ABSTRACT
Correction for 'Efficient formation of oil-in-oil Pickering emulsions with narrow size distributions by using electric fields' by Z. Rozynek et al., Soft Matter, 2018, 14, 5140-5149.
ABSTRACT
Droplets covered by adsorbed particles are used in a wide range of research studies and applications, including stabilising emulsions used in the food or cosmetic industries, and fabricating new materials, such as microcapsules or multi-cavity structures. Pickering emulsions are commonly prepared by bulk emulsification techniques, for instance, by ultrasonic homogenisation or mechanical stirring, by membrane emulsification, or with the use of microfluidics. The latter two methods typically allow for more precise control of the droplet size distribution, whereas the bulk techniques guarantee high throughput. Here we propose a new bulk approach to fabricating Pickering emulsions by utilising electric fields. We prepare oil-in-oil emulsions stabilised by microparticles and control the mean size of the Pickering droplets. In our approach we take advantage of total surface area reduction of emulsion droplets by electrocoalescence. This leads to an increase in particle coverage, and eventually to formation of densely packed particle shells on Pickering droplets. First, we prepare an unstable pre-emulsion with droplets having small sizes and low particle coverages, from which the final Pickering emulsion is formed via consecutive coalescence events speeded up by application of electric fields. We monitor the development of the emulsions with optical microscopy imaging. The results demonstrate that the utilisation of electric fields goes beyond the mere role of enhancing coalescence; it plays an important role in surface particle manipulation and droplet rotation that further promote formation of stable particle-covered drops.
ABSTRACT
The ultrasonic propagation in the water-based magnetic fluid with doubled layered surfactant shell was studied. The measurements were carried out both in the presence as well as in the absence of the external magnetic field. The thickness of the surfactant shell was evaluated by comparing the mean size of magnetic grain extracted from magnetization curve with the mean hydrodynamic diameter obtained from differential centrifugal sedimentation method. The thickness of surfactant shell was used to estimate volume fraction of the particle aggregates consisted of magnetite grain and surfactant layer. From the ultrasonic velocity measurements in the absence of the applied magnetic field, the adiabatic compressibility of the particle aggregates was determined. In the external magnetic field, the magnetic fluid studied in this article becomes acoustically anisotropic, i.e., velocity and attenuation of the ultrasonic wave depend on the angle between the wave vector and the direction of the magnetic field. The results of the ultrasonic measurements in the external magnetic field were compared with the hydrodynamic theory of Ovchinnikov and Sokolov (velocity) and with the internal chain dynamics model of Shliomis, Mond and Morozov (attenuation).
ABSTRACT
The effect of magnetic field on the structure formation in an oil-based magnetic fluid with various concentrations of magnetite particles was studied. The evaluation of the experimental data obtained from small-angle X-ray scattering and ultrasonic attenuation indicates the formation of chain-like aggregates composed of magnetite particles. The experimental data obtained from ultrasonic spectroscopy fit well with the recent theoretical model by Shliomis, Mond and Morozov but only for a diluted magnetic fluid. In this model it is assumed that a dimer is the main building block of a B -field-induced chain-like structure, thus the estimation of the nematic order parameter does not depend on the actual length of the structure. The scattering method used reveals information about the aggregated structure size and relative changes in the degree of anisotropy in qualitative terms. The coupling constant [Formula: see text] , concentrations [Formula: see text] , average particle size d and its polydispersity [Formula: see text] were initially obtained using the vibrating sample magnetometry and these results were further confirmed by rheometry and scattering methods. Both the particles' orientational distribution and the nematic order parameter S were inferred from the ultrasonic measurements. The investigation of SAXS patterns reveals the orientation and sizes of aggregated structures under application of different magnetic-field strengths. In addition, the magnetic-field-dependent yield stress was measured, and a relationship between the yield stress and magnetic-field strength up to 0.5 T was established.
ABSTRACT
It has been established that structural changes in a ferrofluid (formation of clusters) upon the effect of an external magnetic field can be effectively studied by ultrasound spectroscopy. In particular, the resonance absorption of ultrasonic waves enables detection and determination of the size of spherical clusters. This paper reports results of a study of changes of the size of clusters formed in a magnetic field as a function of the rate of the magnetic field intensity changes, the ferrofluid temperature, the frequency of the ultrasound wave and the angle between the magnetic field vector and the direction of ultrasound wave propagation.
ABSTRACT
Results of experimental study of anisotropy of ultrasound propagation and anisotropy of magnetic susceptibility in a ferrofluid of considerable viscosity are reported. The dependence of the propagation velocity and absorption coefficient of ultrasonic wave on the angle between the direction of measurement and that of the magnetic field provides important information on the ferrofluid structure in a magnetic field. The results show that the ultrasonic absorption coefficient of a wave propagating in a viscous ferrofluid in a DC magnetic field depends mainly on the rotational degree of freedom. Measurements of the anisotropy of the magnetic susceptibility of a ferrofluid bring the information on the magnetic moment of the magnetic particles and their mean radius.
ABSTRACT
The influence of magnetic field on the acoustic and magnetic properties of magnetic liquids is discussed. By fitting the curve of Taketomi's theory to the experimental data of the anisotropy of ultrasonic attenuation, the values of quantities describing the structure of magnetic liquids have been determined. Moreover, the dependence of magnetic susceptibility on frequency has been measured. It shows that two processes of magnetization, based on the mechanisms proposed by Brown and Neel, contribute to the magnetization of the magnetic liquid.
ABSTRACT
The rate of external magnetic field changes as well as temperature influences the structure of a magnetic fluid. This work presents experimental results on changes in the ultrasonic wave absorption coefficient of EMG-605 water-based magnetic fluid as a function of the external magnetic field intensity for different rates of magnetic field changes, at different temperatures. On the basis of these studies, radii of spherical clusters formed in the fluid under the influence of an external magnetic field have been determined.
