Composting of recovered rock wool from hydroponics for the production of soil amendment.

Due to its fibrous structure and high water holding capacity, rock mineral wool (RMW) has boosted the development of hydroponics. Consequently, the amount of waste RMW has also increased tremendously, which has stimulated the research and development of RMW reuse options. In this study, composting and degradability of RMW from hydroponics (gRMW) were tested in combination with different ratios of biowaste compost, including physical and chemical properties of the starting and final materials, and potential ecological hazards of the final product. gRMW had high water holding capacity and low organic matter content, which was easily degradable. Limits of toxic elements according to EU regulation were not exceeded. Degraded gRMW mixtures with compost did not exhibit toxicity to plants or aquatic bacteria and showed intermediate or limited habitat function for earthworms, which preferred the sole gRMW not mixed with compost. Overall, degraded gRMW exhibited parameters of safe soil amendment.

Microalgae-based removal of contaminants of emerging concern: Mechanisms in Chlorella vulgaris and mixed algal-bacterial cultures.

Incomplete removal of contaminants of emerging concern (CECs) has been reported for conventional wastewater treatment technologies. Microalgae-based treatment has recently gained interest thanks to simultaneous removal capacity of organic and inorganic compounds and potentially CECs. In this study, a lab-scale monoculture of Chlorella vulgaris and mixed microalgal-bacterial culture were compared in terms of removal of 28 CECs (bisphenols, 2018 EU Watch List substances, including neonicotinoids, pharmaceuticals, selected transformation products). The removal pathways in light and dark abiotic controls were also studied. Batch photobioreactors were run at hydraulic retention times of 11-12 days and CECs spiked at environmentally relevant concentrations (1-20 µg L-1). The mixed culture was better at removing bisphenols, compared to C. vulgaris. Bisphenols' log Kow was significant in removal pathways, where bisphenols with high log Kow were removed abiotically while bisphenols with low log Kow were mainly biodegraded. The removal degrees and the pathways of pharmaceuticals and EU Watch List substances were comparable between both cultures, showing no impact of log Kow for most compounds; however, the removal with C. vulgaris was faster for some. High log Kow was associated with high removal of estradiol in abiotic controls, showing the importance of adsorption onto biomass and suspended matter.

Status of decentralised wastewater treatment systems and barriers for implementation of nature-based systems in central and eastern Europe.

The aim of this paper is to present a survey on the current status of wastewater treatment systems in 11 central and eastern European (CEE) countries, with a focus on rural areas and on small treatment wetlands for settlements of below 2,000 people. The results indicate that CEE countries have insufficient sanitation systems with different performance efficiencies. These differences stem from the different historical, political and economic developments as well as legislation in the previous five to six decades. CEE settlements with less than 2,000 inhabitants represent almost 30.0 % of the overall number of persons living in CEE countries. These data show that CEE countries have a mainly rural character, but this is slowly decreasing. Over 42 million inhabitants are waiting for proper sanitation systems. This requirement will be ever-growing in the next future, and it is important to know and to prepare appropriate steps for progressive realisation.

Improved urban stormwater treatment and pollutant removal pathways in amended wet detention ponds.

Dissolved and colloidal bound pollutants are generally poorly removed from stormwater in wet detention ponds. These fractions are, however, the most bio-available, and therefore three wet detention ponds were amended with planted sand filters, sorption filters and addition of precipitation chemicals to enhance the removal of dissolved pollutants and pollutants associated with fine particles and colloids. The three systems treated runoff from industrial, residential and combined (residential and highway) catchments and had permanent volumes of 1,990, 6,900 and 2,680 m(3), respectively. The treatment performance of the ponds for elimination of total suspended solids (TSS), total nitrogen (Tot-N), total phosphorous (Tot-P), PO(4)-P, Pb, Zn, Cd, Ni, Cr, Cu, Hg were within the range typically reported for wet detention ponds, but the concentrations of most of the pollutants were efficiently reduced by the planted sand filters at the outlets. The sorption filters contributed to further decrease the concentration of PO(4)-P from 0.04 ± 0.05 to 0.01 ± 0.01 mg L(-1) and were also efficient in removing heavy metals. Dosing of iron sulphate to enrich the bottom sediment with iron and dosing of aluminium salts to the inlet water resulted in less growth of phytoplankton, but treatment performance was not significantly affected. Heavy metals (Pb, Zn, Cd, Ni, Cr and Cu) accumulated in the sediment of the ponds. The concentrations of Zn, Ni, Cu and Pb in the roots of the wetland plants were generally correlated to the concentrations in the sediments. Among 13 plant species investigated, Rumex hydrolapathum accumulated the highest concentrations of heavy metals in the roots (Concentration Factor (CF) of 4.5 and 5.9 for Zn and Ni, respectively) and Iris pseudacorus the lowest (CF < 1). The translocation of heavy metals from roots to the aboveground tissues of plants was low. Therefore the potential transfer of heavy metals from the metal-enriched sediment to the surrounding ecosystem via plant uptake and translocation is negligible.

Elimination and accumulation of polycyclic aromatic hydrocarbons in urban stormwater wet detention ponds.

The concentrations of polycyclic aromatic hydrocarbons (PAHS) in water and sediments of seven wet detention ponds receiving urban stormwater were investigated. The ponds comprised traditional wet detention ponds with a permanent wet volume and a storage volume as well as ponds that were expanded with sand filters and other means to improve the removal of micropollutants. The concentrations of sigmaPAH in the sediments varied between 6 +/- 5 and 2,222 +/- 603 ng g(-1) dry weight (mean +/- standard deviation), and were highest in the ponds with lower pond volume per catchment area and did not clearly reflect different activities in the catchments. In general, the concentrations of PAHS in the sediments decreased from inlet to outlet, especially in the systems with good conditions for sedimentation such as systems with flow perpendicular sand dikes and extensive submerged vegetation. High molecular weight PAHs were predominant in the sediments indicating the pyrogenic origin of the PAHS. There was no correlation between PAH species concentrations in water or sediments and their hydrophobicity (log K(ow)). PAH concentrations in water fluctuated in response to intensity and frequency of rain events, whereas concentrations in the sediments integrated the pollutant load over time. Pond systems expanded with sand filters and other technologies to enhance removal of micropollutants consistently had concentrations of PAHS in the effluents below the detection level.