ABSTRACT
The far-infrared spectrum (100-500 cm-1) of a d1 isotopologue of the astrophysically important molecule, vinyl alcohol, is reported. We observed several low energy (OD) torsional bands: the fundamental and first two hot bands of the syn rotamer and the fundamental and first hot band of the (higher energy) anti rotamer. While the bands corresponding to the anti rotamer are somewhat obscured by rotational lines of water (making a full spectroscopic analysis unfeasible at this stage), the syn-vinyl alcohol bands are not, and a global fit was performed that included 4404 distinct infrared lines assigned in this work, in addition to 59 previously reported microwave lines. This simultaneous analysis of the torsional fundamental, torsional hot band, and pure rotational band of syn-vinyl alcohol allowed for determination of spectroscopic parameters in the first two torsionally excited states and for refinement of them in the ground state. These parameters should be useful in searches for both cold and warm CH2CHOD in interstellar molecular clouds.
ABSTRACT
Twelve applications of poultry litter were made to a 2.1-ha field located in the Shenandoah Valley of Virginia, United States (USA), between March 1999 and August 2014. The field was planted with bermudagrass (Cynodon dactylon) and used as a pasture on an active farm. Copper, iron, manganese, zinc, and arsenic concentrations in the poultry litter were measured, and the application rates of these metals were calculated. The median application rates were: Cu, 1.32 kg/ha, Fe, 5.57 kg/ha, Mn, 1.80 kg/ha, Zn, 1.39 kg/ha, and As, 0.011 kg/ha. Twelve surface and subsurface soil samples were taken from the treated field in February 2016. Twelve samples were also taken from a comparison site. The comparison site was directly adjacent to the study site, consisted of the same soil type, and had been maintained as an undisturbed forest. Extractable Cu, Fe, Mn, Zn, and As concentrations in the soil samples were determined by atomic absorption spectroscopy, and the results of the chemical analysis were analyzed by ANOVA. Fe and Mn were depleted from the soil in the treated field, while Cu and Zn levels increased over the 12 years of treatment and grazing, and arsenic levels were unchanged in both the surface and subsurface soils between the comparison and the study site. The changes observed for Cu, Fe, Mn, and Zn are within the critical deficiency level and critical toxicity level for these metals, and no arsenic remains in the soil from roxarsone feed supplements, which were added to the poultry feed when the litter was applied to the study site.
