Organochlorine pesticide contamination of soils and dust from an urban environment in the Niger Delta of Nigeria.

The concentrations, sources, and risk of twenty organochlorine pesticides (OCPs) in soils and dusts from a typical urban setting in the Niger Delta of Nigeria were examined. The Σ20 OCP concentrations (ng g-1) varied from 4.49 to 150 with an average value of 32.6 for soil, 4.67 to 21.5 with an average of 11.7 for indoor dust, and 1.6 to 96.7 with an average value of 23.5 for outdoor dust. The Σ20 OCP concentrations in these media were in the order: soil > outdoor dust > indoor dust, which was in contrast with the order of the detection frequency, i.e., indoor dust (95 to 100 %) > soil (60 to 90 %) > outdoor dust (30 to 80 %). The concentrations of the different OCP classes in these media followed the order: aldrin + dieldrin + endrin and its isomers (Drins) > chlordanes > dichlorodiphenyltrichloroethane (DDTs) > hexachlorocyclohexane (HCHs) > endosulfans for outdoor dust and soil, while that of the indoor dust followed the order: Drins > chlordanes > endosulfans > DDTs > HCHs. The cancer risk values for human exposure to OCPs in these sites exceeded 10-6 which indicates possible carcinogenic risks. The sources of OCPs in these media reflected both past use and recent inputs.

Safety evaluation of organochlorine pesticides and polybrominated diphenyl ethers in imported canned fish in Nigeria.

Organochlorine pesticide (OCP) and polybrominated diphenyl ether (PBDE) concentrations were measured in thirty popular brands of imported canned fish (mackerel, sardines, and tuna) in Nigeria to ascertain potential threats to humans arising from their consumption. The Σ20 OCP concentrations in mackerel ranged from 0.47 to 7.36 ng g-1, while those of tuna and sardines varied from 1.06 to 2.19 and 0.11 to 12.7 ng g-1, respectively. The Σ39 PBDE concentrations in mackerel varied from 0.06 to 4.21 ng g-1, while those of tuna and sardines ranged from 0.19 to 3.18 and 0.04 to 8.26 ng g-1, respectively. The estimated daily intake (EDI) of OCPs and PBDEs from ingestion of the canned fish by adults and children were in the magnitude of 0.03 to 17.6 ng kg-1 bw day-1 and 9.9 × 10-3 to 11.5 ng kg-1 bw day-1 respectively. The hazard index (HI) and total cancer risk (TCR) values for OCPs and PBDEs from ingestion of the canned fish were less than 1 and 10-6, respectively. The dietary intakes of OCPs and PBDEs from these brands of canned fish by adults and children result in no adverse non-cancer and cancer risks.

Polybrominated diphenyl ether contamination in sediments from rivers in the western Niger Delta of Nigeria.

This study investigated the concentrations of 39 polybrominated diphenyl ether (PBDE) congeners in sediments from three rivers in the western Niger Delta of Nigeria that have been affected by pollution from urbanization and industrial activities. The Σ39 PBDE concentrations in sediments from these rivers ranged from 0.29 to 95.5, 5.15 to 121, and 0.73 to 66.1 ng g-1 for the Afiesere (AR), Edor (ER), and Okpare Rivers (OR), respectively. The homologue distribution patterns indicated the prominence of tetra- and penta-BDE congeners in sediments from these rivers. The ecological risk assessment results showed that the penta-BDEs were the primary source of risk to sediment-dwelling organisms in these rivers. However, the human health risk assessment indicated negligible risks for exposure of both adults and children to PBDEs in these sediments. The source apportionment suggests that the PBDE contamination in these river sediments was derived from long-distance migration, debromination of highly brominated congeners, and commercial penta-BDEs. These results reflect the use of penta-BDE formulations in this region rather than octa- and deca-BDE formulations.

Distribution, sources, and risk of polycyclic aromatic hydrocarbons in soils from rural communities around gas flaring points in the Niger Delta of Nigeria.

