ABSTRACT
syn-2-Nitrosopropene was generated, in the gas phase, by chemical reaction of 1-chloro-2-(hydroxyimino)propane with K(2)CO(3) and identified by microwave spectroscopy. The microwave spectrum of the reaction product was observed in the frequency range from 8.0 to 40.0 GHz. The rotational constants (MHz) were determined as A = 8744.09(6), B = 4846.07(2), and C = 3177.84(3) for CH(2)&dbond;C(CH(3))&bond;(14)NO (normal species) and A = 8664.36(5), B = 4822.15(3), and C = 3157.04(3) for CH(2)&dbond;C(CH(3))&bond;(15)NO ((15)N species) in the ground vibrational state. The values of the planar moment (P(cc) = (I(a) + I(b) - I(c))/2) obtained for the normal and (15)N species were 1.525(1) and 1.526(1) u Å(2), respectively. This suggests that the nitrogen atom lies in or is close to the ab inertial plane of the molecule and shows also that only two hydrogen atoms are located symmetrically out of the symmetry plane. The reaction product was determined to be syn-2-nitrosopropene by comparing the observed and calculated rotational constants, kappa (Ray's asymmetry parameter) and r(s) coordinates of the nitrogen atom. The dipole moments (D) were determined to be µ(a) = 2.43(5), µ(b) = 1.12(7), and µ(total) = 2.67(7). The barrier heights of the internal rotation owing to the methyl group of the normal species in the ground and first excited torsional states were determined to be 1750(50) and 1740(50) cal/mol (1 cal/mol = 4.184 J/mol), respectively. The (14)N nuclear quadrupole coupling constants (MHz) were determined to be chi(aa) = 0.25(21), chi(bb) = -7.11(40), and chi(cc) = 6.85(61). Two vibrational excited states were observed and the vibrational frequencies (cm(-1)) of the C-N and C-C torsional modes were determined to be 160(40) and 175(40), respectively. The lifetime of syn-2-nitrosopropene was found to be ca. 2 min in the waveguide cell. Copyright 2000 Academic Press.
ABSTRACT
Cadmium ions in a natural isotope mixture have been trapped in a linear Paul trap and laser cooled. The fluorescence spectra from all even isotopes, including the (108)Cd(+) isotopes with a natural abundance of 0.89%, were observed. Additionally, we eliminated the heavier isotopes from the trapping region by adjusting the tuning of the laser frequency and by changing the dc voltage applied to the end electrodes.
ABSTRACT
A cw mode-locked Ti:sapphire laser was efficiently frequency doubled with a lithium triborate crystal in an external enhancement cavity. Second-harmonic output powers of 1.28 W and 860 mW have been generated at 399 nm with fundamental pulse widths of 1.5 and 320 ps, respectively. At the 1.5-ps pulse width the conversion efficiency was 75%. The spectral width of the 320-ps pulses, produced by modification of a laser cavity, is as narrow as the bandwidth of a normal cw, multimode, narrow-bandwidth Ti:sapphire laser. The frequency-doubled output can be thus used as a high-power, narrow-bandwidth light source in the UV region.
ABSTRACT
Continuous-wave radiation of 1.8 mW at 397 nm was generated by frequency doubling a 100-mW GaAlAs diode laser in a lithium iodate crystal placed in an external enhancement cavity. The radiation had a narrow linewidth and a continuous frequency-scanning range of 6 GHz. The UV radiation obtained was applied to laser cooling of calcium ions stored in a rf trap.
ABSTRACT
Continuous-wave coherent radiation tunable near 194 nm has been generated by sum-frequency generation in beta-BaB(2)O(4) placed inside an external enhancement cavity. An output power of 16 microW has been obtained with a walk-off-compensated configuration of beta-BaB(2)O(4) crystals.
ABSTRACT
We describe the laser cooling of Ca(+) ions in a rf ion trap and the measurement of its 3(2)D(5/2) state lifetime. The ions are cooled to below 1 K by radiation from a frequency-doubled Ti:sapphire laser and a laser diode. The radiative lifetime is measured by observing the change in fluorescence when the ions, which are optically pumped to the metastable state, return to the cooling cycle. The lifetime of the 3(2)D(5/2) state is measured to be 0.77 +/- 0.07 s.
