1.
Angew Chem Int Ed Engl
; 40(14): 2697-2699, 2001 Jul 16.
Article
in English
| MEDLINE
| ID: mdl-11458378
2.
Angew Chem Int Ed Engl
; 40(14): 2697-2699, 2001 Jul 16.
Article
in English
| MEDLINE
| ID: mdl-29712338
ABSTRACT
A new immobilization scheme for enantioselective catalysts was developed by using a combination of ionic liquids and compressed CO2 . Under continuous flow conditions, stable conversion and asymmetric induction was achieved over more than 60 h in the enantioselective Ni-catalyzed hydrovinylation of styrene. While the ionic liquid dissolves and activates the organometallic catalyst in a tuneable manner, the presence of compressed CO2 greatly facilitates mass transfer and gives easy access to continuous processes.