1.
Org Lett
; 18(18): 4710-3, 2016 09 16.
Article
in English
| MEDLINE
| ID: mdl-27571142
ABSTRACT
The well-defined aluminum monohydride compound [{(2,4,6-Me3-C6H2)NC(Me)}2(Me)(H)]AlH·(NMe2Et) (1) catalyzes hydroboration of a wide range of aldehydes and ketones under mild reaction conditions. Moreover, compound 1 displayed chemoselective hydroboration of aldehydes over ketones at rt.