Effects of four amendments on cadmium and arsenic immobilization and their exposure risks from pakchoi consumption.

Exposure to heavy metal(loid)s (HM) through contaminated food chains poses significant health risks to humans. While soil amendments are known to reduce HM bioavailability, their effects on bioaccessibility and health risks in soil-pakchoi-human systems remain unclear. To address this knowledge gap, we conducted a greenhouse pot experiment coupling soil immobilization with bioaccessibility-based health risk assessment for Cd and As exposure from pakchoi consumption. Four amendments (attapulgite, shell powder, nanoscale zero-valent iron, and biochar) were applied to soil, resulting in changes to soil characteristics (pH and organic matter), plant dry weight, and exchangeable fractions of As and Cd. Among the tested amendments, biochar exhibited the highest effectiveness in reducing the risk of Cd and As exposure from pakchoi consumption. The bioaccessibility-based health risk assessment revealed that the application of 5% biochar resulted in the lowest hazard index, significantly decreasing it from 1.36 to 0.33 in contaminated soil. Furthermore, the structural equation model demonstrated that pH played a critical role in influencing remediation efficiency, impacting the exposure of the human body to Cd and As. In conclusion, our study offers a new perspective on mitigating exposure risks of soil HM and promoting safe crop production. The results underscore the importance of considering bioaccessibility in health risk assessment and highlight the potential of biochar as a promising amendment for reducing Cd and As exposure from pakchoi consumption.

Long-term spatiotemporal evolution and coordinated control of air pollutants in a typical mega-mountain city of Cheng-Yu region under the "dual carbon" goal.

Clarifying the spatiotemporal distribution and impact mechanism of pollution is the prerequisite for megacities to formulate relevant air pollution prevention and control measures and achieve carbon neutrality goals. Chongqing is one of the dual-core key megacities in Cheng-Yu region and as a typical mountain-city in China, environmental problems are complex and sensitive. This research aims to investigate the exceeding standard levels and spatio-temporal evolution of criteria pollutants between 2014 and 2020. The results indicated that PM10, PM2.5, CO and SO2 were decreased significantly by 45.91%, 52.86%, 38.89% and 66.67%, respectively. Conversely, the concentration of pollutant O3 present a fluctuating growth and found a "seesaw" phenomenon between it and PM. Furthermore, PM and O3 are highest in winter and summer, respectively. SO2, NO2, CO, and PM showed a "U-shaped", and O3 showed an inverted "U-shaped" seasonal variation. PM and O3 concentrations are still far behind the WHO, 2021AQGs standards. Significant spatial heterogeneity was observed in air pollution distribution. These results are of great significance for Chongqing to achieve "double control and double reduction" of PM2.5 and O3 pollution, and formulate a regional carbon peaking roadmap under climate coordination. Besides, it can provide an important platform for exploring air pollution in typical terrain around the world and provide references for related epidemiological research.Implications: Chongqing is one of the dual-core key megacities in Cheng-Yu region and as a typical mountain city, environmental problems are complex and sensitive. Under the background of the "14th Five-Year Plan", the construction of the "Cheng-Yu Dual-City Economic Circle" and the "Dual-Carbon" goal, this article comprehensively discussed the annual and seasonal excess levels and spatiotemporal evolution of pollutants under the multiple policy and the newest international standards (WHO,2021AQG) backgrounds from 2014 to 2020 in Chongqing. Furthermore, suggestions and measures related to the collaborative management of pollutants were discussed. Finally, limitations and recommendations were also put forward.Clarifying the spatiotemporal distribution and impact mechanism of pollution is the prerequisite for cities to formulate relevant air pollution control measures and achieve carbon neutrality goals. This study is of great significance for Chongqing to achieve "double control and double reduction" of PM2.5 and O3 pollution, study and formulate a regional carbon peaking roadmap under climate coordination and an action plan for sustained improvement of air quality.In addition, this research can advanced our understanding of air pollution in complex terrain. Furthermore, it also promote the construction of the China national strategic Cheng-Yu economic circle and build a beautiful west. Moreover, it provides scientific insights for local policymakers to guide smart urban planning, industrial layout, energy structure, and transportation planning to improve air quality throughout the Cheng-Yu region. Finally, this is also conducive to future scientific research in other regions of China, and even megacities with complex terrain in the world.

