Using Nanomaterials as Excellent Immobilisation Layer for Biosensor Design.

The endless development in nanotechnology has introduced new vitality in device fabrication including biosensor design for biomedical applications. With outstanding features like suitable biocompatibility, good electrical and thermal conductivity, wide surface area and catalytic activity, nanomaterials have been considered excellent and promising immobilisation candidates for the development of high-impact biosensors after they emerged. Owing to these reasons, the present review deals with the efficient use of nanomaterials as immobilisation candidates for biosensor fabrication. These include the implementation of carbon nanomaterials-graphene and its derivatives, carbon nanotubes, carbon nanoparticles, carbon nanodots-and MXenes, likewise their synergistic impact when merged with metal oxide nanomaterials. Furthermore, we also discuss the origin of the synthesis of some nanomaterials, the challenges associated with the use of those nanomaterials and the chemistry behind their incorporation with other materials for biosensor design. The last section covers the prospects for the development and application of the highlighted nanomaterials.

Enhanced visible light driven photoelectrochemical degradation of tetracycline hydrochloride using a BiOI photoanode modified with MnO2 films.

Removal of pharmaceuticals in wastewater has been the focus of many research due to the recalcitrant nature and hazardous effects of these compounds. The photoelectrochemical degradation process has proven to be suitable to harness solar energy for the mineralization of organic compounds in wastewater. Herein, we report the application of BiOI/MnO2 heterostructured anode for the photoelectrochemical degradation of tetracycline hydrochloride in aqueous solution. The photoanode was prepared through electrodeposition technique and fully characterized through microscopic, spectroscopic and electrochemical techniques. The results showed that formation of p-n heterojunction between BiOI and MnO2 in the photoanode led to improved charge separation which was evident in improved optical and photoelectrochemical properties. The FTO-BiOI/MnO2 electrode attained a photocurrent density of 0.104 mA cm-2 with applied potential of 1.0 V (vs Ag/AgCl) which was almost double that of pristine BiOI suggesting efficient charge separation. The heterostructured photoanode achieved 94% removal of tetracycline hydrochloride after 120 min through the PEC degradation process with 61% mineralization efficiency. The electrode showed good reusability and stability with 92% PEC removal after eight cycles. Hence, the FTO-BiOI/MnO2 has a great potential as anode for PEC wastewater treatments.

A review on water treatment technologies for the management of oxoanions: prospects and challenges.

Oxoanions are a class of contaminants that are easily released into the aquatic systems either through natural or anthropogenic activities. Depending on their oxidation states, they are highly mobile, resulting in the contamination of underground water. Above the permissible level in groundwater, they pose as threats to mammals when the contaminated water is consumed. Some of the health challenges caused are cancer, neurological, cardiac, gastrointestinal, and skin disorders. Several treatment technologies have been adopted over the years for the management of these oxoanions present in the aquatic systems. However interesting these treatment technologies might be, they also have their limitations such as cost-effectiveness, the complexity of the process, and generation of secondary pollutants. This work focused on some of the water treatment technologies applied for the removal of oxoanions. Some of the advantages and disadvantages of these treatment technologies are also highlighted. Amongst all the treatment technologies, adsorption is the most applied method for the removal of oxoanions. However, photocatalysis has a higher prospect since it is non-selective and secondary pollutants are not generated after the treatment process. Also, photocatalysis can simultaneously reduce and oxidise oxoanions as well as organic pollutants respectively.

Recent advances in degradation of pharmaceuticals using Bi2WO6 mediated photocatalysis - A comprehensive review.

The pollution of water bodies by residual pharmaceuticals is a major problem globally. Bismuth tungstate mediated photocatalysis has been effective in the removal of these organics from water. Bismuth tungstate (Bi2WO6) has proven to be an excellent visible light active photocatalyst because of its non-toxicity, low band gap energy and ease of preparation. It has been widely applied for the removal of a wide array of organic pollutants, particularly dyes, from wastewater. However, recently, much attention has been channelled to its application for the degradation of pharmaceuticals. In this present review, the recent trends in the applications of Bi2WO6 based photocatalysts for the removal of pharmaceuticals in wastewater are comprehensively discussed. The fabrication of Bi2WO6 based photocatalysts with enhanced photocatalytic performances through morphology control, doping and formation of heterojunctions are highlighted. Much discussion centres on the mechanisms and possible degradation pathways of antibiotic pharmaceuticals in wastewater. Finally, areas needing more attention and investigation on the use of Bi2WO6 based photocatalysts for removal of pharmaceuticals from wastewater especially towards real-life applications are presented for future research directions.

Sensitive and selective electrochemical detection of bisphenol A based on SBA-15 like Cu-PMO modified glassy carbon electrode.

This work reports the electrochemical detection of bisphenol A (BPA) using a novel and sensitive electrochemical sensor based on the Cu functionalized SBA-15 like periodic mesoporous organosilica-ionic liquid composite modified glassy carbon electrode (Cu@TU-PMO/IL/GCE). The structural morphology of Cu@TU-PMO is characterized by X-ray powder diffraction (XRD), energy dispersive X-ray analysis (EDX), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), Field emission scanning electron microscopy (FE-SEM), and Brunauer-Emmett-Teller (BET). The catalytic activity of the modified electrode toward oxidation of BPA was interrogated with cyclic voltammetry (CV) and differential pulse voltammetry (DPV) in phosphate buffer solution (pH 7.0) using the fabricated sensor. The electrochemical detection of the analyte was carried out at a neutral pH and the scan rate studies revealed that the sensor was stable. Under the optimal conditions, a linear range from 5.0 nM to 2.0 µM and 4.0 to 500 µM for detecting BPA was observed with a detection limit of 1.5 nM (S/N = 3). The sensor was applied to detect BPA in tap and seawater samples, and the accuracy of the results was validated by high-performance liquid chromatography (HPLC). The proposed method provides a powerful tool for the rapid and sensitive detection of BPA in environmental samples.