This study investigates the concentrations, sources, and ecological and human health risks resulting from exposure to polycyclic aromatic hydrocarbons (PAHs) in soils of rural communities around gas flaring points in Delta State, Nigeria. PAHs were extracted from these soil samples with hexane/dichloromethane by ultra-sonication and the extracts were cleaned on a silica gel/alumina-packed column. The PAH concentrations in the extracts were quantified by gas chromatography-mass spectrometry (GC-MS). The Σ16 PAH concentrations in soils from these communities varied from 2370-134 000, 461-389 000, and 2130-34 900 µg kg-1 for Emu-Ebendo (EME), Otu-Jeremi (OTJ) and Ebedei (EBD), respectively. The estimated lifetime carcinogenic risk values recorded in this study were above the acceptable limit of 10-6, indicating a high potential carcinogenic risk resulting from human exposure to PAHs in these soils. The isomeric ratio and principal component analysis results suggest that emissions from high-temperature combustion, potentially gas flaring, vehicular emissions, burning of wood/biomass, and fossil fuel combustion are responsible for the high concentrations of PAHs in soils of these rural communities. This study recommends implementing remediation and source control measures to minimise the impact of PAHs in the affected soils on humans and the environment.

Polycyclic aromatic hydrocarbons in dust from rural communities around gas flaring points in the Niger Delta of Nigeria: an exploration of spatial patterns, sources and possible risk.

Indoor and outdoor dust from three rural communities (Emu-Ebendo, EME, Otu-Jeremi, OTJ, and Ebedei, EBD) around gas flaring points, and a rural community (Ugono Abraka, UGA) without gas flare points, in the Niger Delta of Nigeria, was analysed for the concentrations and distribution of polycyclic aromatic hydrocarbons (PAHs), their sources, and possible health risk resulting from human exposure to PAHs in dust from these rural communities. The PAHs were extracted from the dust with a mixture of dichloromethane/n-hexane by ultrasonication, and purified on a silica gel/alumina packed column. Gas chromatography-mass spectrometry was employed to determine the identity and concentrations of PAHs in the cleaned extracts. The Σ16PAH concentrations in the indoor dust ranged from 558 to 167 000, 6580 to 413 000, and 2350-37 500 µg kg-1 for EME, OTJ and EBD respectively, while those of their outdoor counterparts varied from 347 to 19 700, 15 000 to 130 000, and 1780 to 46 300 µg kg-1 for EME, OTJ and EBD respectively. On the other hand, the UGA community without gas flare points had Σ16PAH concentrations in the range of 444-5260 µg kg-1 for indoor dust, and 154-7000 µg kg-1 for outdoor dust. The lifetime cancer risk values for PAHs in these matrices surpassed the acceptable limit of 10-6 suggesting a potential carcinogenic risk resulting from human exposure to PAHs in indoor and outdoor dust from these rural communities. Principal component analysis suggested that PAH contamination of dust from these communities arises principally from gas flaring, combustion of wood/biomass, and vehicular emissions.

Spatial characteristics, sources and exposure risk of polychlorinated biphenyls in dusts and soils from an urban environment in the Niger Delta of Nigeria.

