Printable Light-Emitting Metasurfaces with Enhanced Directional Photoluminescence.

Nanoimprint lithography is gaining popularity as a cost-efficient way to reproduce nanostructures in large quantities. Recent advances in nanoimprinting lithography using high-index nanoparticles have demonstrated replication of photonic devices, but it is difficult to confer special properties on nanostructures beyond general metasurfaces. Here, we introduce a novel method for fabricating light-emitting metasurfaces using nanoimprinting lithography. By utilizing quantum dots embedded in resin, we successfully imprint dielectric metasurfaces that function simultaneously as both emitters and resonators. This approach to incorporating quantum dots into metasurfaces demonstrates an improvement in photoluminescence characteristics compared to the situation where quantum dots and metasurfaces are independently incorporated. Design of the metasurface is specifically tailored to support photonic modes within the emission band of quantum dots with a large enhancement of photoluminescence. This study indicates that nanoimprinting lithography has the capability to construct nanostructures using functionalized nanoparticles and could be used in various fields of nanophotonic applications.

Dual-wavelength metalens enables Epi-fluorescence detection from single molecules.

Single molecule fluorescence spectroscopy is at the heart of molecular biophysics research and the most sensitive biosensing assays. The growing demand for precision medicine and environmental monitoring requires the creation of miniaturized and portable sensing platforms. However, the need for highly sophisticated objective lenses has precluded the development of single molecule detection systems for truly portable devices. Here, we propose a dielectric metalens device of submicrometer thickness to excite and collect light from fluorescent molecules instead of an objective lens. The high numerical aperture, high focusing efficiency, and dual-wavelength operation of the metalens enable the implementation of fluorescence correlation spectroscopy with a single Alexa 647 molecule in the focal volume. Moreover, the metalens enables real-time monitoring of individual fluorescent nanoparticle transitions and identification of hydrodynamic diameters ranging from a few to hundreds of nanometers. This advancement in sensitivity extends the application of the metalens technology to ultracompact single-molecule sensors.

Scalable manufacturing of high-index atomic layer-polymer hybrid metasurfaces for metaphotonics in the visible.

Metalenses are attractive alternatives to conventional bulky refractive lenses owing to their superior light-modulating performance and sub-micrometre-scale thicknesses; however, limitations in existing fabrication techniques, including high cost, low throughput and small patterning area, have hindered their mass production. Here we demonstrate low-cost and high-throughput mass production of large-aperture visible metalenses using deep-ultraviolet argon fluoride immersion lithography and wafer-scale nanoimprint lithography. Once a 12″ master stamp is imprinted, hundreds of centimetre-scale metalenses can be fabricated using a thinly coated high-index film to enhance light confinement, resulting in a substantial increase in conversion efficiency. As a proof of concept, an ultrathin virtual reality device created with the printed metalens demonstrates its potential towards the scalable manufacturing of metaphotonic devices.

Planar Optical Cavities Hybridized with Low-Dimensional Light-Emitting Materials.

Low-dimensional light-emitting materials have been actively investigated due to their unprecedented optical and optoelectronic properties that are not observed in their bulk forms. However, the emission from low-dimensional light-emitting materials is generally weak and difficult to use in nanophotonic devices without being amplified and engineered by optical cavities. Along with studies on various planar optical cavities over the last decade, the physics of cavity-emitter interactions as well as various integration methods are investigated deeply. These integrations not only enhance the light-matter interaction of the emitters, but also provide opportunities for realizing nanophotonic devices based on the new physics allowed by low-dimensional emitters. In this review, the fundamentals, strengths and weaknesses of various planar optical resonators are first provided. Then, commonly used low-dimensional light-emitting materials such as 0D emitters (quantum dots and upconversion nanoparticles) and 2D emitters (transition-metal dichalcogenide and hexagonal boron nitride) are discussed. The integration of these emitters and cavities and the expect interplay between them are explained in the following chapters. Finally, a comprehensive discussion and outlook of nanoscale cavity-emitter integrated systems is provided.

An achromatic metafiber for focusing and imaging across the entire telecommunication range.

