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1.
Bioorg Med Chem ; 9(2): 211-6, 2001 Feb.
Article in English | MEDLINE | ID: mdl-11249112

ABSTRACT

The inter-residual dihedral angles phi and phip of chitin and chitosan oligomers were determined from experimental 3J(C-H) constants and ROESY cross peaks.


Subject(s)
Chitin/chemistry , Bandages , Biopolymers/chemistry , Carbohydrate Conformation , Chitin/analogs & derivatives , Chitosan , Magnetic Resonance Spectroscopy , Oligosaccharides/chemistry
2.
Carbohydr Res ; 325(3): 177-82, 2000 Apr 20.
Article in English | MEDLINE | ID: mdl-10795808

ABSTRACT

The conformation of maltose-type oligomers in water and in dimethylsulfoxide (Me2SO) was studied using two-dimensional NMR spectra. In Me2SO all of the oligomers have a 1a-type conformation. In water, they tend to adopt the same conformation, but the oligomers are looser and more flexible than in Me2SO.


Subject(s)
Amylose/chemical synthesis , Glucans/chemical synthesis , Glucose/chemistry , Maltose/chemistry , Carbohydrate Conformation , Deuterium Oxide/chemistry , Magnetic Resonance Spectroscopy , Water/chemistry
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