Chlorinated organic compounds, such as polychlorinated biphenyls (PCBs), are a threat to both humans and the environment because of their toxicity, persistence, and capacity for long-range atmospheric transport. The concentrations of 28 PCB congeners, including 12 dioxin-like and seven indicator PCBs, were investigated in soils, and indoor and outdoor dusts from Port Harcourt city, Nigeria, in order to evaluate the characteristic distribution patterns in these media, their sources, and possible risk. The PCB concentrations varied from 4.59 to 116 ng g-1 for soils, and from 1.80 to 23.0 ng g-1 and 2.73 to 57.4 ng g-1 for indoor and outdoor dusts respectively. The sequence of PCB concentrations in these matrices was soil > outdoor dust > indoor dust. The composition of PCBs in these matrices indicated the prevalence of lower chlorinated PCBs in indoor and outdoor dusts, while the higher chlorinated congeners were dominant in soils. Di-PCBs were the predominant homologues in indoor dusts, while deca-PCBs were the most prevalent homologues in outdoor dusts and soils. The TEQ values of dioxin-like PCBs in 60 % of the soils, 100 % of the indoor dust, and 30 % of the outdoor dust were above the indicative value of 4 pg TEQ g-1 established by the Canadian authority. The hazard index (HI) values for exposure of adults and children to PCBs in these media were mostly greater than one, while the total cancer risk (TCR) values exceeded the acceptable risk value of 10-6, which indicate probable non-carcinogenic and carcinogenic risks resulting from exposure to PCBs in these media. Source analysis for PCBs in these matrices shows that they originated from diverse sources.

Spatial distribution of polycyclic aromatic hydrocarbons in dust and soils from informal trade sites in southern Nigeria: Implications for risk and source analysis.

Polycyclic aromatic hydrocarbons (PAHs) are a group of semi-volatile and persistent organic compounds considered priority pollutants because of their pervasive nature and high toxicity to the ecosystem and humans. Therefore, this study aimed to evaluate the PAH concentrations in dust and soils around informal trade sites (ITS) in Nigeria to determine the level of risk, sources, and significance of these activities to the PAH load of the environment. The 16 US EPA PAHs in dust and soils from ITS were determined by gas chromatography-mass spectrometry (GC-MS). The PAH concentrations in dust from these informal trade sites varied from 120 to 8790, 56 to 4780, and 102-1090 µg kg-1 for automobile mechanic workshops (AMW), car dismantling (CDS), and material recovery sites (MRS), respectively, whereas those of soils ranged from 3000 to 95,500, 554 to 14,700, and 966-25,200 µg kg-1 for AMW, CDS, and MRS respectively. The PAH profiles indicated that 3- to 5-ring PAHs were prominent in dust and soils around the ITS. The concentrations of the US EPA 16 PAHs in dust and soils from these ITS showed no correlation with organic matter, while the concentrations of PAH homologues in soils of these ITS showed no correlation with those of dust. Incremental lifetime cancer risk (ILCR) values in the magnitude of 10-4 to 101 were obtained for adult and childhood exposure to PAHs in dust and soils from these ITS. Exposure to PAHs in dust from these ITS gives rise to less risk than for soils. The results indicated that automobile mechanic workshops contribute more PAHs to the environment than car dismantling and material recovery activities. The source analysis showed that the PAH contamination of these sites arises from burning of biomass, plastic materials, and oils, and emissions from vehicles.

Polychlorinated biphenyls and polychlorinated dibenzo-p-dioxins and furans in imported canned fish in Nigeria and risk assessment.

Concentrations of polychlorinated biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) were measured in imported canned fish such as mackerel, sardine and tuna to evaluate the risk relating to human consumption of these products. Gas chromatography-mass spectrometry (GC/MS) was used to evaluate the concentrations of PCBs and PCDD/Fs in the samples. The ∑28 PCB concentrations in the canned mackerel, tuna and sardine ranged from 0.33 to 9.48 ng g -1,

Occurrence and spatial characteristics of polychlorinated biphenyls (PCBs) in sediments from rivers in the western Niger delta of Nigeria impacted by urban and industrial activities.

The characteristic concentrations of 28 PCB congeners, their spatial distributions, sources, and associated risks to the ecosystem were investigated in sediments of some rivers around a glass industry and power generating plant in the Niger Delta of Nigeria. Gas chromatography-mass spectrometry (GC-MS) was applied for the identification and quantification of PCBs in sediments from these rivers. The Æ©28 PCB concentrations (dry weight) in sediments ranged from 1520 to 3540 ng g-1 for the Afiesere River, 976-5670 ng g-1 for the Edor River, and from 1440 to 6340 ng g-1 for the Okpare River. The homologue distribution patterns in sediments from these rivers indicated that low-chlorinated (2 Cl to 5 Cl) PCBs were more dominant than high-chlorinated (6 Cl to 10 Cl) PCBs with tri-, penta- and deca-PCBs as the top homologues. The PCB source analyses suggested that the PCB contamination of these river sediments could have originated from Aroclor mixtures, paints, pigments and other inadvertent sources. The risk assessment indicated a high risk to the ecosystem.

