ABSTRACT
Ultrafiltration membrane technology holds promise for wastewater treatment, but its widespread application is hindered by fouling and flux reduction issues. One effective strategy for enhancing ultrafiltration membranes involves incorporating activated carbon powder. In this study, composite polyethersulfone (PES) ultrafiltration membranes were fabricated to include activated carbon powder concentrations between 0 and 1.5 wt.%, with carbon size fixed at 200 mesh. The ultrafiltration membranes were evaluated in terms of membrane morphology, hydrophilicity, pure water flux, equilibrium water content, porosity, average pore size, protein separation, and E-coli bacteria removal. It was found that the addition of activated carbon to PES membranes resulted in improvements in some key properties. By incorporating activated carbon powder, the hydrophilicity of PES membranes was enhanced, lowering the contact angle from 60° to 47.3° for composite membranes (1.0 wt.% of activated carbon) compared to the pristine PES membrane. Water flux tests showed that the 1.0 wt.% composite membrane yielded the highest flux, with an improvement of nearly double the initial value at 2 bar, without compromising bovine serum albumin rejection or bacterial removal capabilities. This study also found that the inclusion of activated carbon had a minor impact on the membrane's porosity and equilibrium water content. Overall, these insights will be beneficial in determining the optimal concentration of activated carbon powder for PES ultrafiltration membranes.
ABSTRACT
The aim of this research was to study the possibility of using silver nanoflakes (SNFs) as an antibacterial agent in polysulfone (PSF) membranes. SNFs at different concentrations (0.1, 0.2, 0.3 and 0.4 wt.%) were added to a PSF membrane dope solution. To investigate the effect of SNFs on membrane performance and properties, the water contact angle, protein separation, average pore size and molecular weight cutoffs were measured, and water flux and antibacterial tests were conducted. The antimicrobial activities of the SNFs were investigated using Escherichia coli taken from river water. The results showed that PSF membranes blended with 0.1 wt.% SNFs have contact angles of 55°, which is less than that of the pristine PSF membrane (81°), exhibiting the highest pure water flux. Molecular weight cutoff values of the blended membranes indicated that the presence of SNFs does not lead to enlargement of the membrane pore size. The rejection of protein (egg albumin) was improved with the addition of 0.1 wt.% SNFs. The SNFs showed antimicrobial activity against Escherichia coli, where the killing rate was dependent on the SNF concentration in the membranes. The identified bacterial colonies that appeared on the membranes decreased with increasing SNF concentration. PSF membranes blended with SNF, to a great degree, possess quality performance across several indicators, showing great potential to be employed as water filtration membranes.
