ABSTRACT
We prepared electrospun polymer nanofibers by electrospnning method and investigated about their applications to dye-sensitized solar cells (DSSCs). Electrospun polymer nanofibers applied to the polymer matrix in electrolyte for DSSCs. To improve the stiffness of polymer nanofiber, poly(vinylidene fluoride-hexafluoro propylene)/Poly(methyl methacrylate) (PVDF-HFP/PMMA) blend nanofibers were prepared and examined. In the electrospun PVDF-HFP/PMMA (1:1) blend nanofibers, the best results of VOC, JSC, FF, and efficiency of the DSSC devices showed 0.71 V, 12.8 mA/cm2, 0.61, and 5.56% under AM 1.5 illumination.
Subject(s)
Coloring Agents/chemistry , Electric Power Supplies , Electrolytes/chemistry , Nanofibers , Polymethyl Methacrylate/chemistry , Polytetrafluoroethylene/analogs & derivatives , Polyvinyls/chemistry , Solar Energy , Microscopy, Electron, Scanning , Polytetrafluoroethylene/chemistryABSTRACT
We have synthesized soluble TiOPc derivatives containing alkoxy groups for use as additives in dye-sensitized solar cells (DSSCs). The DSSC devices containing these TiOPc derivatives exhibited short-circuit current densities of 8.49~10.04 mA/cm(2) and power conversion efficiencies of 2.73~3.62 % under AM 1.5 illumination and 100 mW/cm(2) irradiation.