ABSTRACT
Rotational transitions of the mono(ß)-deuterated vinyl radical, HDC=CH, produced in a supersonic jet expansion by the ArF excimer laser photolysis, were observed by millimeter-wave spectroscopy. The b-type rotational transitions together with the weak a-type transitions were observed only for the lower component of the tunneling doublet, and no tunneling-rotation transitions connecting the lower and upper components were observed, suggesting that state mixing between the two components is negligibly small. The derived molecular constants such as the A rotational constant, Fermi contact interaction constants, and magnetic dipolar interaction constants indicate that the carrier of the observed spectrum is the trans-form of HDC=CH isomers, where the α-proton is located on the opposite side of the ß-deuteron. The present conclusion of the trans-form of HDC=CH was also supported by the ab initio calculation in the CCSD(T)/cc-pVTZ level since the trans-form is calculated to be located by 30.04 cm-1 lower than the cis-form due to the difference in the zero point energy. As a result, the tunneling components in the ground state of HDC=CH behave as two different isomers localized at the trans- and cis-wells of the asymmetric double minimum potential. Observed hyperfine constants for HDC=CH were compared with those for H2C=CH to be consistent with each other.
ABSTRACT
In previous studies, acoustical levitation in the far-field was limited to particles. Here, this paper proposes the "boundary hologram method," a numerical design technique to generate a static and stable levitation field for macroscopic non-spherical rigid bodies larger than the sound wavelength λ. This paper employs boundary element formulation to approximate the acoustic radiation force and torque applied to a rigid body by discretizing the body surface, which is an explicit function of the transducer's phase and amplitude. Then, the drive of the phased array is numerically optimized to yield an appropriate field that stabilizes the body's position and rotation. In experiments, this paper demonstrates the levitation in air of an expanded polystyrene sphere with a diameter of 3.5 λ and a regular octahedron with diagonal length of 5.9 λ, both located 24 λ from the acoustic elements, by a 40 kHz (λ = 8.5 mm) ultrasonic phased array. This method expands the variety of objects that can be levitated in the far-field of an ultrasonic phased array.
