because the photocatalyst which has been used for several times possesses a stronger ability of light absorption and utilization compared to the fresh catalyst according to the results of the characterization and relative experiments. It is noteworthy that the animal bone support can improve the activity for the photocatalyst, which would provide further impetus to alternate synthesis strategies for photocatalysts and make the photocatalysis process faster, less expensive, and more environmentally friendly.

[Spatial and temporal variations of hydrological characteristic on the landscape zone scale in alpine cold region].

There are few studies on the hydrological characteristics on the landscape zone scale in alpine cold region at present. This paper aimed to identify the spatial and temporal variations in the origin and composition of the runoff, and to reveal the hydrological characteristics in each zone, based on the isotopic analysis of glacier, snow, frozen soil, groundwater, etc. The results showed that during the wet season, heavy precipitation and high temperature in the Mafengou River basin caused secondary evaporation which led to isotope fractionation effects. Therefore, the isotope values remained high. Temperature effects were significant. During the dry season, the temperature was low. Precipitation was in the solid state during the cold season and the evaporation was weak. Water vapor came from the evaporation of local water bodies. Therefore, less secondary evaporation and water vapor exchange occurred, leading to negative values of delta18O and deltaD. delta18O and deltaD values of precipitation and various water bodies exhibited strong seasonal variations. Precipitation exhibited altitude effects, delta18O = -0. 005 2H - 8. 951, deltaD = -0.018 5H - 34. 873. Other water bodies did not show altitude effects in the wet season and dry season, because the runoff was not only recharged by precipitation, but also influenced by the freezing and thawing process of the glacier, snow and frozen soil. The mutual transformation of precipitation, melt water, surface water and groundwater led to variations in isotopic composition. Therefore, homogenization and evaporation effect are the main control factors of isotope variations.

A relevance vector machine-based approach with application to oil sand pump prognostics.

Oil sand pumps are widely used in the mining industry for the delivery of mixtures of abrasive solids and liquids. Because they operate under highly adverse conditions, these pumps usually experience significant wear. Consequently, equipment owners are quite often forced to invest substantially in system maintenance to avoid unscheduled downtime. In this study, an approach combining relevance vector machines (RVMs) with a sum of two exponential functions was developed to predict the remaining useful life (RUL) of field pump impellers. To handle field vibration data, a novel feature extracting process was proposed to arrive at a feature varying with the development of damage in the pump impellers. A case study involving two field datasets demonstrated the effectiveness of the developed method. Compared with standalone exponential fitting, the proposed RVM-based model was much better able to predict the remaining useful life of pump impellers.