Microplastics in sea ice: A fingerprint of bubble flotation.

Sea ice is heavily contaminated with microplastics (MPs), with the repeatedly confirmed increased number of larger-sized particles, deficit of fibers, and prevalence of materials denser than the surrounding water. To get insight into the drivers behind such a specific pattern, sets of laboratory experiments were performed on the formation of ice by cooling from the surface of fresh and salty (NaCl, 34 g/L) water, with particles of different sizes from heavy plastics (HPP) distributed initially over the bottom of the experimental volume. After freezing, about 50-60 % of HPP were trapped in ice in all the runs. Vertical distribution of HPP, plastic mass distribution, ice salinity (in saltwater experiments), and bubble concentration (in freshwater experiments) were recorded. Formation of bubbles on hydrophobic surfaces was the main cause of the entrapment of HPP into ice, with convection playing a secondary role. Supplementary bubble formation experiments with the same particles in water demonstrated that at larger fragments and fibers, several bubbles grow at the same time, so particle rising and residing at the surface is stable. Smaller HPP experience rising/sinking cycles with minimum time spent at the surface: one bubble is enough to cause a particle rising, but it is most often lost when colliding with the water surface. Application of the results to oceanic conditions is discussed. Oversaturation with gases due to various physical/biological/chemical processes and liberation of bubbles from methane seeps and melting permafrost are common in Arctic waters. Convective water motions are able to relocate HPP in vertical. Based on applied research, the bubble nucleation and growth, the hydrophobicity of weathered surfaces, the effectiveness of flotation methods for plastic particles are discussed. Interaction of plastic particles with bubbles is an important feature, still completely overlooked in the context of MPs behavior in marine environment.

Transport and accumulation of plastic particles on the varying sediment bed cover: Open-channel flow experiment.

Contamination of sea bottom sediments by microplastics is widely confirmed, but the reasons for its patchiness remain poorly understood. Laboratory experiments are reported where combined sets of various plastic particles, different by shape, size, density, and flexibility, were transported by the step-wise increasing open-channel flow over the bottom covered with natural sediment of increasing grain size. For every particular flow velocity, observations revealed the recurrent formation of relatively narrow retention areas, where plastic particles lingered for some time in their motion. These areas follow the line of change of the sediment type from finer to coarser grains. It is shown that contact friction drives the retention of a particle at finer sediments, while particle/sediment-grain interaction becomes of importance when particles and sediment grains are of similar sizes. The presence of this effect can be expected for a relatively wide range of natural conditions.

Microplastics distribution in bottom sediments of the Baltic Sea Proper.

An abundance of microplastics particles (0.2-5 mm, MPs) in bottom sediments is analyzed based on 53 samples (3 to 215 m deep) obtained in 8 cruises of research vessels across the Baltic Sea Proper in March-October 2015-2016. MPs content varied between stations from 103 up to 10,179 items kg-1 d.w., with the bulk mean of 863 ± 1371 items kg-1 d.w., showing a statistically significant increase with water depth. As many as 74.5% of MPs are of fibrous shape, followed by films (19.8%) and fragments (5.7%). The distributions of fibres, fragments, films, and different types of natural bottom sediments are significantly different, highlighting the specific behaviour of each of these kinds of bottom deposits. A statistically significant correlation between water depth and fibres content is found. Based on the analysis of oceanographic factors and sedimentological principles, an erosion/transition/accumulation pattern for fibres in the Baltic Sea Proper is outlined. Fibres can be considered as a specific type of "synthetic sediment", while principles of distribution of other MPs are not yet certain.

Catching the variety: Obtaining the distribution of terminal velocities of microplastics particles in a stagnant fluid by a stochastic simulation.

A simple stochastic numerical model is applied to obtain the distribution of the terminal settling/rising velocity of a set of MPs particles whose size, shape, and density have their distributions in accordance with field observations and production trends. Results of the direct Monte Carlo simulation are shown to reproduce well the data of laboratory experiments. Distributions of MPs by size and density appear to be more valuable for the final terminal velocity distribution compared to the influence of the distribution by shape. The most "real" of the simulated distributions of the terminal velocity of MPs particles in the ocean has a multimodal shape, slightly different for fresh and saline waters. Multimodality arises from the fact that the terminal velocity depends on several physical parameters simultaneously and thus should be an expected feature of MPs terminal velocity distribution.

On mechanical fragmentation of single-use plastics in the sea swash zone with different types of bottom sediments: Insights from laboratory experiments.

Mechanical fragmentation of four commonly used plastics, from 2-cm squares or cubes to microplastics (MPs, <5 mm), is experimentally investigated using a rotating laboratory mixer mimicking the sea swash zone with natural beach sediments (large and small pebbles, granules, sand). Macro-samples were prepared from brittle not-buoyant PS (disposable plates), flexible thin film of LDPE (garbage bags), highly buoyant foamed PS (building insulation sheets), and hard buoyant PP (single-use beverage cups). With a great variety of behaviors of plastics while mixing, coarser sediments (pebbles) have higher fragmentation efficiency than sands (measured as the mass of generated MPs), disregarding sinking/floating or mechanical properties of the samples. It is confirmed that, under swash-like mixing with coarse sediments, the MPs tend to burry below the sediment surface. The obtained relationship between the mass of MPs and the number of items is similar to that for MPs floating at the ocean surface.

Settling velocity of microplastic particles of regular shapes.

Terminal settling velocity of around 600 microplastic particles, ranging from 0.5 to 5mm, of three regular shapes was measured in a series of sink experiments: Polycaprolactone (material density 1131kgm-3) spheres and short cylinders with equal dimensions, and long cylinders cut from fishing lines (1130-1168kgm-3) of different diameters (0.15-0.71mm). Settling velocities ranging from 5 to 127mms-1 were compared with several semi-empirical predictions developed for natural sediments showing reasonable consistency with observations except for the case of long cylinders, for which the new approximation is proposed. The effect of particle's shape on its settling velocity is highlighted, indicating the need of further experiments with real marine microplastics of different shapes and the necessity of the development of reasonable parameterization of microplastics settling for proper modeling of their transport in the water column.