Concentrations, sources, and exposure risk of polychlorinated biphenyls in soil profiles of the floodplain of the lower reaches of the River Niger, Nigeria.

The concentrations of 28 polychlorinated biphenyls (PCBs) were determined in soils collected at three depths from thirteen different sites along the floodplain of the lower reaches of the River Niger (LRRN) in Nigeria. The aim of the study was to provide data on the levels of contamination, sources of the contaminants, and risks to the ecosystem and humans. Soil samples were Soxhlet extracted with a solvent mixture of dichloromethane (DCM)/n-hexane and cleaned up on a column packed with Florisil and silica gel. The PCBs in the samples were quantified by gas chromatography-mass spectrometry. The Æ©28 PCB concentrations in the floodplain soils varied between not detected (nd) and 11,151 ng g-1 for different sampling sites and depths. The PCB concentrations and homologue distribution patterns in soil profiles of the floodplain of the LRRN showed remarkable differences with respect to sites and depths. The results obtained were used to evaluate the ecological and human health risks, which indicated that there is a potential risk to organisms and humans from exposure to PCBs in these soil profiles. The source evaluation as determined by principal component analysis suggested that PCBs in these soil profiles came from burnt circuit boards, cable wires, use of paints, discharges from transformers, long-range migration, and deposition.

Impact of Land-Use Types on the Distribution and Exposure Risk of Polycyclic Aromatic Hydrocarbons in Dusts from Benin City, Nigeria.

The concentrations of the sixteen United States Environmental Protection Agency polycyclic aromatic hydrocarbons (PAHs) were determined in dusts from different land-use types in Benin City by means of gas chromatography-mass spectrometry. The results obtained were used to assess the ecological and human health risk and to determine the source apportionment. The Æ©16 PAH concentrations in dusts from Benin City ranged from 230 to 2300 µg kg-1 for industrial areas, 211-1330 µg kg-1 for commercial areas, 153-1170 µg kg-1 for residential areas, and from 216 to 1970 µg kg-1 for school playgrounds/parks. The ecological risk assessment suggested that the levels of PAHs in dusts from these land-use types are of low-to-moderate risk to organisms. The benzo(a)pyrene carcinogenic potency [BaPTEQ] (70.5-131 µg kg-1) and benzo(a)pyrene mutagenic potency [BaPMEQ] (62.9-122 µg kg-1) concentrations were below the Canadian soil quality guideline value of 600 µg kg-1. The incremental lifetime carcinogenic risk (ILCR) arising from exposure of adults and children to PAHs in dusts from Benin City were in the magnitude of 10-4-10-2, which exceeded the safe target levels of 10-6, implying a considerable cancer risk for residents of this city. The PAH source apportionment derived from isomeric ratios and multivariate statistics indicated that burning of biomass, wood, and charcoal, and vehicular traffic were the predominant sources of PAHs in dusts from Benin City.

Distribution, sources and exposure risk of polycyclic aromatic hydrocarbons in soils, and indoor and outdoor dust from Port Harcourt city, Nigeria.

