ABSTRACT
In this study, the occurrence, spatial distribution, sources, and ecological risks of perfluoroalkyl substances (PFASs) in the surface waters of the Lingang hybrid constructed wetland were systematically investigated. Twenty-three PFASs were analyzed from 7 representative sampling zones. The obtained results indicated that PFBA, PFPeA, PFHxA, PFHpA, PFOA, PFBS, PFOS, and HFPO-DA were frequently detected; and PFBA, PFOA, and PFOS were the dominant PFASs with the relative abundances in ranges of 26.91 to 52.26%, 11.79 to 28.79%, and 0 to 31.98%, respectively. The total concentrations of 8 PFASs (Σ8PFASs) ranged from 25.9 to 56.6 ng/L, and the highest concentration was observed in subsurface flow wetland. Moreover, HFPO-DA with high toxicity was detected in wetlands for the first time. Based on the principal component analysis-multiple linear regression (PCA-MLR) analysis, three sources and their contributions were fluoropolymer processing aids (67.6%), fluororesin coatings and metal plating (17.9%), and food packaging materials and atmospheric precipitation (14.5%), respectively. According to the risk quotients (RQs), the ecological risk of 8 PFASs was low to the aquatic organisms.