Dispersion engineering is essential to the performance of most modern optical systems including fiber-optic devices. Even though the chromatic dispersion of a meter-scale single-mode fiber used for endoscopic applications is negligible, optical lenses located on the fiber end face for optical focusing and imaging suffer from strong chromatic aberration. Here we present the design and nanoprinting of a 3D achromatic diffractive metalens on the end face of a single-mode fiber, capable of performing achromatic and polarization-insensitive focusing across the entire near-infrared telecommunication wavelength band ranging from 1.25 to 1.65 µm. This represents the whole single-mode domain of commercially used fibers. The unlocked height degree of freedom in a 3D nanopillar meta-atom largely increases the upper bound of the time-bandwidth product of an achromatic metalens up to 21.34, leading to a wide group delay modulation range spanning from -8 to 14 fs. Furthermore, we demonstrate the use of our compact and flexible achromatic metafiber for fiber-optic confocal imaging, capable of creating in-focus sharp images under broadband light illumination. These results may unleash the full potential of fiber meta-optics for widespread applications including hyperspectral endoscopic imaging, femtosecond laser-assisted treatment, deep tissue imaging, wavelength-multiplexing fiber-optic communications, fiber sensing, and fiber lasers.

Disordered-nanoparticle-based etalon for ultrafast humidity-responsive colorimetric sensors and anti-counterfeiting displays.

The development of real-time and sensitive humidity sensors is in great demand from smart home automation and modern public health. We hereby proposed an ultrafast and full-color colorimetric humidity sensor that consists of chitosan hydrogel sandwiched by a disordered metal nanoparticle layer and reflecting substrate. This hydrogel-based resonator changes its resonant frequency to external humidity conditions because the chitosan hydrogels are swollen under wet state and contracted under dry state. The response time of the sensor is ~104 faster than that of the conventional Fabry-Pérot design. The origins of fast gas permeation are membrane pores created by gaps between the metal nanoparticles. Such instantaneous and tunable response of a new hydrogel resonator is then exploited for colorimetric sensors, anti-counterfeiting applications, and high-resolution displays.

Metasurface-Driven Optically Variable Devices.

Optically variable devices (OVDs) are in tremendous demand as optical indicators against the increasing threat of counterfeiting. Conventional OVDs are exposed to the danger of fraudulent replication with advances in printing technology and widespread copying methods of security features. Metasurfaces, two-dimensional arrays of subwavelength structures known as meta-atoms, have been nominated as a candidate for a new generation of OVDs as they exhibit exceptional behaviors that can provide a more robust solution for optical anti-counterfeiting. Unlike conventional OVDs, metasurface-driven OVDs (mOVDs) can contain multiple optical responses in a single device, making them difficult to reverse engineered. Well-known examples of mOVDs include ultrahigh-resolution structural color printing, various types of holography, and polarization encoding. In this review, we discuss the new generation of mOVDs. The fundamentals of plasmonic and dielectric metasurfaces are presented to explain how the optical responses of metasurfaces can be manipulated. Then, examples of monofunctional, tunable, and multifunctional mOVDs are discussed. We follow up with a discussion of the fabrication methods needed to realize these mOVDs, classified into prototyping and manufacturing techniques. Finally, we provide an outlook and classification of mOVDs with respect to their capacity and security level. We believe this newly proposed concept of OVDs may bring about a new era of optical anticounterfeit technology leveraging the novel concepts of nano-optics and nanotechnology.

Unlocking the future of optical security with metasurfaces.

The complex degrees of freedom of light, such as amplitude, phase, polarization, and orbital angular momentum, make it a prime candidate for use in optical security and encryption. By exploiting the unique characteristics of metasurfaces, exciting new optical security platforms have been demonstrated.

Pixelated bifunctional metasurface-driven dynamic vectorial holographic color prints for photonic security platform.