In this study, we evaluated the concentrations, composition, sources, and potential risks of polycyclic aromatic hydrocarbons (PAHs) in soils, and indoor and outdoor dust from Port Harcourt city in Nigeria. Gas chromatography-mass spectrometry (GC-MS) was used for the detection and quantification of PAH species in the samples. The concentrations of the US EPA 16 PAHs plus 2-methyl-naphthalene (∑17 PAHs) in soils, and indoor and outdoor dust from Port Harcourt city ranged from 240 to 38 400, 276 to 9130 and 44 to 13 200 µg kg-1 (dry weight, d.w.) respectively. The PAH concentrations in these matrices followed the sequence: soil > indoor dust > outdoor dust. The composition of PAHs in soils and dust (indoor and outdoor) showed remarkable differences with prominence of 3- and 5-ring PAHs. The estimated carcinogenic risk to the residents arising from exposure to these concentrations of PAHs in soils, and indoor and outdoor dust from Port Harcourt was above the acceptable target cancer risk value of 10-6. We concluded that these sites require clean-up, remedial actions and implementation of stringent pollution control measures with the intention of reducing the undesirable impacts of PAHs on both the ecosystem and humans.

Polycyclic aromatic hydrocarbons (PAHs) in surficial sediments from selected rivers in the western Niger Delta of Nigeria: Spatial distribution, sources, and ecological and human health risks.

This study assessed the concentrations, sources, and risks of polycyclic aromatic hydrocarbons (PAHs) in sediments from the Rivers Niger, Ase and Forcados in the western Niger Delta. The concentrations of PAHs (in µg kg-1 dry weight), as determined by gas chromatography-mass spectrometry, in sediments from these rivers varied from 2400 to 19,000, 2930 to 16,100, and from 1620 to 19,800 for the Niger, Ase and Forcados Rivers respectively. High molecular weight (HMW) PAHs were the most prevalent compounds present in these sediments. An assessment of the possible ecological and human health risks suggested high risks for both organisms and humans. The PAH source analysis suggested that sediments from these river systems were contaminated with PAHs arising from burning of biomass, gasoline/diesel emissions, burning of natural gas, and oil spillages.

Distribution and Sources of n-Alkanes and Polycyclic Aromatic Hydrocarbons in Sediments Around Oil Production Facilities in the Escravos River Basin, Niger Delta, Nigeria.

This study provides data on the characteristic levels, spatial patterns, sources, and risk of n-alkanes (AHs) [octane, n-C8, to tetracontane, n-C40] and polycyclic aromatic hydrocarbons (PAHs) in surficial sediments from the Escravos River Basin (ERB), Nigeria. The n-alkane and PAH concentrations in sediments were quantified by chromatographic methods. The concentrations of AHs and PAHs in the ERB sediments varied from 95 to 3430 µg g-1 and from 0.75 to 213 µg g-1, respectively. Both the concentrations of AHs and PAHs in ERB sediments exceeded their respective guideline values. The carbon preference index and other AH markers provide evidence that the AHs in the ERB sediments originated from petroleum sources. Ecological risk assessment indicated that the ecological risk relating to an organism's contact with PAHs in the ERB sediments was high. The possible carcinogenic risk arising from human exposure with PAHs in surface sediments through accidental oral ingestion and skin contact exceeded the safe level of 10-6, indicating a considerable probable cancer risk for fishermen and other inhabitants of the ERB. PAH isomer ratios and multivariate statistics suggested that the PAHs in sediments from the ERB originated from gas flaring inputs, discharges from oil drilling platforms, diesel engines, ships, and speed boats, and combustion of wood and other biomass.

Spatial characteristics, sources, and ecological and human health risks of polychlorinated biphenyls in sediments from some river systems in the Niger Delta, Nigeria.

Polychlorinated biphenyls (PCBs) were quantified in sediments from the lower reaches of the Niger, Ase and Forcados Rivers in Nigeria with the aim of elucidating the sources, spatial characteristics and likely ecological and human health risks relating to exposure to PCBs in the sediments. A total of 28 PCB congeners, including 7 indicator PCBs and 12 dioxin-like PCBs, were identified and quantified after Soxhlet extraction with acetone/n-hexane/dichloromethane by gas chromatography-mass spectrometry. The Σ28 PCB concentrations in sediments from the Niger, Ase and Forcados Rivers ranged from 13.5 to 277 ng g-1, not detected to 1633 ng g-1 and 6.9 to 78.6 ng g-1 respectively. The PCB composition in sediments from these three rivers indicate the dominance of lower chlorinated (2-Cl to 5-Cl) congeners over higher chlorinated (6-Cl to 10-Cl) congeners. The ecological and human health risk assessment suggests potential risks for exposure of both organisms and humans to PCBs in sediments from these three river systems.

