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1.
Gold-gold cooperation in the addition of methanol to alkynes.
Roithová, Jana; Janková, Stepánka; Jasíková, Lucie; Vána, Jirí; Hybelbauerová, Simona.
Angew Chem Int Ed Engl ; 51(33): 8378-82, 2012 Aug 13.
Article in English | MEDLINE | ID: mdl-22782688

Subject(s)
Alkynes/chemistry , Gold/chemistry , Methanol/chemistry , Catalysis , Organogold Compounds/chemical synthesis , Organogold Compounds/chemistry
2.
Synthesis and characterisation of Dewar benzene-ferrocene conjugates.
Janková, Stepánka; Císarová, Ivana; Uhlík, Filip; Stepnicka, Petr; Kotora, Martin.
Dalton Trans ; (17): 3137-9, 2009 May 07.
Article in English | MEDLINE | ID: mdl-19421614

ABSTRACT

The first Dewar benzene-ferrocene conjugates were synthesised by the reaction of tetraalkylcyclobutadiene-AlCl(3) complexes with 3-ferrocenylpropynoates. Owing to extensive delocalisation, these conjugates feature unusually high thermal and chemical stability, rearranging to their corresponding phenylferrocenes (benzenes) under forcing microwave irradiation conditions.

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