The performance of pharmaceutical wastewater treatment system of electrocoagulation assisted adsorption using perforated electrodes to reduce passivation.

The integrated electrocoagulation-assisted adsorption (ECA) system with a solar photovoltaic power supply has gained more attention as an effective approach for reduction chemical oxygen demand (COD) from pharmaceutical wastewater (PhWW). In this research, the ECA system was used for the treatment of PhWW. Several operating parameters were investigated, including electrode number, configuration, distance, operating time, current density, adsorption time, and temperature. A current density of 6.656 mA/cm2, six electrodes, a 20-min time, a 4 cm distance, an MP-P configuration, and a 45 °C temperature produced the maximum COD reductions, where the operating cost of conventional energy was 0.273 $/m3. The EC, adsorption, and combination of EC and adsorption processes achieved efficient COD reductions of 85.4, 69.1, and 95.5%, respectively. The pseudo-second-order kinetic model and the Freundlich isotherm fit the data of the endothermic adsorption process. Therefore, it was found that the combination processes were superior to the use of these processes in isolation to remove COD.

Assessment of groundwater vulnerability in the coastal region of Oman using DRASTIC index method in GIS environment.

A study was carried out to develop a vulnerability map for Barka region in the North Batina of Oman using DRASTIC vulnerability index method in GIS environment. DRASTIC layers were created using data from published reports and the seven DRASTIC layers were processed by the ArcGIS geographic information system. Finally, DRASTIC maps were created for 1995 and 2004 to understand the long-term changes in the vulnerability index. DRASTIC vulnerability maps were evaluated using groundwater quality data such as chemical and biological parameters. DRASTIC vulnerability maps of 1995 and 2004 indicate that the northern part of Barka is more vulnerable to pollution than southern part and the central part of Barka also shows high relative vulnerability which is mostly related to the high conductivity values. Moreover, the changes in water level due to high abstraction rate of groundwater reflect in the vulnerability maps and low vulnerability area is increased in the southern part during 2004 compared to 1995. Moreover, regional distribution maps of nitrate, chloride and total and fecal coliforms are well correlated with DRASTIC vulnerability maps. In contrast to this, even though DRASTIC method predicted the central part of the study region is highly vulnerable, both chemical and biological parameters show lower concentrations in this region compared to coastal belt, which is mainly due to agricultural and urban development. In Barka, urban development and agricultural activities are very high in coastal region compared to southern and central part of the study area. Hence, this study concluded that DRASTIC method is also applicable in coastal region having ubiquitous contamination sources.

Evaluating greywater reuse potential for sustainable water resources management in Oman.

This study aims to evaluate the potential of greywater availability in Muscat Governorate in the Sultanate of Oman, to establish a methodology for greywater quantity estimation, to test greywater quality in order to assess reuse potential, and to examine public acceptance for reuse.Total fresh water consumption and greywater generation from different household sources were measured by water meters in five selected households during summer and winter. Additionally, a survey was designed and conducted in five administrative areas of Muscat Governorate, with the objective of testing a methodology for estimating greywater generation potential in these areas. Collected data were compared with that used by the Ministry of Housing, Electricity and Water, Sultanate of Oman. The survey covered a total of 169 houses and 1,365 people. Greywater samples were collected and analyzed from showers, laundries, kitchens and sinks in some of these households to determine their water quality parameters. Statistical analysis results indicated that there is no significant variance in the total fresh water consumption between data used by the ministry and those measured and estimated during this study, highlighting the applicability of the tested method. The study concluded that the average per capita greywater generation rate is 151 Lpcd. Greywater production ranged from 80 to 83% of the total fresh water consumption and most of the greywater is generated from showers. Further, 55 to 57% of the greywater generated in a typical Omani household originated from the shower, 28 to 33% originated from the kitchen, 6 to 9% originated from laundry, and 5 to 7% originated from sink, which constitutes approximately 81% of the total fresh water consumption. The physical, chemical, and biological analyses of the grab samples revealed that greywater contains significant levels of suspended solids, inorganic constituents, total organic carbon, chemical and biochemical oxygen demands, total Coliforms and Escherichia Coliform bacteria. The public acceptance survey illustrated that approximately 76% of the respondents accepted the reuse of greywater for gardening, 53% for car washing and 66% for toilet flushing.