Spatial characteristics and risk assessment of polychlorinated biphenyls in surficial sediments around crude oil production facilities in the Escravos River Basin, Niger Delta, Nigeria.

In this study, the concentrations of 28 polychlorinated biphenyl (PCB) congeners, including 12 dioxin-like PCBs and 7 indicator PCBs, were determined in sediments around oil production facilities in the Escravos River Basin of the Niger Delta in Nigeria. The aim was to describe the spatial patterns, sources, and ecosystem risks associated with exposure to PCBs in sediments of this river basin. Gas chromatography-mass spectrometry (GC-MS) was used to determine the concentrations of PCBs in the sediments. The Æ©28 PCB concentrations in sediments from the Escravos River Basin ranged between 226 and 31,900 ng g-1 with a median concentration of 2300 ng g-1. The results indicated that sediments around crude oil production facilities, such as, wellheads, flow stations, and truck lines, had significantly higher levels of Æ©28 PCBs (p < 0.05) than those collected near residential communities within the river basin. The median concentrations of PCB homologues in sediments from this river basin followed the sequence: hexaPCBs > penta-PCBs > tetra-PCBs > hepta-PCBs > tri-PCBs > di-PCBs > deca-PCBs > octa-PCBs > nona-PCBs. The risk assessment of PCBs in sediments from this river basin suggest very high potential risks for both organisms and humans.

Occurrence, sources and ecological and human health risks of polycyclic aromatic hydrocarbons in soils from some functional areas of the Nigerian megacity, Lagos.

The study investigated the levels of the USEPA 16 PAHs in soils collected from selected functional areas (cemetery, commercial, industrial and residential areas) of the Nigerian megacity, Lagos. The soil samples were subjected to ultrasonic-assisted extraction in a 1:1 (v/v) mixture of dichloromethane/hexane, and the PAHs in the resulting extracts were determined by gas chromatography-mass spectrometry. The Σ16 PAHs in soils of these functional areas varied between 890-4675, 485-4513, 111-15,577 and 509-2047 µg kg-1 for cemetery, industrial, commercial and residential areas, respectively. The benzo(a)pyrene carcinogenic (BaPTEQ) and mutagenic equivalency (BaPMEQ) values of PAHs in these soils spanned from 523 to 1046 and 446 to 1129 µg kg-1, respectively. The hazard index values suggested that there are adverse (non-carcinogenic) health effects for a child's exposure to PAHs in soils of commercial areas. The cancer risk values resulting from an adult's and a child's exposure to PAHs in these urban soils via dermal contact and oral ingestion surpassed the target value of 10-6 which suggested that there is a considerable cancer risk relating to human exposure to PAHs in these urban soils. An ecological risk assessment making use of soil quality guidelines and risk quotients suggested a low ecological risk to organisms in soils of these functional areas except for those from commercial areas. PAH isomeric ratios and principal component analysis indicated that PAHs in these soils arise from petrogenic inputs, such as occasional spills of liquid petroleum fuels and discharges from automobile workshops and generator houses, as well as pyrogenic processes including traffic emissions and combustion of fossil fuels and biomass.

Risk of human exposure to metals in some household hygienic products in Nigeria.

