1.
Org Lett
; 15(14): 3594-7, 2013 Jul 19.
Article
in English
| MEDLINE
| ID: mdl-23822170
ABSTRACT
An efficient synthetic approach for functionalization of both the active sites (1,3-) and the K-region (4,5,9,10-) of pyrene was accomplished by bromination and oxidation with considerable yield. These novel pyrene-fused azaacenes were thoroughly investigated by X-ray diffraction studies, electrochemistry, and DFT calculations.
2.
Org Lett
; 15(6): 1318-21, 2013 Mar 15.
Article
in English
| MEDLINE
| ID: mdl-23461603
ABSTRACT
The first example of aryl-functionalized, butterfly-shaped, highly fluorescent and stable blue-emitting monomers, namely, 7-tert-butyl-1,3,5,9-tetrakis(p-R-phenyl)pyrenes, were synthesized by the Suzuki-Miyaura cross-coupling reaction from a novel bromide precursor of 1,3,5,9-tetrabromo-7-tert-butylpyrene. The crystal structures and optical and electronic properties have been investigated.