Long-Term Air Pollution Characteristics and Multi-scale Meteorological Factor Variability Analysis of Mega-mountain Cities in the Chengdu-Chongqing Economic Circle.

Currently, air quality has become central to global environmental policymaking. As a typical mountain megacity in the Cheng-Yu region, the air pollution in Chongqing is unique and sensitive. This study aims to comprehensively investigate the long-term annual, seasonal, and monthly variation characteristics of six major pollutants and seven meteorological parameters. The emission distribution of major pollutants is also discussed. The relationship between pollutants and the multi-scale meteorological conditions was explored. The results indicate that particulate matter (PM), SO2 and NO2 showed a "U-shaped" variation, while O3 showed an "inverted U-shaped" seasonal variation. Industrial emissions accounted for 81.84%, 58% and 80.10% of the total SO2, NOx and dust pollution emissions, respectively. The correlation between PM2.5 and PM10 was strong (R = 0.98). In addition, PM only showed a significant negative correlation with O3. On the contrary, PM showed a significant positive correlation with other gaseous pollutants (SO2, NO2, CO). O3 is only negatively correlated with relative humidity and atmospheric pressure. These findings provide an accurate and effective countermeasure for the coordinated management of air pollution in Cheng-Yu region and the formulation of the regional carbon peaking roadmap. Furthermore, it can improve the prediction accuracy of air pollution under multi-scale meteorological factors, promote effective emission reduction paths and policies in the region, and provide references for related epidemiological research. Supplementary Information: The online version contains supplementary material available at 10.1007/s11270-023-06279-8.

Microplastics may increase the environmental risks of Cd via promoting Cd uptake by plants: A meta-analysis.

Microplastics (MPs) and cadmium (Cd) are widely distributed in soil ecosystems, posing a potential threat to agricultural production and human health. However, the coupled effects of MPs and Cd in soil-plant systems remain largely unknown, especially on a large scale. In this study, a meta-analysis was conducted to evaluate the influence of MPs on plant growth and Cd accumulation under the Cd contamination conditions. Our results showed that MPs had significantly negative effects on shoot biomass (a decrease of 11.8 %) and root biomass (a decrease of 8.79 %). MPs also significantly increased Cd accumulation in the shoots and roots by 14.6 % and 13.5 %, respectively, revealing that MPs promote plant Cd uptake. Notably, polyethylene displayed a stronger promoting effect (an increase of 29.4 %) on Cd accumulation among these MP types. MPs induced a significantly increase (9.75 %) in concentration of soil available Cd and a slight decrease in soil pH, which may be the main driver promoting plant Cd uptake. MP addition posed physiological toxicity risks to plants by inhibiting photosynthesis and enhancing oxidative damage, directly demonstrating that MPs in combination with Cd can pose synergetic toxicity risks to plants. We further noted that MPs altered microbial diversity, likely influencing Cd bioavailability in soil-plant systems. Overall, our study has important implications for the combined impacts of Cd and MPs on plants and provides new insights into developing guidelines for the sustainable use of MPs in agriculture.

Improved hydrogen production from pharmaceutical intermediate wastewater in an anaerobic maifanite-immobilized sludge reactor.