Petroleum contaminated soil in Oman: evaluation of bioremediation treatment and potential for reuse in hot asphalt mix concrete.

This paper presents a study that aims at evaluating the leaching characteristics of petroleum contaminated soils as well as their application in hot mix asphalt concrete. Soil samples are environmentally characterized in terms of their total heavy metals and hydrocarbon compounds and leachability. The total petroleum hydrocarbon (TPH) present in the PCS before and after treatment was determined to be 6.8% and 5.3% by dry weight, indicating a reduction of 1% in the TPH of PCS due to the current treatment employed. Results of the total heavy metal analysis on soils indicate that the concentrations of heavy metals are lower when extraction of the soil samples is carried out using hexane in comparison to TCE. The results show that the clean soils present in the vicinity of contaminated sites contain heavy metals in the following decreasing order: nickel (Ni), followed by chromium (Cr), zinc (Zn), copper (Cu), lead (Pb), and vanadium (V). The current treatment practice employed for remediation of the contaminated soil reduces the concentrations of nickel and chromium, but increases the concentrations of all remaining heavy metals.

Assessment of alternative management techniques of tank bottom petroleum sludge in Oman.

This paper investigated several options for environmentally acceptable management techniques of tank bottom oily sludge. In particular, we tested the applicability of managing the sludge by three options: (1) as a fuel supplement; (2) in solidification; (3) as a road material. Environmental testing included determination of heavy metals concentration; toxic organics concentration and radiological properties. The assessment of tank bottom sludge as a fuel supplement included various properties such as proximate analysis, ultimate analysis and energy content. Solidified sludge mixtures and road application sludge mixtures were subjected to leaching using the toxicity characteristic leaching procedure (TCLP). Tank bottom sludge was characterized as having higher concentrations of lead, zinc, and mercury, but lower concentrations of nickel, copper and chromium in comparison with values reported in the literature. Natural occurring radioactive minerals (NORM) activity values obtained on different sludge samples were very low or negligible compared to a NORM standard value of 100Bq/g. The fuel assessment results indicate that the heating values, the carbon content and the ash content of the sludge samples are comparable with bituminous coal, sewage sludge, meat and bone meal and petroleum coke/coal mixture, but lower than those in car tyres and petroleum coke. The nitrogen content is lower than those fuels mentioned above, while the sulfur content seems comparable with bituminous coal, petroleum coke and a petroleum coke/coal mixture. The apparent lack of leachability of metals from solidification and road material sludge applications suggests that toxic metals and organics introduced to these applications are not readily attacked by weak acid solutions and would not be expected to migrate or dissolved into the water. Thus, in-terms of trace metals and organics, the suggested sludge applications would not be considered hazardous as defined by the TCLP leaching procedure.

Evaluation of traffic noise pollution in Amman, Jordan.

The City of Amman, Jordan, has been subjected to persistent increase in road traffic due to overall increase in prosperity, fast development and expansion of economy, travel and tourism. This study investigates traffic noise pollution in Amman. Road traffic noise index L10(1 h) was measured at 28 locations that cover most of the City of Amman. Noise measurements were carried out at these 28 locations two times a day for a period of one hour during the early morning and early evening rush hours, in the presence and absence of a barrier. The Calculation of Road Traffic Noise (CRTN) prediction model was employed to predict noise levels at the locations chosen for the study. Data required for the model include traffic volume, speed, percentage of heavy vehicles, road surface, gradient, obstructions, distance, noise path, intervening ground, effect of shielding, and angle of view. The results of the investigation showed that the minimum and the maximum noise levels are 46 dB(A) and 81 dB(A) during day-time and 58 dB(A) and 71 dB(A) during night-time. The measured noise level exceeded the 62 dB(A) acceptable limit at most of the locations. The CTRN prediction model was successful in predicting noise levels at most of the locations chosen for this investigation, with more accurate predictions for night-time measurements.