ABSTRACT
The Finite Volume Point Dilution Method (FVPDM) is a single-well tracer experiment which has been successfully used in many hydrogeological contexts to quantify groundwater fluxes. During continuous injection of tracer into a well, the tracer concentration evolution measured within the tested well directly depends on the groundwater flow crossing the well screens. Up to now, the FVPDM mathematical formulation used to simulate the tracer concentration evolution measured in the tested well assumed perfect homogenization of the tracer along the tested interval, which is a reasonable assumption in many cases. However, when FVPDM are performed in long-screened boreholes or in very permeable aquifer materials, the recirculation flow rate imposed to ensure mixing is suspected to be too low to perfectly homogenize the tracer. In order to assess the effect of non-perfect mixing on FVPDM results, we introduce here a new discrete model that explicitly considers the recirculation flow rate. The mathematical developments are validated using field measurements, and a sensitivity analysis is proposed to assess the effect of the mixing flow rate on tracer concentration homogenization within the well. Results confirm that, when the recirculation flow rate applied is not high enough compared to the groundwater flow rate, the tracer distribution is not uniform in the tested interval. In this case, the use of the classical analytical solution, commonly used to interpret the concentration evolution leads to highly overestimated groundwater fluxes. The discrete model introduced here can be used instead to properly estimate groundwater fluxes and assess the tracer distribution within the tested interval. The discrete model offers the possibility of interpreting field measurements conducted under non-perfect mixing conditions and increases the range of fluxes that can be investigated through FVPDM.
Subject(s)
Groundwater , Water Movements , Groundwater/analysis , Models, TheoreticalABSTRACT
Compound-specific isotope analysis (CSIA) is a powerful tool to track contaminant fate in groundwater. However, the application of CSIA to chlorinated ethanes has received little attention so far. These compounds are toxic and prevalent groundwater contaminants of environmental concern. The high susceptibility of chlorinated ethanes like 1,1,1-trichloroethane (1,1,1-TCA) to be transformed via different competing pathways (biotic and abiotic) complicates the assessment of their fate in the subsurface. In this study, the use of a dual C-Cl isotope approach to identify the active degradation pathways of 1,1,1-TCA is evaluated for the first time in an aerobic aquifer impacted by 1,1,1-TCA and trichloroethylene (TCE) with concentrations of up to 20 mg/L and 3.4 mg/L, respectively. The reaction-specific dual carbon-chlorine (C-Cl) isotope trends determined in a recent laboratory study illustrated the potential of a dual isotope approach to identify contaminant degradation pathways of 1,1,1-TCA. Compared to the dual isotope slopes (Δδ(13)C/Δδ(37)Cl) previously determined in the laboratory for dehydrohalogenation/hydrolysis (DH/HY, 0.33 ± 0.04) and oxidation by persulfate (∞), the slope determined from field samples (0.6 ± 0.2, r(2) = 0.75) is closer to the one observed for DH/HY, pointing to DH/HY as the predominant degradation pathway of 1,1,1-TCA in the aquifer. The observed deviation could be explained by a minor contribution of additional degradation processes. This result, along with the little degradation of TCE determined from isotope measurements, confirmed that 1,1,1-TCA is the main source of the 1,1-dichlorethylene (1,1-DCE) detected in the aquifer with concentrations of up to 10 mg/L. This study demonstrates that a dual C-Cl isotope approach can strongly improve the qualitative and quantitative assessment of 1,1,1-TCA degradation processes in the field.