A novel anaerobic maifanite-immobilized sludge reactor (AMSR) was employed to investigate the feasibility and performance of continuous hydrogen production for the treatment of pharmaceutical intermediate wastewater (PIW) at different organic loading rates (OLR) (from 12 to 96 g COD L-1 d-1) according to changes in the hydraulic retention time (HRT). A reactor without maifanite was also employed as a control. The results indicate that maifanite accelerates granular sludge formation and the AMSR presents more efficient and stable performance than the control in terms of the hydrogen production rate. In the AMSR, the highest hydrogen production rate of 11.2 ± 0.4 mmol L-1 h-1 was achieved at an optimum OLR of 72 g COD L-1 d-1. The main metabolic route for hydrogen production was ethanol-type fermentation, which was reflected in the relative abundance of E. harbinense, which was dominant for all of the OLRs. The maximum energy conversion efficiency in the dual production of hydrogen and ethanol was determined to be 24.5 kJ L-1 h-1 at an OLR of 72 g COD L-1 d-1.

Voltage-induced strain clocking of nanomagnets with perpendicular magnetic anisotropies.

Nanomagnetic logic (NML) has attracted attention during the last two decades due to its promise of high energy efficiency combined with non-volatility. Data transmission in NML relies on Bennett clocking through dipole interaction between neighboring nanomagnetic bits. This paper uses a fully coupled finite element model to simulate Bennett clocking based on strain-mediated multiferroic system for Ni, CoFeB and Terfenol-D with perpendicular magnetic anisotropies. Simulation results demonstrate that Terfenol-D system has the highest energy efficiency, which is 2 orders of magnitude more efficient than Ni and CoFeB. However, the high efficiency is associated with switching incoherency due to its large magnetostriction coefficient. It is also suggested that the CoFeB clocking system has lower bit-density than in Ni or Terfenol-D systems due to its large dipole coupling. Moreover, we demonstrate that the precessional perpendicular switching and the Bennett clocking can be achieved using the same strain-mediated multiferroic architecture with different voltage pulsing. This study opens new possibilities to an all-spin in-memory computing system.

Eco-physiological characteristics of Pistia stratiotes and its removal of pollutants from livestock wastewater.

The effectiveness of water lettuce in removing pollutants including organic pollutants, nitrogen (NH3-N) and total phosphorus (TP) from livestock wastewater along with the physiological effects and their correlations, was studied for the first time. The results showed that the water lettuce had higher removal efficiency with low concentrations of livestock wastewater. The removal efficiency of water lettuce for different initial concentrations of livestock wastewater within 8 d was as follows: chemical oxygen demand (CODcr) (68-82%) > NH3-N (57-69%) >TP (27-45%). The speed of purification of water lettuce for CODcr, NH3-N and TP conformed to first order kinetics equations. The water quality indices CODcr, NH3-N and TP had a higher linear correlation with peroxidase (POD) activity (R(2) > 0.9(2)) than with superoxide dismutase (SOD) and catalase (CAT) activity, which indicates that the main reacting enzyme of water lettuce under high CODcr stress is peroxidase.

Bioaccumulation and chemical forms of cadmium, copper and lead in aquatic plants

The cadmium(Cd), copper(Cu) and lead(Pb) accumulation, as well as their relative content of different chemical forms in Sagittaria sagittifolia L. and Potamogeton crispus L. were determined. The results showed that both the plants had the ability to accumulate large amounts of Cd, Cu and Pb, and they absorbed metals in dose-dependent manners. The roots of S. sagittifolia appeared more sensitive to Cd and Pb than the leaves of P. crispus. The potential of Cu uptake by these two plant tissues was similar. Under the same concentration, the uptake of Cu for both the plants was higher than Pb and Cd, while that of Pb was lowest. The Cd, Cu and Pb existed with various forms in the plants. Cd and Pb were mainly in the NaCl extractable form in S. sagittifolia and P. crispus. The HAc and ethanol extractable Cu were the main forms in the root, whereas the ethanol extractable form was the dominant chemical form in the caulis and bulb of the S. sagittifolia L.

Exogenous polyamines enhance copper tolerance of Nymphoides peltatum.