This study presents data on the levels and risk of human exposure to Cd, Pb, Cr, Ni, Cu, Co, Mn, Zn and Fe in some popular brands of household hygienic products (HHPs) available in Nigeria. The HHPs were digested with a mixture of HNO3, HCl and HClO4 in a ratio of 1:3:1 and the concentrations of the selected metals were quantified by atomic absorption spectrophotometry. The metal concentrations (in µg g-1) in these products ranged from 0.4 to 5.4, <0.09-47.0, <0.12-43.7, <0.06-7.5, <0.12-9.5, <0.06-15.0, <0.09-24.5, 9.0-675 and 62.4-434 for Cd, Pb, Cr, Cu, Co, Ni, Mn, Zn and Fe respectively. The systemic exposure dosages for the metals, arising from the use of these HPPs, were less than their respective provisional tolerable daily intake/recommended dietary allowance values. The household hygienic products are safe to use by humans based on the margin of safety values that were all above 100. However, the products contained significant levels of toxic (Cd and Pb), allergenic (Ni and Cr) and other low toxicity metals (Mn, Zn and Fe), which could be a potential threat to the environment.

Concentrations and risks of polychlorinated biphenyls (PCBs) in transformer oils and the environment of a power plant in the Niger Delta, Nigeria.

The concentrations of Æ©14 PCBs were determined, with the aid of gas chromatography-mass spectrometry (GC-MS), in transformer/turbine oils, soils, groundwater, and drainage water collected within a power plant in the Niger Delta of Nigeria. The Æ©14 PCB concentrations in the transformer oils, drainage water, groundwater and soils ranged from 484 to 48506 mg kg-1, 0.99 to 2.95 mg L-1, 0.16 to 0.56 mg L-1 and from 8.4 to 510 mg kg-1 respectively. The congener distribution patterns in these samples indicate the dominance of highly chlorinated homologues (hepta- and octa-PCBs). The Σ14 PCB concentrations in the transformer oils were above the provisional definition of low persistent organic pollutant (POP) content for PCBs of 50 mg kg-1 as defined in the guidelines on the management of POP waste of the Basel Convention. The concentrations of Æ©14 PCBs in the soils were above the Dutch guideline value of 1000 µg kg-1 and the estimated incremental lifetime cancer risks relating to exposure of humans to PCBs in soils indicate serious health risks. There is therefore a need to implement a surveillance programme in the vicinity of power plants to determine the impacts on the adjacent ecosystem.

Characterization of metals in indoor dusts from electronic workshops, cybercafés and offices in southern Nigeria: Implications for on-site human exposure.

The levels of Cd, Pb, Cr, Ni, Cu, Co, Ba, Mn, Zn, Al and Fe were evaluated in indoor dusts from electronic workshops, cybercafés and offices in southern Nigeria. The study was aimed at providing information on the distribution patterns, and the associated risks that may arise from exposure of humans to these metals in indoor dusts from the three work environments. The dust samples were digested with aqua-regia and analyzed for the metal concentrations by inductively coupled plasma-atomic emission spectrometry (ICP-AES). The metal concentrations (mg kg-1) in the indoor dusts from these work environments ranged from 0.2 to 20.5 Cd, 0.6-4810 Pb, 8.65-2210 Cr, 1.85-209 Ni, 6.75-2820 Cu, 0.25-19.6 Co, 22.7-597 Mn, 6.65-140 Ba, 43.3-7310 Zn, 1040-16,800 Al and 969-78,300 Fe. The metal distribution patterns in these dust samples followed the order: electronic workshops > cybercafés > offices. The concentrations of Cd, Pb and Cu in significant proportions of the dust samples from the electronic workshops and cybercafés surpassed their respective permissible limits in soils. The health risk assessment suggests considerable non-cancer risks arising from childhood contact with Pb in dust from the electronic workshops while no considerable non-cancer risk is associated with the adult and child exposure to dust from the cybercafés and offices. The results indicated that Cr and Pb are the main elements responsible for the non-carcinogenic risk arising from childhood exposure to electronic workshop dusts. The carcinogenic risk due to exposure of humans to metals in these dust samples were within the range regarded as safe by the USEPA.