ABSTRACT
A novel adsorbent with excellent adsorptive properties for fluoride was prepared through a green and cheap synthesis route. Populus caspica pruning wastes, a cheap agri-waste material, were reduced to multi-layer green graphene (MLG) and then post-modified to aluminum/iron modified multi-layer green graphene (AMLG and IMLG). Batch experiments revealed the effect of pH (3-11), contact time (0.5-12 h), and initial fluoride concentration (5-40 mg/L). The conversion of raw material to MLG increased the specific surface area about 120 times (from 4 to 475 m2/g). Furthermore, a significant improvement in zero points of charge (pHzpc) was attained for IMLG (7.1) and AMLG (8) compared with pristine MLG (4.3). Fluoride showed superior affinity to AMLG and IMLG compared with MLG. Fluoride removal increased gradually by pH from 3 to 8 and then decreased sharply up to pH 11. The study of process dynamics demonstrated the monolayer fluoride adsorption onto AMLG and IMLG controlled by the chemisorptions. The highest predicted adsorption capacities based on the Langmuir model were 31.52, 47.01, and 53.76 mg/g for MLG, IMLG, and AMLG, respectively. Considering economic and technical feasibility presents AMLG and IMLG as a promising candidate against water contamination by elevated fluoride. Graphical abstract.