The protective effects of polyamines (PAs) against copper (Cu) toxicity were investigated in the leaves of Nymphoides peltatum. Cu treatment increased the putrescine (Put) level and lowered spermidine (Spd) and spermine (Spm) levels, thereby reducing the (Spd+Spm)/Put ratio in leaves. Exogenous application of Spd or Spm markedly reversed these Cu-induced effects for all three PAs and partially restored the (Spd+Spm)/Put ratio in leaves. It also significantly enhanced the level of proline, retarded the loss of soluble protein, decreased the rate of O2*- generation and H2O2 content, and prevented Cu-induced lipid peroxidation. Furthermore, exogenous Spd and Spm reduced the accumulation of Cu and effectively maintained the balance of nutrient elements in plant leaves under Cu stress. These results suggest that exogenous application of Spd or Spm can enhance the tolerance of N. peltatum to Cu by increasing the levels of endogenous Spd and Spm as well as the (Spd+Spm)/Put ratio.

Physiological responses of Alternanthera philoxeroides (Mart.) Griseb leaves to cadmium stress.

Aquatic macrophytes were found to be the potential scavengers of heavy metals from aquatic environment. In this study, several physiological responses of Alternanthera philoxeroides (Mart.) Griseb leaves to elevated concentrations of cadmium (up to 10mM) were investigated. It was found that A. philoxeroides was able to accumulate cadmium in its leaves. The pigment contents decreased with the increase of the Cd concentrations. The Cd could induce rise of the activity of peroxidase (POD) at lower concentration (<5mM), however, when the concentration of Cd rose up to 10mM, the POD activity declined. The changes of superoxide dismutase (SOD) and Catalase (CAT) activities were exactly opposite to that of POD. In the leaves of Cd-treated fronds, the amounts of three polypeptides with apparent molecular weights 80, 39 and 28kDa, respectively, were became visible in SDS-PAGE. The nature of these polypeptides remains to be determined.

[Protective effects of exogenous ascorbic acid on antioxidant system in Hydrilla verticillata under Cd2+].

In this paper, Hydrilla verticillata was cultured in the hoagland solution containing 5 mg L(-1) Cd2+ and different concentration ascorbic acid (AsA) to investigate the protective action of AsA to aquatic plant suffered from heavy metal's stress. The O2 generation rate, H2O2 content, antioxidants (AsA and GSH) contents, and antioxidant enzymes (SOD, POD, CAT and APX) activities were analyzed. The results showed that compared with single Cd2+ treatment, AsA addition lessened the reactive oxygen species (O2-* and H2O2) generation rates, endogenous AsA content, and antioxidant enzyme activities. It was concluded that exogenous AsA could relieve the Cd2+ poison to H. verticillata, and its optimum concentration was 60 mg x L(-1).

[Effects of exogenous spermidine on resistance of Nymphoides peltatum to Hg2+ stress].

Effects of different exogenous spermidine concentrations on the activities of some enzymes (SOD, CAT, POD, APX), O(-)(2) generation rate, the MDA, chlorophyll, soluble protein and polyamine contents in leaves of Nymphoides peltatum without Hg(2+) stress or under Hg(2+) stress were studied. The results showed that: (1) The spermidine (Spd) and spermine (Spm) content dropped significantly under Hg(2+) (3 mg/L) stress 4 d, while that of putrescine (Put) was increased markedly. Exogenous Spd could increase the Spd and Spm content in leaves, while that of Put lowered at first and rose later. (2) Hg(2+) 3 mg/L decreased drastically the activities of SOD, CAT and APX, increased the O(-)(2) generation rate, led to the accumulation of a large amount of MDA and loss of chlorophyll and soluble protein. Exogenous Spd could enhance the activities of SOD, CAT and APX, decrease O(-)(2) generation rate and reduce the MDA content. In addition, Spd could also decrease the loss of chlorophyll and soluble protein content induced by Hg(2+) stress, enhance the ability of Nymphoides peltatum to resist Hg(2+) stress. The most suitable concentration of Spd was in the range 0.1-0.5 mmol/L.