Response surface optimization of product yields and biofuel quality during fast hydrothermal liquefaction of a highly CO2-tolerant microalgae.

The effects of biochemical components and processing variables (e.g., temperatures, solid-liquid ratio, ethanol concentration, and time) during fast hydrothermal liquefaction of a highly CO2-tolerant microalgae (Micractinium sp.) on the product yields and biofuel quality were explored using response surface methodology coupled with central composite design. Results showed that the maximum bio-oil yield (51.4 %) was obtained at 321 °C for 49 min at ethanol concentration of 75 % and solid-liquid ratio of 15.3 %. Among different studied parameters, ethanol concentration showed the highest significant impact on the bio-oil yield due to the low P-value and high F-value in ANOVA analysis. Furthermore, the chemical compositions of bio-oils were determined, which showed that the increase of ethanol concentration in the solvent not only increased the bio-oil yield but also promoted the bio-oil quality by reduction of carboxylic acids and nitrogen-containing compounds with simultaneous enhancement of esters in the bio-oil. The present results show that fast hydrothermal liquefaction is a promising approach to convert the microalgae into high quality biofuels rich in esters.

Study on the co-operative effect of kitchen wastewater for harvest and enhanced pyrolysis of microalgae.

Microalgae biofuels have received extensive attention as a new generation of renewable energy. However, the cost of cultivation and harvest limits the large-scale use of microalgae. An innovative method for harvesting microalgae through flocculation using kitchen wastewater (KWW) and further co-pyrolysis to enhance the crude bio-oil production was proposed. Flocculation efficiency of KWW for Scenedesmus obliquus showed the highest value of 94.09%. Compared with centrifugation and chemical flocculation (CF), the thermogravimetric curve of the sample after KWW flocculation showed different pattern. In addition, bio-oil yield of microalgae harvested through KWW flocculation was also the highest among the three studied harvest methods, reaching 55.59%. Gas chromatographic mass spectrometry (GC-MS) analysis of bio-oil showed that addition of KWW could promote the production of esters and hydrocarbons in comparison to the microalgae harvested by centrifugation or CF.