Vectorial holography has gained a lot of attention due to the promise of versatile polarization control of structured light for enhanced optical security and multi-channel optical communication. Here, we propose a bifunctional metasurface which combines both structural color printing and vectorial holography with eight polarization channels towards advanced encryption applications. The structural colour prints are observed under white light while the polarization encoded holograms are reconstructed under laser illumination. To encode multiple holographic images for different polarization states, a pixelated metasurface is adopted. As a proof-of-concept, we devise an electrically tunable optical security platform incorporated with liquid crystals. The optical security platform is doubly encrypted: an image under white light is decrypted to provide the first key and the corresponding information is used to fully unlock the encrypted information via projected vectorial holographic images. Such an electrically tunable optical security platform may enable smart labels for security and anticounterfeiting applications.

Nearly Perfect Transmissive Subtractive Coloration through the Spectral Amplification of Mie Scattering and Lattice Resonance.

Silicon has been utilized in metasurfaces to produce structural color filters due to its compatibility with mature and cost-effective methods for complementary metal oxide semiconductor devices. In this work, we propose and demonstrate efficiency- and scattering-enhanced structural color filters using all-dielectric metasurfaces made up of engineered hydrogenated amorphous silicon (a-Si:H) nanoblocks. Wavelength-dependent filtering is achieved by Mie scattering as each structure individually supports the electric dipole (ED) and magnetic dipole (MD) resonances. The ED and MD resonances are identified by observing the field profiles of the resonance calculated by finite element method (FEM) simulations. To enhance the efficiency and scattering response of the all-dielectric metasurfaces, the proposed structural color filters are designed with consideration of the lattice resonances and scattering directivity. The spectral positions of the transmission dips and peaks are rigorously analyzed in accordance with the Mie theory and multipole expansion. The transmission spectra exhibit 100% transmission where Kerker's first condition is satisfied, while the lattice resonances amplify the ED and MD scattering responses throughout the entire visible regime. Various colors are generated by varying the resonance peak, which is controlled by varying the geometric parameters of a-Si:H nanoblocks. The proposed structural color printing devices are expected to have applications in dynamic color displays, imaging devices, and photorealistic color printing.

Nanophotonics for light detection and ranging technology.

Light detection and ranging (LiDAR) technology, a laser-based imaging technique for accurate distance measurement, is considered one of the most crucial sensor technologies for autonomous vehicles, artificially intelligent robots and unmanned aerial vehicle reconnaissance. Until recently, LiDAR has relied on light sources and detectors mounted on multiple mechanically rotating optical transmitters and receivers to cover an entire scene. Such an architecture gives rise to limitations in terms of the imaging frame rate and resolution. In this Review, we examine how novel nanophotonic platforms could overcome the hardware restrictions of existing LiDAR technologies. After briefly introducing the basic principles of LiDAR, we present the device specifications required by the industrial sector. We then review a variety of LiDAR-relevant nanophotonic approaches such as integrated photonic circuits, optical phased antenna arrays and flat optical devices based on metasurfaces. The latter have already demonstrated exceptional functional beam manipulation properties, such as active beam deflection, point-cloud generation and device integration using scalable manufacturing methods, and are expected to disrupt modern optical technologies. In the outlook, we address the upcoming physics and engineering challenges that must be overcome from the viewpoint of incorporating nanophotonic technologies into commercially viable, fast, ultrathin and lightweight LiDAR systems.

Stimuli-Responsive Dynamic Metaholographic Displays with Designer Liquid Crystal Modulators.

Flat optics, realized by the artificially created 2D material platform called optical metasurfaces, is currently undergoing a science-to-technology transition. However, "real-time" active operations of such flat optical devices remain yet unresolved. Here, liquid crystals (LCs)-integrated metaholograms for ultracompact dynamic holographic displays are proposed. The anisotropic nature of the LCs allows facile and repeatable manipulation of the polarization of light. Specifically designed ("designer") LCs and efficient helicity-encoded metaholograms are combined to realize stimuli-responsive dynamic displays. The designer LC modulators are used as switches that enable a variety of external stimuli (e.g., electric field, heat, surface pressure) to operate holographic images in real-time. Such a dynamic metaholographic platform will provide a path to external stimuli-driven "smart" sensing and display applications such as hologram labels for temperature/pressure/touch monitoring and interactive holographic displays with haptic motion recognition.

Full and gradient structural colouration by lattice amplified gallium nitride Mie-resonators.

The hybridised resonances between Mie-scatterers and lattice resonances, i.e. quasi-guided mode resonances, are investigated. The scattering of the Mie-resonators is improved by the first order of transmitted diffracted light which is coupled to the lattice formed by the Mie-resonators. The conditions of coupling are dependent on the refractive index of the substrate and the effective refractive index of the unit cell of the resonators. Based on the momentum matching conditions, the cut-off wavelength of coupling and the amount of the amplification can be controlled. As a proof-of-concept application of this framework, gallium nitride metasurfaces are designed to produce metasurfaces that display structural colour. Palettes of full spectral colour and gradients are successfully demonstrated. The hue of the colour can be controlled by changing the periodicity of the unit cell at a fixed filling ratio of Mie-scatterer radius to unit cell periodicity, since the increase in periodicity redshifts the cut-off wavelength of the lattice resonance conditions, identified as the Rayleigh anomaly. The brightness of the colour can be tuned by adjusting the filling ratio of the unit cell. Consequently, the proposed framework may provide a fundamental guideline to design spectral filters made up of low-index Mie-scatterers for various applications.

Spectral Modulation through the Hybridization of Mie-Scatterers and Quasi-Guided Mode Resonances: Realizing Full and Gradients of Structural Color.

Metasurfaces made up of subwavelength arrays of Mie scatterers can be engineered to control the optical properties of incident light. The hybridization of the fundamental Mie resonances with lattice resonances greatly enhances the scattering cross-section of individual Mie scatterers. Through careful design of the locations of these hybridized modes using two differently engineered hydrogenated amorphous silicon nanorods, we numerically calculate and experimentally fabricate two examples of full color printing; one with spectral colors comparable to the Adobe RGB gamut, and another with gradients of color. We identify and characterize the mechanisms behind each and provide a framework that can be used to design any all-dielectric metasurfaces of subwavelength Mie scatterers for spectral modulation.

Complex-amplitude metasurface-based orbital angular momentum holography in momentum space.

Digital optical holograms can achieve nanometre-scale resolution as a result of recent advances in metasurface technologies. This has raised hopes for applications in data encryption, data storage, information processing and displays. However, the hologram bandwidth has remained too low for any practical use. To overcome this limitation, information can be stored in the orbital angular momentum of light, as this degree of freedom has an unbounded set of orthogonal helical modes that could function as information channels. Thus far, orbital angular momentum holography has been achieved using phase-only metasurfaces, which, however, are marred by channel crosstalk. As a result, multiplex information from only four channels has been demonstrated. Here, we demonstrate an orbital angular momentum holography technology that is capable of multiplexing up to 200 independent orbital angular momentum channels. This has been achieved by designing a complex-amplitude metasurface in momentum space capable of complete and independent amplitude and phase manipulation. Information was then extracted by Fourier transform using different orbital angular momentum modes of light, allowing lensless reconstruction and holographic videos to be displayed. Our metasurface can be three-dimensionally printed in a polymer matrix on SiO2 for large-area fabrication.

Plasmonic- and dielectric-based structural coloring: from fundamentals to practical applications.

Structural coloring is production of color by surfaces that have microstructure fine enough to interfere with visible light; this phenomenon provides a novel paradigm for color printing. Plasmonic color is an emergent property of the interaction between light and metallic surfaces. This phenomenon can surpass the diffraction limit and achieve near unlimited lifetime. We categorize plasmonic color filters according to their designs (hole, rod, metal-insulator-metal, grating), and also describe structures supported by Mie resonance. We discuss the principles, and the merits and demerits of each color filter. We also discuss a new concept of color filters with tunability and reconfigurability, which enable printing of structural color to yield dynamic coloring at will. Approaches for dynamic coloring are classified as liquid crystal, chemical transition and mechanical deformation. At the end of review, we highlight a scale-up of fabrication methods, including nanoimprinting, self-assembly and laser-induced process that may enable real-world application of structural coloring.